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1. 发明授权

EP0584328B1 MONOMERES DERIVES DE SULTONES PERHALOGENEES ET POLYMERES OBTENUS A PARTIR DE CES MONOMERES 失效
标题翻译：全卤化内酯衍生单体及聚合物生产由这些单体
公开(公告)号：EP0584328B1
公开(公告)日：1995-12-13
申请号：EP93905408.6
申请日：1993-02-19
申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) , HYDRO-QUEBEC
发明人： ARMAND, Michel , SANCHEZ, Jean-Yves , SYLLA, Salime
IPC分类号： C07C309/83 , C07C309/82 , C07C309/81 , C07C309/15 , C07C309/10 , C07F7/18 , C07D303/22 , C08G65/32
CPC分类号： H01M10/052 , C07C309/07 , C07C309/09 , C07C309/17 , C07C309/82 , C07C309/84 , C07F7/0834 , C07F7/1836 , C08G65/14 , C08G65/22 , C08G65/226 , C08G65/3346 , C08G65/337 , C08G79/02 , H01B1/122 , H01M6/181 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , H01M10/0565 , Y02P70/56
摘要： Perhalogenated sultone-derived monomers, a preparation method therefor, polymers produced therefrom, and uses thereof for producing ionically conductive materials. The monomers are cpmpounds having the following formula: A-CFX-SO2Z, wherein A is a R3-O-CF2- or R3- or R'R2N-CO- group; Z is F, Cl, -OSi(CH¿3?)3 or an ionic grouping, and is other than F when A is R?3-O-CF¿2- or R3-; X is F, Cl, H or R¿F?, and X is RF when A is R?3¿-; the radicals R', R?2 and R3¿ are chosen from polymerizable non-perfluorinated organic radicals; and R¿F? is chosen from perfluoroalkyl and perfluoroaryl radicals. Polymers produced from said monomers may be used for producing ionically conductive materials.

2. 发明授权

EP1916237B1 COMPOUND CONTAINING FLUOROSULFONYL GROUP, PROCESS FOR PRODUCING THE SAME, AND POLYMER THEREOF 有权转让
标题翻译：一氟含氮化合物，PROCESS FOR THEIR和其聚合物
公开(公告)号：EP1916237B1
公开(公告)日：2010-05-05
申请号：EP06781724.7
申请日：2006-07-26
申请人： Asahi Glass Company, Limited
发明人： KANEKO, Isamu, Asahi Glass Company Limited , WATAKABE, Atsushi, Asahi Glass Company, Limited , TAYANAGI, Jyunichi, Asahi Glass Company, Limited , SAITO, Susumu, Asahi Glass Company, Limited
IPC分类号： C07C303/02 , C07C303/22 , C07C309/82 , C08F214/18
CPC分类号： C07C303/22 , C07C309/82 , C07C309/84 , C08F214/18 , C08J5/2237 , C08J2327/18 , H01B1/122 , H01M2008/1095 , H01M2300/0082
摘要： A compound containing two fluorosulfonyl groups, which are groups convertible to sulfo groups; an intermediate therefor; and processes for producing these compounds with high productivity. Also provided are: a fluorosulfonylated polymer obtained by polymerizing the compound; and a sulfo-group-containing polymer obtained from that polymer. The compound is represented by the following formula (m0) (wherein RF01 represents a single bond or a C1-6 divalent perfluorinated organic group; RF02 represents a C1-6 divalent perfluorinated organic group; and n is 0 or 1).

3. 发明公开

EP1352243A4 PERFLUORO SULFONYL HALIDES AND RELATED SPECIES AS POLYMER SUPPORT MODIFIERS 审中-公开
标题翻译： PERFLUORSULFONYLHALOGENIDE及其近缘种作为修饰的聚合物载体
公开(公告)号：EP1352243A4
公开(公告)日：2008-07-02
申请号：EP02714736
申请日：2002-01-11
申请人： GE HEALTHCARE LTD
发明人： HOLMES CHRISTOPHER , PAN YIJUN
IPC分类号： G01N33/543 , B01J19/00 , B01J20/289 , B01J20/32 , B01J31/10 , B01J31/22 , B01J31/24 , C07B61/00 , C07C15/24 , C07C43/20 , C07C49/76 , C07C49/782 , C07C49/786 , C07C49/807 , C07C49/84 , C07C233/07 , C07C255/54 , C07C309/24 , C07C309/82 , C07C309/83 , C07C309/84 , C07F7/08 , C40B50/14 , C40B60/14
CPC分类号： C40B50/14 , B01J19/0046 , B01J20/289 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3219 , B01J20/3251 , B01J20/3257 , B01J31/10 , B01J31/1658 , B01J31/2208 , B01J31/2409 , B01J2219/00283 , B01J2219/00454 , B01J2219/00596 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00626 , B01J2219/00637 , B01J2219/00641 , B01J2219/0072 , B01J2219/00738 , B01J2231/4211 , B01J2231/4255 , B01J2231/4261 , B01J2231/4266 , B01J2531/824 , C07B2200/11 , C07C309/10 , C07C309/24 , C07C309/82 , C07C309/84 , C07F7/0834 , C40B60/14 , C40B80/00 , C40B99/00
摘要： Activated Supports, support-bound activators, strongly acidic supports, and silylating supports are provided; the activated support having the formula (I) wherein L is a linking group component; X is F, CL, OH, and trisubstituted silyloxy; and the shaded circle represents a solid or semi-solid support. Methods of using the activated supports in solid phase organic synthesis are also provided.

4. 发明公开

EP1916237A1 COMPOUND CONTAINING FLUOROSULFONYL GROUP, PROCESS FOR PRODUCING THE SAME, AND POLYMER THEREOF 有权转让
标题翻译：一氟含氮化合物，PROCESS FOR THEIR和其聚合物
公开(公告)号：EP1916237A1
公开(公告)日：2008-04-30
申请号：EP06781724.7
申请日：2006-07-26
申请人： Asahi Glass Company, Limited
发明人： KANEKO, Isamu, Asahi Glass Company Limited , WATAKABE, Atsushi, Asahi Glass Company, Limited , TAYANAGI, Jyunichi, Asahi Glass Company, Limited , SAITO, Susumu, Asahi Glass Company, Limited
IPC分类号： C07C303/02 , C07C303/22 , C07C309/82 , C08F214/18
CPC分类号： C07C303/22 , C07C309/82 , C07C309/84 , C08F214/18 , C08J5/2237 , C08J2327/18 , H01B1/122 , H01M2008/1095 , H01M2300/0082
摘要： A compound containing two fluorosulfonyl groups which are groups convertible to sulfonic acid groups, an intermediate therefor, and methods for their production with high productivity, are provided. Also provided are a fluorosulfonyl group-containing polymer obtained by polymerizing such a compound, and a sulfonic acid group-containing polymer obtained from such a polymer.
A method for producing a compound of the following formula (m0), such a compound, a fluorosulfonyl group-containing polymer obtained by polymerizing such a compound, and a sulfonic acid group-containing polymer obtained from such a polymer, provided that R F01 is a single bond or a C 1-6 bivalent perfluoro organic group, R F02 is a C 1-6 bivalent perfluoro organic group, and n is 0 or 1:
摘要翻译：含有两个氟基团可转化为在它们的生产以高生产率中间为此，与方法为磺酸基团的化合物，提供了。所以本发明提供一种氟基团的聚合物通过聚合寻求的化合物获得，并且含磺酸基的聚合物寻求的聚合物得到。提供了一种生产下式（M0）的化合物，求的化合物，通过聚合寻求的化合物而获得的氟磺酰基的聚合物，以及从寻求聚合物获得的含磺酸基的聚合物的方法，做了[R F01是单键或C 1-6二价全氟有机基团，R F02为碳数1-6的二价全氟有机基团，n是0或1：

5. 发明公开

EP0584328A1 MONOMERES DERIVES DE SULTONES PERHALOGENEES ET POLYMERES OBTENUS A PARTIR DE CES MONOMERES 失效
标题翻译：全卤化内酯衍生单体及聚合物所制造的这些单体。
公开(公告)号：EP0584328A1
公开(公告)日：1994-03-02
申请号：EP93905408.0
申请日：1993-02-19
申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) , HYDRO-QUEBEC
发明人： ARMAND, Michel , SANCHEZ, Jean-Yves , SYLLA, Salime
IPC分类号： C07C309 , C07C311 , C07D303 , C07F7 , C08G65 , C08G79 , H01B1 , H01M6 , H01M8 , H01M10
CPC分类号： H01M10/052 , C07C309/07 , C07C309/09 , C07C309/17 , C07C309/82 , C07C309/84 , C07F7/0834 , C07F7/1836 , C08G65/14 , C08G65/22 , C08G65/226 , C08G65/3346 , C08G65/337 , C08G79/02 , H01B1/122 , H01M6/181 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , H01M10/0565 , Y02P70/56
摘要： L'invention concerne des monomères dérivés de sultones perhalogénées, leur procédé de préparation, les polymères obtenus à partir desdits monomères et leur utilisation pour l'élaboration de matériaux à conduction ionique. Les monomères sont des composés répondant à la formule: A-CFX-SO2Z dans laquelle A représente un groupe R3-O-CF2- ou R3- ou R1R2N-CO-; Z représente F, Cl, -OSi(CH3)3 ou un groupement ionique, Z étant différent de F lorsque A représente R3-O-CF2- ou R3-; X représente F, Cl, H ou RF, X étant RF lorsque A représente R3-; les radicaux R1, R2 et R3 sont choisis parmi les radicaux organiques non perfluorés polymérisables; RF est choisi parmi les radicaux perfluoroalkyle et les radicaux perfluoroaryle. Les polymères obtenus à partir de ces monomères sont utiles pour l'élaboration de matériaux à conduction ionique.

6. 发明授权

EP1642890B1 PROCESS FOR PRODUCTION OF FLUORINATED SULFONYL FLUORIDES 有权
标题翻译：用于生产氟化磺酰
公开(公告)号：EP1642890B1
公开(公告)日：2010-09-29
申请号：EP04747237.8
申请日：2004-07-02
申请人： ASAHI GLASS COMPANY LTD.
发明人： MURATA, Koichi , OKAZOE, Takashi , MUROTANI, Eisuke
IPC分类号： C07C303/22 , C07C303/16 , C07C209/84
CPC分类号： C07C303/02 , C07C303/22 , C07C309/84
摘要： The invention provides a process for the production of fluorinated sulfonyl fluorides useful as the material of ion -exchange resins or the like and novel chemical substances useful as the intermediate in the process. Namely, a process which comprises oxidizing a compound of the general formula: Y-S-RA-E-RB with an oxidizing agent containing a halogen atom as the essential constituent into a compound of the general formula: XSO2-RA-E-RB, subjecting the obtained compound as such when X is a fluorine atom or after the conversion of X into a fluorine atom when X is a halogen atom other than fluorine to reaction with fluorine in a liquid phase to obtain a compound of the general formula: FSO2-RAF-EF-RBF, and decomposing this compound into a compound of the general formula: FSO2-RAF-COF (wherein RA is a divalent organic group such as alkylene; RB is a monovalent organic group such as perfluoroalkyl; E is -CH2OCO-; Y is a monovalent organic group such as cyano; X is a halogen atom; RAF is a divalent organic group obtained by fluorinating RA or the like; RBF is the same group as RB or the like; and EF is -CF2OCO-).

7. 发明公开

EP1642890A4 PROCESS FOR PRODUCTION OF FLUORINATED SULFONYL FLUORIDES 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG FLUORIERTER SOFONYLFLUORIDE
公开(公告)号：EP1642890A4
公开(公告)日：2006-11-29
申请号：EP04747237
申请日：2004-07-02
申请人： ASAHI GLASS CO LTD
发明人： MURATA KOICHI , OKAZOE TAKASHI , MUROTANI EISUKE
IPC分类号： C07C303/22 , C07C209/84 , C07C303/02 , C07C303/16 , C07C309/84
CPC分类号： C07C303/02 , C07C303/22 , C07C309/84
摘要： The invention provides a process for the production of fluorinated sulfonyl fluorides useful as the material of ion -exchange resins or the like and novel chemical substances useful as the intermediate in the process. Namely, a process which comprises oxidizing a compound of the general formula: Y-S-RA-E-RB with an oxidizing agent containing a halogen atom as the essential constituent into a compound of the general formula: XSO2-RA-E-RB, subjecting the obtained compound as such when X is a fluorine atom or after the conversion of X into a fluorine atom when X is a halogen atom other than fluorine to reaction with fluorine in a liquid phase to obtain a compound of the general formula: FSO2-RAF-EF-RBF, and decomposing this compound into a compound of the general formula: FSO2-RAF-COF (wherein RA is a divalent organic group such as alkylene; RB is a monovalent organic group such as perfluoroalkyl; E is -CH2OCO-; Y is a monovalent organic group such as cyano; X is a halogen atom; RAF is a divalent organic group obtained by fluorinating RA or the like; RBF is the same group as RB or the like; and EF is -CF2OCO-).
摘要翻译：本发明提供一种制备用作离子交换树脂等材料的氟化磺酰氟和用作该方法中间体的新型化学物质的方法。即，包括将通式为：YS-RA-E-RB的化合物与含有卤素原子作为基本组分的氧化剂氧化成通式：XSO2-RA-E-RB的化合物，当X是氟原子时，或者当X是氟以外的卤素原子时将X转化为氟原子后，在液相中与氟反应得到通式为FSO2-RAF的化合物（其中RA是二价有机基团如亚烷基; RB是单价有机基团如全氟烷基; E是-CH 2 OCO-;并且E是-CH 2 COO-），并且将该化合物分解成通式为FSO 2 -RAF-COF的化合物。 Y表示氰基等一价有机基团，X表示卤原子，RAF表示将RA等氟化而成的2价有机基团，RBF表示与RB等相同的基团，EF表示-CF 2 OCO-）。

8. 发明公开

EP1640362A2 PROCESS FOR PRODUCTION OF FLUORINATED SULFONYL FLUORIDES 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG氟化物磺酰氟
公开(公告)号：EP1640362A2
公开(公告)日：2006-03-29
申请号：EP04747247.7
申请日：2004-07-02
申请人： ASAHI GLASS COMPANY LTD.
发明人： MURATA, Koichi , OKAZOE, Takashi , MUROTANI, Eisuke
IPC分类号： C07C303/22 , C07C309/84
CPC分类号： C07C303/16 , C07C303/22 , C07C309/82 , C07C309/84
摘要： It is an object of the present invention to solve difficulty in production and to provide a process to obtain fluorinated sulfonyl fluoride compound having various molecular structures efficiently at a low cost.
That is, the present invention provides a process which comprises reacting (FSO 2 -) n R A (-E-R B ) m (1F) with fluorine in a liquid phase to form (FSO 2 -) n R AF (-E F -R BF ) m (2), and decomposing this compound to obtain (FSO 2 -) n R AF (-E F1 ) m (3), provided that R A is a (n+m)valent organic group having at least two carbon atoms, R AF is a group having R A fluorinated, or the like, each of R B and R BF is a fluorinated monovalent organic group, or the like, E is -COOCH 2 - or the like, E F is -COOCF 2 - or the like, E F1 is -COF or the like, n is an integer of at least 2, and m is an integer of at least 1.
摘要翻译：本发明的目的是解决生产难度，并提供以低成本有效地获得具有各种分子结构的氟化磺酰氟化合物的方法。也就是说，本发明提供了一种方法，其包括使（FSO 2 - ）n RA（-ER B）m（1F）与氟在液相中反应以形成（FSO 2 - ）n R AF（-EF -R BF ）m（2），并分解该化合物以获得（FSO 2 - ）n R AF（-E F1）m（3），条件是RA是具有至少两个碳原子的（n + m）价有机基团， R AF是具有RA氟化等的基团，RB和R BF各自为氟化一价有机基团等，E为-COOCH 2 - 等，EF为-COOCF 2 - 等， E F1为-COF等，n为2以上的整数，m为1以上的整数。

9. 发明公开

EP1352243A2 PERFLUORO SULFONYL HALIDES AND RELATED SPECIES AS POLYMER SUPPORT MODIFIERS 审中-公开
标题翻译： PERFLUORSULFONYLHALOGENIDE及其近缘种作为修饰的聚合物载体
公开(公告)号：EP1352243A2
公开(公告)日：2003-10-15
申请号：EP02714736.2
申请日：2002-01-11
申请人： Amersham plc
发明人： HOLMES, Christopher , PAN, Yijun
IPC分类号： G01N33/543
CPC分类号： C40B50/14 , B01J19/0046 , B01J20/289 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3219 , B01J20/3251 , B01J20/3257 , B01J31/10 , B01J31/1658 , B01J31/2208 , B01J31/2409 , B01J2219/00283 , B01J2219/00454 , B01J2219/00596 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00626 , B01J2219/00637 , B01J2219/00641 , B01J2219/0072 , B01J2219/00738 , B01J2231/4211 , B01J2231/4255 , B01J2231/4261 , B01J2231/4266 , B01J2531/824 , C07B2200/11 , C07C309/10 , C07C309/24 , C07C309/82 , C07C309/84 , C07F7/0834 , C40B60/14 , C40B80/00 , C40B99/00
摘要： Activated Supports, support-bound activators, strongly acidic supports, and silylating supports are provided; the activated support having the formula (I) wherein L is a linking group component; X is F, CL, OH, and trisubstituted silyloxy; and the shaded circle represents a solid or semi-solid support. Methods of using the activated supports in solid phase organic synthesis are also provided.

10. 发明公开

EP1916237A4 COMPOUND CONTAINING FLUOROSULFONYL GROUP, PROCESS FOR PRODUCING THE SAME, AND POLYMER THEREOF 有权转让
标题翻译： EINE FLUORSULFONYLGRUPPE ENTHALTENDE VERBINDUNG，VERFAHREN ZU DEREN HERSTELLUNG UND聚合物DAVON
公开(公告)号：EP1916237A4
公开(公告)日：2008-11-26
申请号：EP06781724
申请日：2006-07-26
申请人： ASAHI GLASS CO LTD
发明人： KANEKO ISAMU , WATAKABE ATSUSHI , TAYANAGI JYUNICHI , SAITO SUSUMU
IPC分类号： C07C303/02 , C07C303/22 , C07C309/82 , C08F214/18
CPC分类号： C07C303/22 , C07C309/82 , C07C309/84 , C08F214/18 , C08J5/2237 , C08J2327/18 , H01B1/122 , H01M2008/1095 , H01M2300/0082
摘要： A compound containing two fluorosulfonyl groups, which are groups convertible to sulfo groups; an intermediate therefor; and processes for producing these compounds with high productivity. Also provided are: a fluorosulfonylated polymer obtained by polymerizing the compound; and a sulfo-group-containing polymer obtained from that polymer. The compound is represented by the following formula (m0) (wherein RF01 represents a single bond or a C1-6 divalent perfluorinated organic group; RF02 represents a C1-6 divalent perfluorinated organic group; and n is 0 or 1).
摘要翻译：含有两个可转化为磺基的氟磺酰基的化合物; 为此的中间体; 以及以高生产率生产这些化合物的方法。还提供了：通过聚合化合物获得的氟磺酰化聚合物; 和由该聚合物得到的含磺基聚合物。该化合物由下式（m0）表示（其中RF01表示单键或C1-6二价全氟有机基团; RF02表示C1-6二价全氟有机基团;并且n为0或1）。

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