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    • 2. 发明公开
    • Alternative to tetrazene
    • 替代四氮
    • EP2733134A3
    • 2017-10-11
    • EP14154634.1
    • 2011-04-21
    • Pacific Scientific Energetic Materials Company
    • Fronabarger, John W.Williams, Michael D.
    • C06B43/00C06C7/00C07D257/06
    • C07D257/06C06B43/00C06C7/00
    • Embodiments of materials suitable for use as a replacement for Tetrazene and methods of preparing such materials are described. In one embodiment, the material comprises MTX-1, as well as simple salts or complexes derived therefrom. The methods of preparing such materials include combining Tetrazene and an acid to form suspension, where the acid is nitric acid, sulfuric acid, perchloric acid, or hydrochloric acid. A nitrite salt may be added to the suspension, where the nitrite salt is sodium nitrite, lithium nitrite, potassium nitrite, an aqueous solution of sodium nitrite, an aqueous solution of lithium nitrite, or an aqueous solution of potassium nitrite. In some embodiments, the suspension is stirred until the suspension has a white appearance.
    • 描述了适用于替代四氮的材料的实施方式以及制备这些材料的方法。 在一个实施方案中,该材料包含MTX-1以及由其衍生的简单盐或复合物。 制备这些材料的方法包括将四氮与酸结合形成悬浮液,其中酸为硝酸,硫酸,高氯酸或盐酸。 亚硝酸盐可以添加到悬浮液中,其中亚硝酸盐是亚硝酸钠,亚硝酸锂,亚硝酸钾,亚硝酸钠水溶液,亚硝酸锂水溶液或亚硝酸钾水溶液。 在一些实施方案中,搅拌悬浮液直至悬浮液具有白色外观。
    • 9. 发明公开
    • Novel energetic polyphosphazenes
    • 新能源聚磷腈
    • EP2460842A2
    • 2012-06-06
    • EP12001143.2
    • 2005-09-21
    • The Secretary of State For Defence
    • Golding, PeterTrussel, Stephen John
    • C08G79/02C06B45/10C06B49/00C06B43/00C06B25/00
    • C08G79/025C06B43/00C06B45/105C08L85/02
    • This invention describes the synthesis and use of novel energetic poly(phosphazene) materials suitable for binding high explosives, consisting of homopolymer compounds comprising n units of structure (iii):

      where R 2 = R 3 and are each alkyl, alkyl ether or carbohydrate based side chains which contain energetic functionalities including nitro, nitramine, nitrate ester, or azide, and 3 ≤ n ≤ 10000.
      These materials may also be used as explosives in their own right. The materials possess high energy density and are highly amenable to chemical modification thereby allowing for modification to the physical properties of the material. In particular the tacky and rubbery nature of these materials makes them ideal for shaping co-binder materials.
    • 本发明描述了适用于结合高爆炸物的新型能量聚(磷腈)材料的合成和使用,其由包含n个结构单元(iii)的均聚物化合物组成:其中R 2 = R 3并且各自为烷基,烷基醚或碳水化合物 含有硝基,硝胺,硝酸酯或叠氮等能量官能团的侧链,以及3‰¤‰‰10000。这些材料也可以作为炸药自己使用。 这些材料具有高能量密度,并且高度易于化学改性,从而允许改变材料的物理性能。 特别是这些材料的粘性和橡胶性质使其成为共粘合剂材料成型的理想选择。