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    • 4. 发明公开
    • HEAT RAY-ABSORBING GLASS PLATE AND METHOD FOR PRODUCING SAME
    • VERFAHREN ZUR HERSTELLUNG DAVON的WESRMESTRAHLENABSORBIERENDE GLASPLATTE
    • EP3141531A1
    • 2017-03-15
    • EP15790014.3
    • 2015-05-08
    • Asahi Glass Company, Limited
    • SHIMADA, YuyaARAI, Yusuke
    • C03C4/08C03C3/087
    • C03C3/087C03C3/095C03C4/08C03C4/082
    • To provide a heat-absorbing glass plate having a low solar transmittance, a high visible light transmittance and a low excitation purity, and a process for its production.
      A heat-absorbing glass plate containing iron, tin, selenium, cobalt and sulfur, wherein
      the mass ratio of divalent iron as calculated as Fe 2 O 3 to total iron as calculated as Fe 2 O 3 is at least 55%,
      the ratio Tv/Te of the visible light transmittance Tv (by illuminant A, 2° visual field) as defined in JIS R3106 (1998) calculated as 4 mm thickness of the glass plate to the solar transmittance Te as defined in JIS R3106 (1998) calculated as 4 mm thickness of the glass plate, is at least 1.5,
      the visible light transmittance Tv (by illuminant A, 2° visual field) is higher than 65% as defined in JIS R3106 (1998) calculated as 4 mm thickness of the glass plate, and
      the excitation purity Pe is at most 7% as defined in JIS Z8701 (1999) calculated as 4 mm thickness of the glass plate.
    • 提供一种具有低太阳透光率,高可见光透射率和低激发纯度的吸热玻璃板及其制造方法。 含有铁,锡,硒,钴和硫的吸热玻璃板,其中按Fe 2 O 3计算的二价铁的总铁与总铁的质量比计算为至少55%,比率Tv 按照JIS R3106(1998)中定义的JIS R3106(1998)中定义的可见光透射率Tv(通过光源A,2°视野)计算为玻璃板的4mm厚度与JIS R3106(1998)中定义的太阳能透射率Te计算为 4mm厚的玻璃板,至少为1.5,可见光透射率Tv(通过光源A,2°视野)高于JIS R3106(1998)中定义的65%,其计算为玻璃板的4mm厚度 ,并且按照JIS Z8701(1999)中定义的激发纯度Pe为至多7%,其计算为玻璃板的4mm厚度。
    • 5. 发明公开
    • GLASS COMPOSITION ABSORBING ULTRAVIOLET RAY AND INFRARED RAY AND APPLICATION THEREOF
    • 玻璃AM UNG UNG UR V V ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON ON
    • EP3070061A1
    • 2016-09-21
    • EP13897281.5
    • 2013-11-19
    • He, KaishengHu, YixiangHe, Haibo
    • YANG, QihanTAN, SixiHU, YangHU, Gan
    • C03C4/08C03C3/087
    • C03C3/118B32B17/10119C03C3/11C03C4/02C03C4/082C03C4/085G02B5/208G02B5/226
    • An ultraviolet ray and infrared ray-absorbing glass composition includes the following basic glass components (weight ratio): 60% to 75% of SiO 2 , 8% to 20 % of Na 2 O, 3% to 12% of CaO, 0.1% to 5% of Al 2 O 3 , 2% to 5% of MgO, 0.02% to 7% of K 2 O, 0.1% to 5% of BaO, 0.01% to 0.4% of SO 3 and the following ultraviolet ray and infrared ray-absorbing glass main body coloring and coordinating part: 0.22% to 1.35% of Fe 2 O 3 , 0.001% to 0.8% of ZrO 2 +HfO 2 , 0% to 0.5% of Cl, 0% to 2% of B 2 O 3 , 0.01% to 0.8% of TiO 2 , 0.001% to 0.06% of CuO, 0% to 2.0% of Br, 0% to 0.02% of MnO, 0% to 2.0% of F, 0.001% to 0.5% of SrO, and 0.005% to 2.2% of CeO 2 . The reduction oxidation ratio of Fe 2 O 3 in the glass composition is 0.4 to 0.8. A certain amount of rare metals and rare earth metal compounds are added to the glass composition, which breaks through various limitations of existing insulating glass, reasonably controls the Chemical Oxygen Demand (COD) in raw materials, controls reduction oxidation ratios, effectively blocking ultraviolet rays, infrared ray and sunlight total energy while improving the transmittance of visible light to obtain insulating glass capable of intensively absorbing ultraviolet rays and near infrared rays.
    • 紫外线和红外线吸收玻璃组合物包括以下碱性玻璃组分(重量比):60%至75%的SiO 2,8%至20%的Na 2 O,3%至12%的CaO,0.1% 至5%的Al 2 O 3,2%至5%的MgO,0.02%至7%的K 2 O,0.1%至5%的BaO,0.01%至0.4%的SO 3和以下的紫外线和红外 光吸收玻璃主体着色和配位部分:Fe 2 O 3为0.22〜1.35%,ZrO 2 + HfO 2为0.001〜0.8%,Cl为0〜0.5%,B 2为0〜2% O 3,TiO 2 0.01〜0.8%,CuO 0.001〜0.06%,Br 0〜2.0%,MnO 0〜0.02%,F:0〜2.0%,F:0.001〜0.5% SrO和0.005〜2.2%的CeO 2。 玻璃组合物中Fe 2 O 3的还原氧化率为0.4〜0.8。 玻璃组合物中加入了一定数量的稀有金属和稀土金属化合物,破坏了现有绝缘玻璃的各种局限性,合理控制了原料中的化学需氧量(COD),控制还原氧化比例,有效阻断了紫外线 ,红外线和太阳光的总能量,同时提高可见光的透射率,获得能够集中吸收紫外线和近红外线的绝缘玻璃。