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1. 发明授权

EP2950378B1 FUEL CELL SYSTEM 有权
公开(公告)号：EP2950378B1
公开(公告)日：2018-12-12
申请号：EP14742975.7
申请日：2014-01-14
申请人： Panasonic Intellectual Property Management Co., Ltd.
发明人： KOBAYASHI, Susumu , UKAI, Kunihiro , YAKUMARU, Yuuichi
IPC分类号： H01M8/06 , C01B3/38 , H01M8/04 , H01M8/12
CPC分类号： H01M8/0675 , C01B3/38 , C01B2203/066 , C01B2203/1047 , C01B2203/127 , C01B2203/16 , C01B2203/1614 , H01M8/04014 , H01M8/04022 , H01M8/04089 , H01M8/0432 , H01M8/04365 , H01M8/04373 , H01M8/04738 , H01M8/04753 , H01M8/04776 , H01M8/0618 , H01M8/2475 , H01M2008/1293 , H01M2250/20 , Y02E60/525 , Y02T90/32
摘要： A fuel cell system includes: a reformer (14) configured to generate a fuel gas from a raw material gas, reforming water, and air that are supplied to the reformer (14); an SOFC (11) configured to generate electric power through a power-generating reaction by utilizing the fuel gas and air; a combustor (17) configured to combust an anode off gas discharged from the SOFC (1); a hot module (10) housing the reformer (14), the SOFC (11), and the combustor (17), which are covered with a heat insulating material; and a hydrodesulfurizer (20) configured to remove a sulfur component from the raw material gas by hydrodesulfurization. The anode off gas is supplied to the combustor (17) and the hydrodesulfurizer (20) in a distributed manner. The hydrodesulfurizer (20) performs the hydrodesulfurization of the raw material gas by utilizing the anode off gas as a hydrogen source and utilizing an exhaust gas discharged from the hot module (10) as a heat source, the exhaust gas containing at least combustion heat from the combustor (17).

2. 发明公开

EP3118155A4 HYDROGEN PRODUCTION SYSTEM AND HYDROGEN PRODUCTION METHOD 有权
标题翻译： WASSERSTOFFHERSTELLUNGSSYSTEM UND WASSERSTOFFHERSTELLUNGSVERFAHREN
公开(公告)号：EP3118155A4
公开(公告)日：2017-08-30
申请号：EP15761874
申请日：2015-03-06
申请人： CHIYODA CORP
发明人： MIKURIYA TOMOYUKI , IMAGAWA KENICHI , KAWAI HIRONORI , NAKAJIMA YUSUKE , KANDA TAKENORI
IPC分类号： C01B3/26
CPC分类号： C01B3/26 , B01J7/00 , B01J8/0492 , C01B3/22 , C01B2203/0277 , C01B2203/0833 , C01B2203/1047 , C01B2203/1082 , C01B2203/1211 , C01B2203/1252 , C01B2203/142 , C01B2203/16 , C01B2203/1623
摘要： To allow hydrogen to be supplied to a dehydrogenation reaction unit for dehydrogenating an organic hydride by using a highly simple structure so that the activity of the dehydrogenation catalyst of the dehydrogenation reaction unit is prevented from being rapidly reduced. The hydrogen production system (1) comprises a first dehydrogenation reaction unit (3) for producing hydrogen by a dehydrogenation reaction of an organic hydride in presence of a first catalyst, and a second dehydrogenation reaction unit (4) for receiving a product of the first dehydrogenation reaction unit, and producing hydrogen by a dehydrogenation reaction of the organic hydride remaining in the product in presence of a second catalyst, wherein an amount of the first catalyst used in the first dehydrogenation reaction unit is equal to or less than an amount of the second catalyst used in the second dehydrogenation reaction unit, and an amount of hydrogen produced in the first dehydrogenation reaction unit is less than an amount of hydrogen produced in the second dehydrogenation reaction unit.
摘要翻译：为了通过使用非常简单的结构将氢供给脱氢反应单元以使有机氢化物脱氢，从而防止脱氢反应单元的脱氢催化剂的活性迅速降低。本发明的氢生成系统（1）具备：第一脱氢反应部（3），其在第一催化剂的存在下通过有机氢化物的脱氢反应来制造氢;以及第二脱氢反应部（4），其接收第一脱氢反应部以及在第二催化剂存在下通过产物中残留的有机氢化物的脱氢反应来生产氢气，其中第一脱氢反应单元中使用的第一催化剂的量等于或小于第二脱氢反应单元中使用的第二催化剂，并且第一脱氢反应单元中产生的氢的量小于第二脱氢反应单元中产生的氢的量。

3. 发明公开

EP3184488A1 HYDROGEN GENERATOR, METHOD FOR OPERATING SAME AND FUEL CELL SYSTEM 有权
标题翻译：氢发生器，其操作方法和燃料电池系统
公开(公告)号：EP3184488A1
公开(公告)日：2017-06-28
申请号：EP15834009.1
申请日：2015-08-19
申请人： Panasonic Intellectual Property Management Co., Ltd.
发明人： NARITA, Satoru , YASUDA, Shigeki , MIDORIKAWA, Yoichi , SHIMADA, Yasuaki , TAGUCHI, Kiyoshi , IIYAMA, Shigeru , ASO, Tomonori
IPC分类号： C01B3/38 , H01M8/04 , H01M8/06 , H01M8/10 , H01M8/12 , H01M8/0612
CPC分类号： C01B3/38 , C01B2203/0233 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/16 , C01B2203/1614 , C01B2203/1619 , C01B2203/1623 , C01B2203/169 , C01B2203/1695 , H01M8/0618 , H01M8/0668 , H01M2008/1095
摘要： Hydrogen generation apparatus (200) includes reformer (2), raw material gas supply device (3) that supplies a raw material gas to reformer (2), combustor (4), and combustion air supply device (9) that supplies combustion air to combustor (4). In addition, hydrogen generation apparatus (200) further includes raw material gas supply amount detector (5) that detects the amount of the raw material gas that is supplied to reformer (2), reforming temperature detector (6) that detects a temperature of reformer (2), and controller (7). Controller (7) sets a control parameter on the basis of a reforming temperature, which is detected by reforming temperature detector (6), in a case where raw material gas supply device (3) supplies the raw material gas so that the amount of the raw material gas supplied, which is detected by raw material gas supply amount detector (5), becomes a predetermined value, or on the basis of a temperature variation rate, which is detected by reforming temperature detector (6), when the temperature of reformer (2) rises due to heating by combustor (4).
摘要翻译：氢生成装置（200）具备：改性器（2）;向重整器（2）供给原料气体的原料气体供给装置（3）;燃烧器（4）;以及燃烧用空气供给装置（9）燃烧器（4）。另外，氢生成装置（200）还具备：检测向重整器（2）供给的原料气体量的原料气体供给量检测器（5）;检测重整器温度的重整温度检测器（6）（2）和控制器（7）。在原料气体供给装置（3）供给原料气体的情况下，控制器（7）基于由重整温度检测器（6）检测出的重整温度来设定控制参数，由原料气体供应量检测器（5）检测的供应的原料气体变成预定值，或者基于由重整温度检测器（6）检测到的温度变化率，当重整器温度（2）由于燃烧器（4）的加热而升高。

4. 发明公开

EP3184487A1 HYDROGEN GENERATOR, METHOD FOR OPERATING SAME AND FUEL CELL SYSTEM 审中-公开
标题翻译：氢发生器，其操作方法和燃料电池系统
公开(公告)号：EP3184487A1
公开(公告)日：2017-06-28
申请号：EP15832662.9
申请日：2015-08-19
申请人： Panasonic Intellectual Property Management Co., Ltd.
发明人： NARITA, Satoru , YASUDA, Shigeki , MIDORIKAWA, Yoichi , SHIMADA, Yasuaki , TAGUCHI, Kiyoshi , IIYAMA, Shigeru , ASO, Tomonori
IPC分类号： C01B3/38 , H01M8/04 , H01M8/06 , H01M8/10 , H01M8/12
CPC分类号： C01B3/38 , C01B2203/0233 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/16 , C01B2203/1614 , C01B2203/1619 , C01B2203/1623 , C01B2203/169 , C01B2203/1695 , H01M8/0618 , H01M8/0668 , H01M2008/1095
摘要： Provided is hydrogen generation apparatus (200) including reformer (31), raw material gas supply device (34) that supplies a raw material gas to reformer (31), and a combustor that heats reformer (31). Hydrogen generation apparatus (200) further includes combustion air supply device (36) that supplies combustion air to the combustor, a combustion state detector that detects a combustion state of the combustor, and controller (39) that performs control on the basis of a control parameter. Controller (39) is configured to set the control parameter on the basis of a value that is detected by the combustion state detector when changing a ratio of the amount of the combustion air that is supplied to the combustor by combustion air supply device (36) to the amount of the raw material gas that is supplied by raw material gas supply device (34) in a state in which the combustor heats reformer (31).
摘要翻译：本发明提供一种包含重整器31的氢生成装置200，向重整器31供给原料气体的原料气体供给装置34以及对重整器31进行加热的燃烧器。氢生成装置（200）还具备：向燃烧器供给燃烧用空气的燃烧用空气供给装置（36）;检测燃烧器的燃烧状态的燃烧状态检测器;以及基于控制进行控制的控制器（39）参数。控制器（39）构成为，基于由燃烧空气供给装置（36）向燃烧器供给的燃烧用空气的量的比例变更时由燃烧状态检测器检测出的值来设定控制参数，与在燃烧器加热重整器（31）的状态下由原料气体供给装置（34）供给的原料气体的量。

5. 发明公开

EP2433904A4 HYDROGEN GENERATION DEVICE AND FUEL CELL SYSTEM 审中-公开
标题翻译：设备技术制氢和燃料电池系统
公开(公告)号：EP2433904A4
公开(公告)日：2014-01-15
申请号：EP10777555
申请日：2010-05-18
申请人： PANASONIC CORP
发明人： NAKAMURA AKINARI , URATA TAKAYUKI , OHARA HIDEO
IPC分类号： C01B3/38 , H01M8/06 , H01M8/10
CPC分类号： H01M8/0618 , C01B3/38 , C01B3/382 , C01B2203/0233 , C01B2203/0283 , C01B2203/044 , C01B2203/0445 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0894 , C01B2203/1058 , C01B2203/1076 , C01B2203/1082 , C01B2203/1235 , C01B2203/1241 , C01B2203/1288 , C01B2203/16 , C01B2203/1695 , H01M8/0631 , H01M2008/1095 , Y02E60/50 , Y02P20/128
摘要： A hydrogen generator of the present invention comprises a reformer (1) including a reforming catalyst (1A) which allows a hydrogen-containing gas to be generated using a raw material and steam; a water evaporator (3) for generating the steam; a raw material supply passage (2) which supplies the raw material to the reforming catalyst (1A) of the reformer (1); a steam supply passage (4) which supplies the steam generated in the water evaporator (3) to the reforming catalyst (1A) of the reformer (1); a pressure releasing device (6) provided at the raw material supply passage (2) or the steam supply passage (4); an exhaust passage (7) which flows a gas exhausted from the pressure releasing device (6) and containing the steam; and a cooler (8) provided at the exhaust passage and configured to cool the gas.

6. 发明公开

EP2211413A4 FUEL CELL POWER GENERATION SYSTEM, AND METHOD FOR OPERATING FUEL CELL POWER GENERATION SYSTEM 有权转让
标题翻译：燃料电池电流生成系统和操作燃料电池电流生成系统的方法
公开(公告)号：EP2211413A4
公开(公告)日：2013-05-01
申请号：EP09758126
申请日：2009-06-04
申请人： PANASONIC CORP
发明人： UKAI KUNIHIRO , KANI YUKIMUNE , KANEKO HIROAKI
IPC分类号： H01M8/06 , C01B3/38 , H01M8/04
CPC分类号： H01M8/0618 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/1258 , C01B2203/16 , H01M8/04089 , H01M8/04425 , H01M8/04619 , H01M8/04753 , H01M8/04776 , H01M8/0662 , Y02E60/50

7. 发明公开

EP1510683A3 Method and apparatus for determining state of reformer 有权
标题翻译：用于确定重整器的状态的方法和装置
公开(公告)号：EP1510683A3
公开(公告)日：2012-01-18
申请号：EP04020321.8
申请日：2004-08-26
申请人： Toyota Jidosha Kabushiki Kaisha
发明人： Wakao, Kazuhiro , Sakurai, Kazuhiro
IPC分类号： F02M25/00 , F02M27/02 , F02M25/10 , C01B3/38 , C01B3/40 , F02M25/12
CPC分类号： F02M25/12 , C01B3/38 , C01B2203/0261 , C01B2203/06 , C01B2203/16 , C01B2203/84 , F02D2200/1012 , F02M27/02 , Y02T10/121
摘要： An internal combustion engine (1) includes a reformer (20) for reforming a fuel air mixture to produce a reformed gas, a crank angle sensor (19) for detecting a rotational speed of the engine (1), and an ECU (50). The ECU (50) obtains a difference of an actual rotational speed from a target rotational speed of the engine (1) during an idling thereof based on a signal from the crank angle sensor (19). When the difference thus obtained exceeds a predetermined threshold value, the ECU (50) determines that a reforming catalyst of the reformer (20) has deteriorated or there is any abnormality in the reformer (20).

8. 发明公开

EP2350748A1 OPTIMIZING REFINERY HYDROGEN GAS SUPPLY, DISTRIBUTION AND CONSUMPTION IN REAL TIME 审中-公开
标题翻译：优化氢气供应，分配和消费精炼厂实时地
公开(公告)号：EP2350748A1
公开(公告)日：2011-08-03
申请号：EP09819586.0
申请日：2009-10-09
申请人： ExxonMobil Research and Engineering Company
发明人： GURCIULLO, Christopher, S. , ANDREI, Marco, A. , BARRETT-PAYTON, Dave , GEORGIOU, Apostolos, T.
IPC分类号： G05B15/00
CPC分类号： G05B17/02 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/0445 , C01B2203/063 , C01B2203/065 , C01B2203/16 , Y02E60/324
摘要： The present invention is directed to innovative and unique mathematical models that capture key constraints, process kinetics and control structures such that a wide envelope of hydrogen gas and associated light gas supply, distribution and use can be modeled. The present invention is also directed to a real time optimization (RTO) computer application for effective optimization of hydrogen and associated light gas supply and distribution and, thereby, consumption, in a refinery that employs said models and solves an objective function, as well as to a method and refinery using the same. The objective function can be an economic objective function such as the minimization of cost for hydrogen supply and distribution or the maximization of profit based on a valuation of products made by hydrogen consumers in the hydrogen system minus the corresponding cost of the hydrogen supply and distribution.

9. 发明公开

EP2211413A1 FUEL CELL POWER GENERATION SYSTEM, AND METHOD FOR OPERATING FUEL CELL POWER GENERATION SYSTEM 有权转让
标题翻译： BRENNSTOFFZELLENSTROMERZEUGUNGSSYSTEM UND VERFAHREN ZUM BETRIEB DES BRENNSTOFFZELLENSTROMERZEUGUNGSSYSTEMS
公开(公告)号：EP2211413A1
公开(公告)日：2010-07-28
申请号：EP09758126.8
申请日：2009-06-04
申请人： Panasonic Corporation
发明人： UKAI, Kunihiro , KANI, Yukimune , KANEKO, Hiroaki
IPC分类号： H01M8/06 , C01B3/38 , H01M8/04
CPC分类号： H01M8/0618 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/1258 , C01B2203/16 , H01M8/04089 , H01M8/04425 , H01M8/04619 , H01M8/04753 , H01M8/04776 , H01M8/0662 , Y02E60/50
摘要： A fuel cell power generation system 100 for performing power generation using hydrogen-containing gas generated from a raw material containing a hydrocarbon component and an odorizer component includes a raw material supply section 4 for controlling a flow rate of the raw material; a water supply section 3 for supplying water; an adsorptive removal section 5 for causing the raw material to pass therethrough and adsorbing the odorizer component contained in the raw material; a reformer 1 for generating the hydrogen-containing gas by a reforming reaction of the raw material which has passed the adsorptive removal section and water supplied from the water supply section; a fuel cell 8 for performing power generation using the hydrogen-containing gas as a fuel; and an operating control section for, as an accumulated flow volume of the raw material supplied to the adsorptive removal section 5 from the raw material supply section 4 increases, decreasing the flow rate of the raw material to be supplied to the adsorptive removal section 5 from the raw material supply section 4, the flow rate being set with respect to an amount of power to be generated by the fuel cell 8.
摘要翻译：使用由含有烃成分的原料产生的含氢气体进行发电的燃料电池发电系统100和加臭剂成分包括：原料供给部4，其控制原料的流量; 用于供水的供水部3; 用于使原料通过并吸附原料中所含的加味剂成分的吸附除去部5; 用于通过已经通过吸附除去部分的原料与从供水部分供应的水的重整反应产生含氢气体的重整器1; 用于使用含氢气体作为燃料进行发电的燃料电池8; 以及操作控制部，作为从原料供给部4供给到吸附除去部5的原料的累积流量增加，将供给到吸附除去部5的原料的流量从原料供给部4相对于由燃料电池8产生的动力量设定流量。

10. 发明公开

EP1949477A2 IMPROVED REFORMING CATALYST AND METHOD AND APPARATUS FOR MAKING AND LOADING SAME 审中-公开
标题翻译：具有改进的重整和为生产和充电方法及装置催化剂
公开(公告)号：EP1949477A2
公开(公告)日：2008-07-30
申请号：EP06837177.2
申请日：2006-11-10
申请人： Fuelcell Energy, Inc.
发明人： KATIKANENI, Sai, P. , CORREA, Salvador E. , GLADKE, Edward H.
IPC分类号： H01M4/86
CPC分类号： H01M8/0637 , B01J23/755 , B01J35/026 , B01J35/04 , B01J35/1061 , B01J37/0009 , B01J37/344 , C01B3/40 , C01B2203/0233 , C01B2203/067 , C01B2203/1058 , C01B2203/1241 , C01B2203/16 , H01M4/8885 , H01M8/0254 , H01M8/0289 , H01M2008/147 , Y02E60/526 , Y02E60/566 , Y02P20/52 , Y02P70/56 , Y10T156/1039
摘要： A reforming catalyst member having an elongated body whose outer surface has a number of peak and valley regions so as to increase the area of the outer surface to enhance catalyst utilization.

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