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1. 发明公开

EP1829822A2 Hydrogen production process with regenerant recycle 有权
标题翻译： Verfahren zur Wasserstoffherstellung mit Regenerationsmittel-Recycling
公开(公告)号：EP1829822A2
公开(公告)日：2007-09-05
申请号：EP07001017.8
申请日：2007-01-18
申请人： Air Products and Chemicals, Inc.
发明人： Peng, Xiang-Dong , Nataraj, Shankar
IPC分类号： C01B3/38 , C01B3/46
CPC分类号： C01B3/38 , B01D53/047 , B01D2253/1124 , B01D2256/16 , B01D2257/30 , B01D2257/302 , B01D2257/502 , B01D2257/504 , B01D2259/40007 , B01D2259/40052 , B01D2259/40056 , B01D2259/404 , C01B3/46 , C01B2203/0233 , C01B2203/0425 , C01B2203/043 , C01B2203/0475 , C01B2203/0485 , C01B2203/0827 , C01B2203/0833 , C01B2203/10 , C01B2203/148 , Y02C10/08 , Y02P20/152
摘要： The present invention relates to a process for producing a hydrogen-containing gas. The process comprises introducing a regeneration gas into a hydrogen reaction vessel containing solid packing material thereby at least partially regenerating the solid packing material and forming an effluent gas from the regeneration gas. At least a portion of the effluent gas is introduced into another hydrogen reaction vessel containing solid packing material. The effluent gas may be used, for example, to purge the other hydrogen reaction vessel and/or regenerate the solid packing material in the other hydrogen reaction vessel. Solid packing materials may include at least one of a complex metal oxide, a steam hydrocarbon reforming catalyst, an oxygen ion conducting ceramic, a hydrocarbon partial oxidation catalyst, and a hydrocarbon cracking catalyst.
摘要翻译：本发明涉及含氢气体的制造方法。该方法包括将再生气体引入含有固体包装材料的氢反应容器中，从而至少部分地再生固体包装材料并形成来自再生气体的流出气体。将至少一部分废气引入含有固体包装材料的另一氢反应容器中。可以使用流出气体例如吹扫另一个氢反应容器和/或再生另一个氢反应容器中的固体填充材料。固体包装材料可以包括复合金属氧化物，蒸汽烃重整催化剂，氧离子导电陶瓷，烃部分氧化催化剂和烃裂化催化剂中的至少一种。

2. 发明授权

EP1942537B1 Brennstoffzellensystem mit einer Regenerationseinrichtung für einen Reformer und zugehöriges Verfahren 有权
标题翻译：与再生装置的燃料电池系统用于重整器和相关联的方法
公开(公告)号：EP1942537B1
公开(公告)日：2016-01-27
申请号：EP07121731.9
申请日：2007-11-28
申请人： Eberspächer Climate Control Systems GmbH & Co. KG
发明人： Reiners, Karsten
IPC分类号： H01M8/00 , H01M8/06 , C01B3/36
CPC分类号： H01M8/0618 , C01B3/386 , C01B2203/0261 , C01B2203/066 , C01B2203/10 , H01M2250/20 , Y02T90/32

3. 发明公开

EP1829822A3 Hydrogen production process with regenerant recycle 有权
标题翻译：一种用于制氢与再生剂循环方法
公开(公告)号：EP1829822A3
公开(公告)日：2008-02-27
申请号：EP07001017.8
申请日：2007-01-18
申请人： Air Products and Chemicals, Inc.
发明人： Peng, Xiang-Dong , Nataraj, Shankar
IPC分类号： C01B3/38 , C01B3/46
CPC分类号： C01B3/38 , B01D53/047 , B01D2253/1124 , B01D2256/16 , B01D2257/30 , B01D2257/302 , B01D2257/502 , B01D2257/504 , B01D2259/40007 , B01D2259/40052 , B01D2259/40056 , B01D2259/404 , C01B3/46 , C01B2203/0233 , C01B2203/0425 , C01B2203/043 , C01B2203/0475 , C01B2203/0485 , C01B2203/0827 , C01B2203/0833 , C01B2203/10 , C01B2203/148 , Y02C10/08 , Y02P20/152
摘要： The present invention relates to a process for producing a hydrogen-containing gas. The process comprises introducing a regeneration gas into a hydrogen reaction vessel containing solid packing material thereby at least partially regenerating the solid packing material and forming an effluent gas from the regeneration gas. At least a portion of the effluent gas is introduced into another hydrogen reaction vessel containing solid packing material. The effluent gas may be used, for example, to purge the other hydrogen reaction vessel and/or regenerate the solid packing material in the other hydrogen reaction vessel. Solid packing materials may include at least one of a complex metal oxide, a steam hydrocarbon reforming catalyst, an oxygen ion conducting ceramic, a hydrocarbon partial oxidation catalyst, and a hydrocarbon cracking catalyst.

4. 发明授权

EP2441731B1 In-situ coke removal in a catalytic partial oxidation process 有权
标题翻译：在催化部分氧化过程中原位除焦
公开(公告)号：EP2441731B1
公开(公告)日：2014-05-14
申请号：EP11181361.4
申请日：2011-09-15
申请人： Honda Motor Co., Ltd. , Precision Combustion, Inc.
发明人： Roychoudhury, Subir , Mastanduno, Richard , Spence, David , Iwamoto, Jun , Motohashi, Go
IPC分类号： C01B3/38
CPC分类号： C01B3/386 , C01B2203/0261 , C01B2203/10 , C01B2203/1205 , C01B2203/169

5. 发明公开

EP1942537A1 Brennstoffzellensystem mit einer Regenerationseinrichtung für einen Reformer und zugehöriges Verfahren 有权
标题翻译： Brennstoffzellensystem mit einer Regenerationseinrichtungfüreinen Reformer undzugehörigesVerfahren
公开(公告)号：EP1942537A1
公开(公告)日：2008-07-09
申请号：EP07121731.9
申请日：2007-11-28
申请人： J. Eberspächer GmbH & Co. KG
发明人： Reiners, Karsten
IPC分类号： H01M8/00 , H01M8/06 , C01B3/36
CPC分类号： H01M8/0618 , C01B3/386 , C01B2203/0261 , C01B2203/066 , C01B2203/10 , H01M2250/20 , Y02T90/32
摘要： Die vorliegende Erfindung betrifft ein Brennstoffzellensystem (1), insbesondere in einem Kraftfahrzeug, umfassend einen Reformer (2) zum Generieren eines Wasserstoffgas enthaltenden Anodengases aus einem Wasserstoff enthaltenden Brennstoff und einem Sauerstoff enthaltenden Oxidator sowie eine Brennstoffzelle (3) zum Generieren von elektrischem Strom aus den Anodengas und einem Sauerstoffgas enthaltenden Kathodengas.
Um den Wirkungsgrad des Reformers (2) bzw. des Brennstoffzellensystems (1) zu erhöhen, kann eine Regenerationseinrichtung (25) zum Fördern eines Sauerstoffgas enthaltenden Oxidatorgases durch den Reformer (2) entgegen einer während eines Normalbetriebs zum Generieren des Anodengases und/oder des Stroms vorliegenden Strömungsrichtung (30) vorgesehen sein.
摘要翻译：该方法包括使用重整器（2）从燃料产生阳极气体，其中燃料含有氢。使用燃料电池（3）从阳极气体和阴极气体产生电流，其中阴极气体含有氧气。包含氧气的氧化剂通过重整器相对于流动方向（30）输送，其中存在用于在正常操作期间产生阳极气体和/或电流的流动方向，并且在再生操作期间再生重整器。

6. 发明授权

EP3023387B1 LIGHT-CATALYZED REACTION SYSTEM BY COLLECTING SUNLIGHT 有权
公开(公告)号：EP3023387B1
公开(公告)日：2018-08-08
申请号：EP14825810.6
申请日：2014-06-17
申请人： Zhongying Changjiang International New Energy Investment Co., Ltd
发明人： CHEN, Yilong , YANG, Qingping , ZHANG, Yanfeng
IPC分类号： C01B3/04 , C07C31/04 , F03G6/06 , F24J2/38 , B01J19/12 , C01B3/22 , C01B13/02 , F24J2/06 , F24J2/08 , F24J2/16 , F24J2/18
CPC分类号： B01J19/127 , B01J2219/0801 , B01J2219/0871 , B01J2219/0875 , B01J2219/1203 , C01B3/042 , C01B3/22 , C01B13/0207 , C01B2203/0277 , C01B2203/10 , C01B2203/1223 , F03G6/06 , F24S23/12 , F24S23/30 , F24S23/77 , F24S23/79 , Y02E10/46 , Y02E60/364 , Y02P20/134
摘要： A light-catalyzed reaction system by collecting sunlight mainly comprises a light collector, a light conduction device, and a light transmitting reactor capable of transmitting full-spectrum rays of sunlight. The light collector is fixed at the free end of a two-degree-of-freedom bracket formed by connecting a pitching main shaft to an orientation main shaft, and the orientation main shaft and the pitching main shaft can be driven respectively by separate servo motors to relatively rotate to track the sun. Multiple layers of light-collection convex lens groups are disposed on the light collector, and converging rays formed by transmission and convergence of collected sunlight through the light conduction device are directed to the light transmitting reactor. The light transmitting reactor comprises a light transmitting cylinder and a sealing cover. The sealing cover is arranged on the light transmitting cylinder, and the light transmitting cylinder is filled with a reaction solution. The system is applied to processes of light-catalyzed hydrogen production and light-catalyzed methyl alcohol and oxygen production.

7. 发明公开

EP2441731A1 In-situ coke removal in a catalytic partial oxidation process 有权
标题翻译：在催化部分氧化过程中原位除焦
公开(公告)号：EP2441731A1
公开(公告)日：2012-04-18
申请号：EP11181361.4
申请日：2011-09-15
申请人： Honda Motor Co., Ltd. , Precision Combustion, Inc.
发明人： Roychoudhury, Subir , Mastanduno, Richard , Spence, David , Iwamoto, Jun , Motohashi, Go
IPC分类号： C01B3/38
CPC分类号： C01B3/386 , C01B2203/0261 , C01B2203/10 , C01B2203/1205 , C01B2203/169
摘要： A process of catalytic partial oxidation of a hydrocarbon fuel, such as diesel, with an oxidant, such as air, to produce a partially-oxidized reaction product, such as a hydrogen-containing fuel gas, with simultaneous in-situ coke removal. The process involves feeding a hydrocarbon fuel and an oxidant to a reactor in a fuel-rich feed ratio; reacting the fuel and oxidant for a fuel-rich cycle-time so as to produce a partially-oxidized reaction product; varying the fuel feed, or the oxidant feed, or both feeds to produce a fuel-lean feed to the reactor; maintaining the fuel-lean feed for a fuel-lean cycle-time sufficient to reduce coke deposits while maintaining a substantially constant yield of partially-oxidized reaction product; and alternating between the fuel-rich and fuel-lean operating cycles.
摘要翻译：用诸如空气之类的氧化剂将烃燃料如柴油催化部分氧化以产生部分氧化的反应产物如含氢燃料气体同时就地除焦的过程。该方法涉及以富含燃料的进料比将烃燃料和氧化剂供给反应器; 使燃料和氧化剂反应富燃料循环时间以产生部分氧化的反应产物; 改变燃料进料或氧化剂进料或两种进料以产生到反应器的贫燃料进料; 将所述贫燃料进料维持足够的贫燃料循环时间以减少焦炭沉积，同时保持部分氧化的反应产物的基本恒定产率; 并且在富燃料和贫燃料操作循环之间交替。

8. 发明公开

EP1462170A1 Gas-phase chemical reactions using a molten metal catalyst 审中-公开
标题翻译： Chemische Reaktionen in der Gasphase unter Verwendung von geschmolzenem Metall als Katalysator
公开(公告)号：EP1462170A1
公开(公告)日：2004-09-29
申请号：EP03251984.5
申请日：2003-03-28
申请人： EUROPEAN COMMUNITY
发明人： Edwards, Robert Arthur Henry , Burghartz, Stephan Maurice Marco Boris
IPC分类号： B01J35/12 , B01J23/14 , C01B3/32 , C01B3/40 , B01J10/00 , B01J19/26 , B01J19/10
CPC分类号： B01J4/002 , B01B1/005 , B01J19/10 , B01J19/26 , B01J23/14 , B01J35/12 , B01J2219/00087 , C01B3/16 , C01B3/326 , C01B3/386 , C01B3/40 , C01B2203/00 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/10 , C01B2203/1041 , C01B2203/1088 , C01B2203/1211 , C01B2203/1229 , C01B2203/1288 , Y02P20/52
摘要： A process involving a gas- or vapour-phase chemical reaction, wherein a molten or liquid metal is used to catalyse the reaction. The chemical reaction may involve the transfer of a chemical species selected from oxygen, sulphur, phosphorous, nitrogen and a halogen from the first reactant to the second reactant. The reaction may be a steam-reforming reaction, a water-gas-shift reaction, or an oxidation or partial-oxidation reaction.
摘要翻译：涉及气相或气相化学反应的方法，其中使用熔融或液态金属催化反应。化学反应可能涉及从第一反应物向第二反应物转移选自氧，硫，磷，氮和卤素的化学物质。反应可以是蒸汽重整反应，水煤气变换反应或氧化或部分氧化反应。

9. 发明公开

EP1413548A1 Regeneration of partial oxidation catalysts 审中-公开
标题翻译： Regenerierung von Teiloxidationskatalysatoren
公开(公告)号：EP1413548A1
公开(公告)日：2004-04-28
申请号：EP03256715.8
申请日：2003-10-23
申请人： ConocoPhillips Company
发明人： Cnossen, Robin G. , Carmichael, Lisa M.
IPC分类号： C01B3/38 , C01B3/40 , B01J38/04 , B01J23/96
CPC分类号： C01B3/386 , B01J23/90 , B01J23/96 , B01J38/04 , B01J2219/00006 , C01B3/40 , C01B2203/0261 , C01B2203/062 , C01B2203/10 , Y02P20/125 , Y02P20/52 , Y02P20/584
摘要： The present invention relates to a process for the preparation of synthesis gas (i.e., a mixture of carbon monoxide and hydrogen), typically labeled syngas. More particularly, the present invention relates to a regeneration method for a syngas catalyst. Still more particularly, the present invention relates to the regeneration of syngas catalysts using a re-dispersion technique. The re-dispersion technique involves the formation and removal of carbonyls with the active metals. The carbonyl formation and removal effectively re-disperses the catalyst metal.
摘要翻译：再生失活的部分氧化催化剂（a1）的方法（M1）包括：（a）在（a1）存在下使烃和含氧气体反应，以产生包含至少一种氢氧化物的氢和一氧化碳的产物（P1）第一反应器（R1）; 和（b）使至少部分失活的（a1）与至少一个再生气体在至少第二反应器（R2）中反应。（R1）和（R2）包含在一个整合的过程中。独立权利要求包括以下内容：（1）合成气生产的连续操作过程（P1）：（a）在含金属的合成气催化剂（a2）存在下使烃和含氧气体反应，生成（ P1）; 和（b）间歇地，当（a2）已经变得至少部分失活时，通过化学重新分散催化金属来原位再生失活的（a2），包括将去活化的合成气催化剂暴露于再分散气体一段时间重新分散催化金属; 和（2）用于最佳生产合成气的连续操作过程，其中反应器以优化的方式操作，使得：（a）一段时间t1，反应器被供给包含烃和氧的气体，并且在存在下的催化剂在压力> =至少两倍的环境压力下产生包含合成气的产物; 和（b）一段时间t2，使用再生气体再生反应器中的催化剂。 t1 => =两次t2，t1 => 24小时。

10. 发明公开

EP3023387A4 LIGHT-CATALYZED REACTION SYSTEM BY COLLECTING SUNLIGHT 审中-公开
标题翻译： DURCH SAMMELN VON SONNENLICHT LICHTKATALYSIERTES REAKTIONSSYSTEM
公开(公告)号：EP3023387A4
公开(公告)日：2017-01-04
申请号：EP14825810
申请日：2014-06-17
申请人： ZHONGYING CHANGJIANG INT NEW ENERGY INVEST CO LTD
发明人： CHEN YILONG , YANG QINGPING , ZHANG YANFENG
IPC分类号： C01B3/04 , B01J19/12 , C01B3/22 , C01B13/02 , C07C31/04 , F03G6/06 , F24S23/00 , F24S23/30 , F24S23/77 , F24S23/79 , F24S50/20
CPC分类号： B01J19/127 , B01J2219/0801 , B01J2219/0871 , B01J2219/0875 , B01J2219/1203 , C01B3/042 , C01B3/22 , C01B13/0207 , C01B2203/0277 , C01B2203/10 , C01B2203/1223 , F03G6/06 , F24J2/067 , F24J2/08 , F24J2/16 , F24J2/18 , Y02E10/46 , Y02E60/364 , Y02P20/134
摘要： A light-catalyzed reaction system by collecting sunlight mainly comprises a light collector, a light conduction device, and a light transmitting reactor capable of transmitting full-spectrum rays of sunlight. The light collector is fixed at the free end of a two-degree-of-freedom bracket formed by connecting a pitching main shaft to an orientation main shaft, and the orientation main shaft and the pitching main shaft can be driven respectively by separate servo motors to relatively rotate to track the sun. Multiple layers of light-collection convex lens groups are disposed on the light collector, and converging rays formed by transmission and convergence of collected sunlight through the light conduction device are directed to the light transmitting reactor. The light transmitting reactor comprises a light transmitting cylinder and a sealing cover. The sealing cover is arranged on the light transmitting cylinder, and the light transmitting cylinder is filled with a reaction solution. The system is applied to processes of light-catalyzed hydrogen production and light-catalyzed methyl alcohol and oxygen production.
摘要翻译：通过收集阳光的光催化反应系统主要包括光收集器，光传导装置和能够透射全光谱的太阳光的透光反应器。集光器固定在通过将俯仰主轴连接到定向主轴而形成的两自由度支架的自由端上，并且可以通过分开的伺服电动机驱动定向主轴和俯仰主轴相对旋转以跟踪太阳。在集光器上设置多层收光凸透镜组，并且通过透光装置将收集的太阳光的透射和会聚而形成的会聚的光线导向光透射反应器。透光反应器包括透光圆筒和密封盖。密封盖布置在透光圆柱体上，并且透光圆柱体填充有反应溶液。该系统应用于轻催化氢生产和轻催化甲醇和氧气生产的工艺。

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