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    • 4. 发明公开
    • Air separation by pressure swing adsorption with a high capacity carbon molecular sieve
    • 使用分子筛具有高容量通过变压吸附空气分离。
    • EP0554805A1
    • 1993-08-11
    • EP93101437.7
    • 1993-01-29
    • AIR PRODUCTS AND CHEMICALS, INC.
    • Auvil, Steven RaySchork, Joan MarieSrinivasan, Rajagopalan Sree
    • C01B21/04
    • B01D53/02B01D53/047B01D2253/102B01D2253/302B01D2253/308B01D2256/10B01D2257/104B01D2259/402B01J20/20C01B21/0461C01B32/306Y10S95/903
    • Nitrogen is produced by separating air in a pressure swing adsorption process using a high capacity kinetically O₂ selective material as the adsorbent. An example of such an adsorbent is a carbon molecular sieve made from coconut shell char. Such a coconut shell char having a high oxygen volumetric capacity is provided by crushing and sizing coconut shells to form granules which are then heated in flowing inert gas at a temperature ramp rate of about 2 to 12°C per minute to a peak temperature of 775 to 900°C which is then held so that the total heating time is up to 8 hours and thereafter the granular char is cooled in an inert gas atmosphere. The granular char thus produced is kinetically selective for O₂ over N₂ without further modification to narrow the openings of its micropores and has an oxygen volumetric capacity in excess of 8.0 cc/cc at 1 atm. and ambient temperature. Further modification of this char is provided by contacting it with an oxidizing atmosphere of carbon dioxide or a mixture of inert gas and carbon dioxide, H₂O or O₂ at temperatures ranging from 650 to 900°C until the gasified char has been altered so that its volumetric oxygen capacity is greater than 9.0 cc/cc at 1 atm. and ambient temperature.
    • 氮是通过使用大容量动力学O2选择性材料作为吸附剂的变压吸附方法分离空气生产的。 寻求吸附剂的一个例子是从椰子壳炭制成的碳分子筛。 具有高的氧体积容量这样的椰子壳炭通过破碎和筛分椰子壳以形成颗粒然后将其在以每分钟约2℃至12℃的升温速率至峰值温度的775流动的惰性气体加热提供 至900℃的所有然后保持如此做了总的加热时间为1〜8小时,其后的粒状炭在惰性气体气氛中冷却英寸 由此制得的粒状炭为O2 N2以上动力学选择性没有进一步修改,以缩小其微孔的开口,并且具有超过8.0立方厘米/立方厘米的氧气体积容量大气压在第一 和环境温度。 这种炭的进一步修饰是通过与接触它在氧化的二氧化碳的气氛中或惰性气体和二氧化碳,H 2 O或O 2在温度范围从650至900℃的混合物中提供,直到气化炭已经改变所以没有它的体积 氧容量大于9.0立方厘米/立方厘米在1个大气压。 和环境温度。