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1. 发明公开

EP2322300A1 REFRACTORY FOR NOZZLE USED IN CONTINUOUS CASTING AND NOZZLE FOR CONTINUOUS CASTING 有权转让
标题翻译：用于连续铸造的连续喷嘴喷嘴用于连续铸造的耐火材料
公开(公告)号：EP2322300A1
公开(公告)日：2011-05-18
申请号：EP09802929.1
申请日：2009-07-27
申请人： Krosakiharima Corporation , Nippon Steel Corporation
发明人： MORIKAWA, Katsumi , SASAKI, Akinari , HIRAIWA, Yoshitaka , NEBA, Keiichiro , SADANO, Takashi , FUKUNAGA, Shinichi , TANAKA, Kazuhisa
IPC分类号： B22D11/10 , B22D41/50
CPC分类号： B22D41/54 , C03C11/002 , C04B35/013 , C04B35/0435 , C04B35/057 , C04B35/18 , C04B35/66 , C04B2235/3201 , C04B2235/3206 , C04B2235/3208 , C04B2235/3418 , C04B2235/36 , C04B2235/401 , C04B2235/402 , C04B2235/425 , C04B2235/5436
摘要： In a insert-type continuous casting nozzle comprising a highly functional layer formed to have a high corrosion resistance, a high anti-attachment capability, etc., and provided to defme an inner bore thereof, the present invention is directed to providing a refractory material (mortar) for an intermediate layer of the continuous casting nozzle, which has a property capable of fixing an inner bore-side layer to an outer periphery-side layer (a nozzle body) of the continuous casting nozzle, while preventing the occurrence of expansion splitting in the outer periphery-side layer due to a difference in thermal expansion between the inner bore-side and outer periphery-side layers, and a continuous casting nozzle using the refractory material for the intermediate layer. The refractory material for the intermediate layer contains a hollow refractory aggregate in an amount of 10 to 75 volume%, wherein a ratio of an average radius R of each particle of the aggregate to an average wall thickness t of the particle satisfies the following relation: R/t ≥ 10. This refractory material is disposed between an inner bore-side layer (2) and an outer periphery-side layer (3, 4) of a continuous casting nozzle.
摘要翻译：本发明涉及一种嵌入式连续铸造用喷嘴，其具有形成为具有高耐腐蚀性，高耐附着性等的高功能层，并用于限定其内孔，本发明的目的在于提供耐火材料（砂浆），其具有能够将内孔侧层固定到连续铸造用喷嘴的外周侧层（喷嘴体）的性质，同时防止发生膨胀由于内孔侧和外周侧层之间的热膨胀差异而在外周侧层中分裂，以及使用耐火材料作为中间层的连续铸造喷嘴。用于中间层的耐火材料包含10至75体积％的空心耐火骨料，其中骨料的每个颗粒的平均半径R与颗粒的平均壁厚t之比满足下列关系： R /t≥10。该耐火材料设置在连续铸造用喷嘴的内孔侧层（2）和外周侧层（3,4）之间。

2. 发明授权

EP1504831B1 METHOD FOR CONTINUOUS CASTING OF ALUMINUM KILLED STEEL 有权
标题翻译：连续铸轧工艺铝镇静钢
公开(公告)号：EP1504831B1
公开(公告)日：2009-04-01
申请号：EP03721000.2
申请日：2003-04-30
申请人： Krosakiharima Corporation , LWB Refractories Company
发明人： Ogata, Koji, KROSAKIHARIMA CORPORATION , Shimizu, Koichi, KROSAKIHARIMA CORPORATION , Asano, Keisuke, KROSAKIHARIMA CORPORATION , Hokii, Toshiyuki, KROSAKIHARIMA CORPORATION , Yoshitomi, Joki, KROSAKIHARIMA CORPORATION
IPC分类号： B22D41/50 , C04B35/03 , B22D41/54
CPC分类号： B22D41/54
摘要： A nozzle system for continuous casting of an aluminum killed steel wherein 50 % or more of the total area of inner surfaces of all the nozzles for continuous casting being used for injecting a molten steel from a tundish to a mold is formed by a refractory containing CaO in an amount of 20 mass % or more. In the application of a material containing CaO to a nozzle for casting an aluminum killed steel, the amount of alumina inclusions of a large size formed in a cast piece has been found to correlate well with the total area of the inner surface of nozzles used and the CaO content of the refractory applied to the surface, and the above nozzle system allows the reduction of the amount of alumina inclusions of a large size contained in a cast piece, in any type (single type or dividable type) of nozzle.

3. 发明授权

EP1493516B1 BINDING STRUCTURE OF REFRACTORY SLEEVE FOR INNER HOLE OF NOZZLE FOR CONTINUOUS CASTING 有权
标题翻译：装订防火套筒的结构适用于多孔喷嘴连铸的内部
公开(公告)号：EP1493516B1
公开(公告)日：2007-04-25
申请号：EP03715683.3
申请日：2003-03-31
申请人： Krosakiharima Corporation , LWB Refractories Company
发明人： OGATA, Koji, c/o KROSAKIHARIMA CORPORATION
IPC分类号： B22D11/10 , B22D41/50 , B22D41/54 , C04B37/02 , C04B35/66
CPC分类号： C04B35/482 , B22D41/54 , B32B2315/02 , C04B35/013 , C04B35/043 , C04B35/06 , C04B35/103 , C04B37/003 , C04B37/005 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/48 , C04B2235/77 , C04B2237/06 , C04B2237/064 , C04B2237/068 , C04B2237/34 , C04B2237/343 , C04B2237/348 , C04B2237/708
摘要： A binding structure of a refractory sleeve with a body of a nozzle for continuous casting having a refractory sleeve containing 20 mass % or more of CaO attached on the inside of the body thereof for reducing the adhesion of alumina, wherein an adhesive material comprising a mixture of a refractory aggregate and a binder is applied to the outer face of the sleeve, a part or the whole of the surface of the inner wall of the hole in the nozzle body on which surface the refractory sleeve is to be attached, or a joint portion formed between the inserted refractory sleeve and the surface of the inner wall, and the porosity of the adhesive material after drying is adjusted so as to be 15 to 90 %. The binding structure allows the relaxation of thermal stress due to the rapid expansion resulting from the flow of molten steel into the inner hole during operation, which results in the prevention of the fallout of a sleeve and the adverse effect on the body of a nozzle due to the expansion thereof.

4. 发明公开

EP1760419A1 Verfahren zur Herstellung eines feuerfesten keramischen Produkts, Verwendung des Produkts und Verfahren zur Veränderung einer Schmelze mit dem Produkt 有权
标题翻译： Verfahren zur Herstellung eines feuerfesten keramischen Produkts
公开(公告)号：EP1760419A1
公开(公告)日：2007-03-07
申请号：EP05018796.2
申请日：2005-08-30
申请人： Refractory Intellectual Property GmbH & Co. KG
发明人： Djuricic Boro , Reitrer Franz
IPC分类号： F27D1/00 , C03B5/43 , C04B35/66 , B22D41/02 , C21C7/04
CPC分类号： B22D41/02 , B22D1/00 , B22D41/18 , B22D41/32 , B22D41/54 , C03B5/43 , C21C7/0006 , C21C7/04 , C22B9/00 , C22B15/006 , F27D1/0006
摘要： Produkte, insbesondere Massen und Formteile, die bei der bestimmungsgemäßen Anwendung feuerfeste Eigenschaften aufweisen, worden insbesondere in Einrichtungen zur Aufnahme, Behandlung und/oder Durchleitung von Schmelzen eingesetzt. Solche Schmelzen können Stahlschmelzen (Eisenschmelzen), Nicht-Eisenschmelzen (wie Kupferschmelzen) aber auch Glasschmelzen oder Gesteinsschmelzen sein, wobei solche Schmelzen üblicherweise Temperaturen zwischen 1000° C und 2.000°C aufweisen.
Die Schmelzenanalyse wird gezielt über die dosierte Abgabe mindestens einer Substanz aus dem feuerfesten Produkt verändert.
摘要翻译：产品，特别是具有耐火性能的组合物或成型部件，例如。在用于接收，处理和/或通过熔体的设备中，例如钢，铜或玻璃在1000-2000℃的温度下熔化。

5. 发明公开

EP1541259A4 NOZZLE REFRACTORY FOR CASTING BEING REDUCED IN DEPOSITION OF ALUMINA 有权
标题翻译：防火材料铸造喷嘴带减速氧化铝矿床
公开(公告)号：EP1541259A4
公开(公告)日：2006-05-24
申请号：EP03792721
申请日：2003-08-19
申请人： KROSAKIHARIMA CORP , LWB REFRACTORIES COMPANY
发明人： OGATA KOJI , HOOVER DONALD BRUCE
IPC分类号： B22D11/10 , B22D41/50 , B22D41/54 , C04B35/06 , C04B41/50 , C04B41/85 , B22D41/52
CPC分类号： C04B41/009 , B22D41/54 , C04B35/06 , C04B41/501 , C04B41/85 , C04B2111/00887 , C04B2235/321 , C04B2235/425 , C04B2235/5427 , C04B2235/5436 , C04B2235/5463 , C04B2235/604 , C04B2235/652 , C04B41/0072 , C04B41/4519 , C04B41/4556 , C04B35/013 , C04B35/057
摘要： Disclosed is anti-alumina-buildup refractories for casting nozzles, which comprises a refractory aggregate including 20 mass% or more of CaO component, and 10 mass % or more of clinker particles each containing CaO as a mineral phase, on the basis of 100 mass % of the entire composition. At least a part of the surfaces of the CaO exposed from the surfaces of the corresponding clinker particles is formed with a CaCO3 film. The CaCO3 film releases CO2 gas through thermal decomposition to smooth an operative surface of the nozzle so as to prevent the accretion of metal thereon, so that CaO is continuously supplied to alumina attached on the operative surface to prevent alumina buildup. In addition, the CaCO3 film effectively prevents the hydration of CaO due to a hydration reaction.

6. 发明公开

EP1534449A4 COATINGS FOR ARTICLES USED WITH MOLTEN METAL 审中-公开
标题翻译：涂料的金属液使用的物品
公开(公告)号：EP1534449A4
公开(公告)日：2006-03-01
申请号：EP03735158
申请日：2003-06-30
申请人： CAST CENTRE PTY LTD
发明人： JAHEDI MAHNAZ , GULIZIA STEFAN
IPC分类号： B22C3/00 , B22D17/30 , B22D41/02 , B22D41/54 , F27D1/00
CPC分类号： B22D41/02 , B22D41/00 , B22D41/54
摘要： An improved multilayer coating for use on molten metal holding and transfer apparatus, the coating including a bond layer applied directly to the surface of molten metal holding and transfer apparatus, and a porous layer of ceramic material produced by co-deposition of a powder of said ceramic material and a powder of a suitable organic polymer material and, after the co-deposition, heating of said polymer material to thermally decompose the polymer material and form the porous layer. The bond layer preferably is formed of a metallic, intermetallic or composite particulate materials. The metal component may be in the metallic, intermetallic, oxide, clad or alloyed form consisting of any one or more of the metal components selected from the group of Mo, Ni, Al, Cr, Co, Y and W and may be in combination with yttria, alumina, zirconia, boron, carbon and have a particle size in the range of 5 to 250 m, typically 40 to 125 m. The bond layer preferably has a thickness of 5 to 300 m with a substantially uniform coating layer being provided over the surfaces to have the porous ceramic coat applied.

7. 发明公开

EP1504831A4 NOZZLE FOR CONTINUOUS CASTING OF ALUMINUM KILLED STEEL AND CONTINUOUS CASTING METHOD 有权
标题翻译： DÜSEFÜRDAS STRANGGIESSEN VON ALUMINIUMBERUHIGTEM STAHL UND STRANGGIESSVERFAHREN
公开(公告)号：EP1504831A4
公开(公告)日：2005-08-17
申请号：EP03721000
申请日：2003-04-30
申请人： KROSAKIHARIMA CORP , LWB REFRACTORIES COMPANY
发明人： OGATA KOJI , SHIMIZU KOICHI , ASANO KEISUKE , HOKII TOSHIYUKI , YOSHITOMI JOKI
IPC分类号： B22D11/10 , B22D11/00 , B22D41/50 , B22D41/54 , C04B35/03
CPC分类号： B22D41/54
摘要： A nozzle system for continuous casting of an aluminum killed steel wherein 50 % or more of the total area of inner surfaces of all the nozzles for continuous casting being used for injecting a molten steel from a tundish to a mold is formed by a refractory containing CaO in an amount of 20 mass % or more. In the application of a material containing CaO to a nozzle for casting an aluminum killed steel, the amount of alumina inclusions of a large size formed in a cast piece has been found to correlate well with the total area of the inner surface of nozzles used and the CaO content of the refractory applied to the surface, and the above nozzle system allows the reduction of the amount of alumina inclusions of a large size contained in a cast piece, in any type (single type or dividable type) of nozzle.
摘要翻译：本发明提供了一种将铝含量的材料施加到用于铸造铝镇静钢的喷嘴单元的技术，其使得可以减少板坯中的大尺寸氧化铝夹杂物的数量，而不管喷嘴类型如单件式或多件式。使用单件式或多部型型喷嘴单元获得的大型氧化铝夹杂物的量，其具有用于将钢水从中间包浇铸到模具中的内孔和使用含CaO耐火材料与内孔的表面具有与喷嘴单元的内孔的整个表面积和所使用的耐火材料中含有的CaO的量的强相关性。根据本发明，喷嘴单元的内孔的整个表面积的50％以上由含有20质量％以上的CaO的耐火材料形成，能够减少大尺寸的氧化铝夹杂物的量。

8. 发明公开

EP1558414A1 PERMEABLE REFRACTORY MATERIAL FOR A GAS PURGED NOZZLE 审中-公开
标题翻译： NOZZLE离火耐热材料和方法生产同样
公开(公告)号：EP1558414A1
公开(公告)日：2005-08-03
申请号：EP03808992.6
申请日：2003-10-14
申请人： VESUVIUS CRUCIBLE COMPANY
发明人： DESAI, Priyadarshi, Gautam , DEBASTIANI, Duane , JANSSEN, Dominique
IPC分类号： B22D41/54 , B22D41/58
CPC分类号： C04B26/10 , B22D41/54 , B22D41/58 , C04B35/106 , C04B35/62665 , C04B35/66 , C04B2111/00267 , C04B2111/00612 , C04B2111/00887 , C04B2235/3217 , C04B2235/3244 , C04B2235/3418 , C04B2235/402 , C04B2235/5463 , C04B14/30 , C04B38/00 , C04B38/0054 , C04B38/0074 , C04B38/0645 , C04B40/0259 , C04B38/02
摘要： A permeable, resin-bonded composition is described, which finds utility as a porous element in a gas-injection nozzle. The permeable composition is notably useful in a canless, resin-bonded, gas-injection nozzle, characterized by an impermeable, resin-bonded composition replaces the metal can. Advantageously, the resin-bonded compositions include an oxygen getter for scrubbing oxygen before the oxygen can reach the molten steel. A method of manufacturing the nozzle is described and includes copressing a standard, resin-bonded composition around the permeable, resin-bonded composition. The pressed piece may be cured at temperatures below about 800 °C.

9. 发明授权

EP1492639B1 THERMAL SHOCK RESISTANT CASTING ELEMENT AND MANUFACTURING PROCESS THEREOF 有权
标题翻译：耐热冲击铸造元件及其制造工艺
公开(公告)号：EP1492639B1
公开(公告)日：2005-06-29
申请号：EP03711721.5
申请日：2003-03-28
申请人： Vesuvius Crucible Company
发明人： HANSE, Eric , DELVOYE, François , LAVAL, Philippe
IPC分类号： B22D41/54
CPC分类号： B22D41/54
摘要： The present invention concerns an element for the casting of a liquid metal, comprising a base body made from a refractory material, said body comprising an outer surface and an inner surface defining a pouring channel for the casting of the liquid metal. This element is characterized in that at least a part of the element inner surface is coated with an insulating coating forming, at the metal liquid contact, a gas impermeable layer. Such an element has an excellent thermal shock resistance which permits its use without preheating. Then a layer reducing advantageously the gas permeability is formed.
摘要翻译：本发明涉及用于铸造液态金属的元件，包括由耐火材料制成的基体，所述主体包括外表面和限定用于铸造液态金属的浇注通道的内表面。该元件的特征在于元件内表面的至少一部分涂覆有绝缘涂层，在金属液体接触处形成不透气层。这样的元件具有优异的耐热冲击性，允许其在不预热的情况下使用。然后形成有利地降低气体渗透性的层。

10. 发明授权

EP1160031B1 Verfahren zum Beschichten von Ausgüssen, Giessrohren, Giessstrahlschutzrohren und dergleichen Werkstücken zum Vergiessen und Überführen von Schmelzen 有权
标题翻译：一种用于涂料水槽，浇注管等Giessstrahlschutzrohren工件用于铸造和的熔融转印处理
公开(公告)号：EP1160031B1
公开(公告)日：2005-01-19
申请号：EP00111606.0
申请日：2000-05-31
申请人： TYK Europe GmbH
发明人： Schrick, Günther
IPC分类号： B22D41/54 , C04B14/36
CPC分类号： C04B14/36 , B22D41/54 , C04B28/06 , C04B2111/00551 , C04B2111/00612 , C04B2111/0087 , C04B20/002

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