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    • 8. 发明公开
    • Method for liquid chromate ion and oxy-metal ions removal and stabilization
    • Entfernung und Stabilisierung von Chromat und Metalloxid-Ionen
    • EP1215176A1
    • 2002-06-19
    • EP00811181.7
    • 2000-12-13
    • INSTITUTE OF NUCLEAR ENERGY RESEARCH, TAIWAN, R.O.C.
    • Huang, Ching-TsuenLiu, Tzeng-MingLee, Tsye-ShingLai, Wen-Chao
    • C02F1/52C02F1/62
    • C02F1/281B01J41/02B01J41/10C02F1/001C02F1/5236C02F2001/422C02F2101/20C02F2101/22
    • This invention discloses a method for removing and stabilizing liquid chromate ion and other oxy-metal ions with barium compounds.
      Barium compounds with very low water solubility , such as barium silicate , barium carbonate, barium fluorosilicate, ect. can be used as powerful adsorbents for adsorbing chromate ion (CrO 4 2- ) and other oxy-metal ions from liquid solutions at a wide pH range with very high adsorption capacity. For instance, one gram of barium silicate can adsorb chromate up to 200 mg. The adsorption capacity is higher than that of all the chromate adsorbents currently available. The chromate waste solution treated by barium silicate leaves as low as 0.01 ppm chromate in the solution. Also disclosed in this invention is a de-sorption process of chromate. After de-sorption, the chromate is recovered as a resource and the adsorbents are regenerated for reuse with the same adsorption power.
      Barium compounds with high water solubility, such as barium chloride and barium hydroxide etc. are used to prepare solutions, and then mixed with liquid wastes containing chromate ion and other oxy-metal ions to form very poorly soluble precipitates of barium compounds. The ions from liquid waste are thus removes by filtration, or the ions are immobilized in the solidification of the wastes, thereby promoting the efficiency of solidification and upgrading the quality of the solidified wastes.
    • 本发明公开了一种利用钡化合物去除和稳定液态铬酸盐离子和其它氧 - 金属离子的方法。 水溶性极低的钡化合物,如硅酸钡,碳酸钡,氟硅酸钡等。 可以作为强吸附剂,在非常高的吸附容量的宽pH范围内从液体溶液中吸附铬酸根离子(CrO4 2-)和其他氧 - 金属离子。 例如,一克硅酸钡可以吸附高达200毫克的铬酸盐。 吸附能力高于目前可获得的所有铬酸盐吸附剂。 用硅酸钡处理的铬酸盐废液在溶液中低至0.01ppm的铬酸盐。 本发明还公开了铬酸盐的脱附方法。 脱附后,铬酸盐作为资源回收,吸附剂再生再利用,具有相同的吸附能力。 使用具有高水溶性的钡化合物如氯化钡和氢氧化钡等来制备溶液,然后与含有铬酸根离子和其它氧 - 金属离子的液体废物混合形成非常难溶的钡化合物沉淀物。 因此,通过过滤除去废液中的离子,或者将废物固定在废物的固化中,从而提高固化效率,提高固化废物的质量。