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    • 2. 发明公开
    • PROCESS AND APPARATUS FOR PREPARING METAL OR NONMETAL PHTHALOCYANINE
    • VERFAHREN UND APPARAT ZUR HERSTELLUNG VON METALL- BZW. NICHTMETALLPHTHALOCYANIN
    • EP1625131A4
    • 2006-12-20
    • EP04733202
    • 2004-05-14
    • PHTHALOS CO LTD
    • KWON JONG HOJUNG KI SUCKSON WOO HOPARK SEONG SOO
    • C07D487/22B01J19/10B01J19/12
    • C07D487/22B01J19/10B01J19/126B01J2219/00063B01J2219/089B01J2219/0892B01J2219/123B01J2219/1275
    • Disclosed herein is a process for preparing a metal or nonmetal phthalocyanine by using both microwave and ultrasonic wave energy in the presence of a solvent, or by using microwave energy in the absence of a solvent. Specifically, according to the process, anhydrous phthalic acid, phthalimide, 1,3-diiminoisoindoline, 1,2-dicyanobenzene, an halogen derivative thereof, an alkyl_ derivative thereof or an alkoxy derivative thereof is mixed with a metal chloride or an alkoxy metal at 130250°C for 0.2515 hours by using microwave at a frequency of 0.1-1000Hz and a power of 100-3,000W and ultrasonic wave at a frequency of 1-1,000GHz and a power of 100-5,000W in the presence of a solvent, or by using microwave at a frequency of 0.1-100GHz and a power of 100-4,000W in the absence of a solvent. Further disclosed is an apparatus for preparing a metal or nonmetal phthalocyanine in the absence or presence of solvent.
    • 本发明公开了一种通过在溶剂存在下使用微波和超声波能量,或者通过在不存在溶剂的情况下使用微波能量来制备金属或非金属酞菁的方法。 具体而言,根据该方法,可以使用无水邻苯二甲酸,邻苯二甲酰亚胺,1,3-二亚氨基异吲哚满,1,2-二氰基苯,其卤素衍生物, 衍生物或其烷氧基衍生物与金属氯化物或烷氧基金属在1302〜150℃下混合0.25〜15小时,使用频率为0.1〜1000Hz,功率为100〜3,000W的微波和频率为1的超声波 -1,000GHz,功率为100-5,000W,或者在溶剂不存在的情况下,使用频率为0.1-100GHz,功率为100-4,000W的微波。 还公开了在溶剂不存在或存在下制备金属或非金属酞菁的设备。