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    • 4. 发明公开
    • A MODIFIED POLYACRYLONITRILE FIBER AND ITS PREPARATION PROCESS AND USE
    • IHRE HERSTELLUNG UND VERWENDUNG改性聚丙烯腈
    • EP2123805A1
    • 2009-11-25
    • EP07816881.2
    • 2007-11-20
    • Hiking Group Co., Ltd
    • ZHANG, XingxiangZHANG, JianhuaCUI, HeWANG, XuechenNIU, Jianjin
    • D01F6/40A41G3/00
    • D01F1/10A41G3/0083D01F6/18D01F6/38
    • A modified polyacrylonitrile fiber and its preparation process and use are disclosed. The modified polyacrylonitrile fiber has the animal hair micropowder as the modifier and the polyacrylonitrile as base body. The weight percent of each component is showed below: the acrylonitrile monomer 50.0-98.8%, the initiator 0.1-0.4%, the animal hair micropowder 1.0-50.0%, the total weight percent of each component is 100%. The preparation process of the modified polyacrylonitrile fiber includes the following steps: 1. preparing the animal hair micropowder suspension, 2. preparing spinning dope of the modified polyacrylonitrile fiber, 3. preparing the modified polyacrylonitrile fiber. The fiber of the invention is especially suitable for making artificial synthetic hair owing to its appearance and performance approaching that of human hair, and its well emulated effect and well replaceability for human hair.
    • 公开了改性聚丙烯腈纤维及其制备方法和用途。 改性聚丙烯腈纤维具有动物毛发微粉作为改性剂,聚丙烯腈为基体。 各成分的重量百分比如下所示:丙烯腈单体50.0-98.8%,引发剂0.1-0.4%,动物毛发微粉1.0-50.0%,各成分的总重量百分比为100%。 改性聚丙烯腈纤维的制备方法包括以下步骤:1.制备动物毛发微粉悬浮液,2.制备改性聚丙烯腈纤维的纺丝原液,3.制备改性聚丙烯腈纤维。 本发明的纤维特别适用于人造合成毛发的外观和性能接近于人的头发,其良好的模拟效果和人类头发的良好的替代性。
    • 8. 发明公开
    • Modified cross-section fiber for artificial hair
    • FaserfürKunsthaar mit modifizierter Querschnittsform
    • EP0740000A1
    • 1996-10-30
    • EP96106778.2
    • 1996-04-29
    • KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA
    • Kakita, NaohikoCho, KenichiroNakashima, HiroyukiNishi, NobuyukiNishiura, Koichi
    • D01D5/253A41G3/00A63H3/44
    • A41G3/0083A63H3/44D01D5/253Y10T428/2913Y10T428/2973Y10T428/298
    • Modified cross-section fibers for artificial hair having an improved bulkiness and a soft feeling as compared with conventional fibers for the artificial hair, comprising synthetic fibers, the synthetic fiber having a cross-section comprising one central connecting portion and projections extending in three directions from the central connecting portions, wherein at least one of the three projections is most narrowed at a portion which is nearer to the top edge of the projection than 1/2 of the length R from the center of the central connecting portion to the top edge of the projection, a ratio of W1/W2 wherein W1 is the width of the widest portion in the portion which is nearer to the top edge than the most narrowed portion, and W2 is the width of the most narrowed portion is 1.05 to 2.0, and a ratio of R/W1 wherein R and W1 are the same as defined above is from 1.10 to 5.0.
    • 与用于人造毛发的常规纤维相比,具有改善的蓬松性和柔软感的人造毛发的改性横截面纤维包括合成纤维,该合成纤维具有截面包括一个中心连接部分和从三个方向延伸的突起 中心连接部分,其中三个突起中的至少一个在距离突起的顶部边缘更靠近突出部分的部分处最窄,该部分距离中心连接部分的中心至顶部边缘的长度R的1/2 投影,其中W1是最接近顶部边缘的部分中最宽部分的宽度比最窄部分宽的W1 / W2的比率,W2最窄部分的宽度为1.05至2.0,以及 其中R和W1与上述定义相同的R / W1比为1.10-5.0。
    • 9. 发明公开
    • Artificial hair
    • Kunsthaar。
    • EP0499194A2
    • 1992-08-19
    • EP92102229.9
    • 1992-02-11
    • ADERANS CO., LTD.
    • Miyachi, Yasuyoshi, c/o Central Research Lab.Ito, Nobuo, c/o Central Research Lab.Koyama, Masako, c/o Central Research Lab.
    • D01F6/68A41G3/00A63H3/44D01F6/78
    • A41G3/0083A63H3/44D01F6/68D01F6/78
    • An artificial hair made of a fibers comprising a poly-a-amino acid derivative insoluble to water and alcohols and represented by one of the following general formulae (1) - (4):


      providing that R in each of the above formula (1) - (4) is R a , R b and R° represented, respectively, by the following general formula (5), (6) or (7):


      or made or polyamino acid urethane fiber comprising a copolymer of an amino acid N-carboxy anhydride and a polyurethane, in which the copolymer is subjected to an amidation reaction with an organic diamine and an organic amine having amino groups and mercapto groups or disulfide groups and to shaping into a fibrous form.
      The artificial hair has a dyeability, shape retainability, natural and soft and flexible feeling, excellent tough and brushing property, as well as has natural color and gloss and toughness like that natural protein fiber.
    • 一种由纤维构成的人造毛发,其包含不溶于水和醇的聚-α-氨基酸衍生物,并由以下通式(1) - (4)之一表示:,其中每个上述式 (1) - (4)分别由以下通式(5),(6)或(7)表示的R a,R b和R c表示:&lparstr&CH 2)kCONR 1 (CH 2)n NR 2 R 3(5),&lparstr&CH 2)kCONR 1(CH 2)1 SR 2(6),&lparstr&CH 2)kCOOR',H,R'或-CH 2 CH 2 SMe(7) 或包含氨基酸N-羧酸酐和聚氨酯的共聚物的聚氨基酸聚氨酯纤维,其中共聚物与有机二胺和具有氨基和巯基或二硫基的有机胺进行酰胺化反应,以及 成型为纤维状。 人造头发具有染色性,形状保持性,自然柔软柔软的感觉,优异的韧性和刷牙性,以及天然的蛋白质纤维具有天然色泽,光泽和韧性。