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1. 发明公开

EP2128197A1 OXYGEN-ABSORBING RESIN COMPOSITION, OXYGEN-ABSORBING MOLDED ARTICLE, PACKAGING MATERIAL AND PACKAGING CONTAINER 审中-公开
标题翻译： SAUERSTOFFABSORBIERENDE HARZZUSAMMENSETZUNG，SAUERSTOFFABSORBIERENDER FORMARTIKEL，VERPACKUNGSMATERIAL UNDVERPACKUNGSBEHÄLTER
公开(公告)号：EP2128197A1
公开(公告)日：2009-12-02
申请号：EP08711353.6
申请日：2008-02-15
申请人： Zeon Corporation
发明人： KITAHARA, Shizuo , ISHIHARA, Jun
IPC分类号： C08L67/02 , B32B27/00 , B65D30/02 , B65D65/40 , B65D81/24 , C08L77/00
CPC分类号： C08L77/00 , B32B15/08 , B32B27/08 , B32B27/20 , B32B27/306 , B32B27/34 , B32B27/36 , B32B2255/10 , B32B2255/205 , B32B2262/101 , B32B2262/103 , B32B2262/106 , B32B2307/306 , B32B2307/3065 , B32B2307/31 , B32B2307/412 , B32B2307/516 , B32B2307/518 , B32B2307/712 , B32B2307/724 , B32B2307/7242 , B32B2439/00 , C08J5/18 , C08J2367/02 , C08J2377/00 , C08L23/0823 , C08L23/20 , C08L45/00 , C08L67/02 , C08L2205/02 , Y10T428/31725 , Y10T428/31739 , Y10T428/31786 , C08L2666/04 , C08L2666/06
摘要： [PROBLEMS]
To provide an oxygen-absorbing resin composition which does not require incorporating a transition metal compound thereinto, which has excellent oxygen absorbability at room temperature, which releases little smell on oxygen absorption, and which can produce a shaped article having excellent transparency; an oxygen-absorbing shaped article comprising the oxygen-absorbing resin composition; and a packaging material and a packaging container each comprised of the shaped article.
[MEANS FOR SOLVING PROBLEMS]
Disclosed is an oxygen-absorbing resin composition comprising a resin composition (A) that comprises an oxygen-absorbing resin (A1) having a cycloene structure in the molecule and a softener (A2) and has a glass transition temperature of from -30°C to +30°C, as dispersed in a resin (B) having an oxygen permeability of from 100 cc to 500 cc 20 µm/m 2 ·day·atom (25°C, 65 % RH). The softening agent (A2) is preferably liquid paraffin or polybutene. The resin (B) is preferably a (terephthalic acid)/(cyclohexanedimethanol) copolymer polyester or a polyamide resin.
摘要翻译： [问题]提供一种氧化吸收性树脂组合物，其不需要在室温下具有优异的氧吸收性的过渡金属化合物，能够吸收氧气吸收少的气味，能够制造透明性优异的成形体，包含氧吸收性树脂组合物的吸氧成形体; 以及每个由成形制品构成的包装材料和包装容器。解决问题的方法公开了一种吸氧树脂组合物，其包含树脂组合物（A），其包含在分子中具有环烯结构的氧吸收性树脂（A1）和软化剂（A2），并且具有玻璃化转变温度分散在透氧度为100cc〜500cc20μm/ m 2·天·原子（25℃，65％RH）的树脂（B）中的-30℃〜30℃。软化剂（A2）优选为液体石蜡或聚丁烯。树脂（B）优选为（对苯二甲酸）/（环己烷二甲醇）共聚物聚酯或聚酰胺树脂。

2. 发明授权

EP1947147B1 OXYGEN-ABSORBING BARRIER RESIN COMPOSITION, FILM COMPRISING THE SAME, MULTILAYER STRUCTURE, AND PACKAGING CONTAINER 失效
标题翻译：吸氧阻隔树脂组合物含有这种薄膜，复合结构和包装容器
公开(公告)号：EP1947147B1
公开(公告)日：2012-03-28
申请号：EP06822454.2
申请日：2006-10-27
申请人： Zeon Corporation
发明人： KITAHARA, Shizuo , KURAKATA, Mako , ISHIHARA, Jun c/o ZEON CORPORATION
IPC分类号： C08L101/00 , B32B27/00 , C08J5/18 , C08L15/00 , C08L45/00 , C08L65/00
CPC分类号： B32B27/00 , C08L23/0861 , Y10T428/1379 , Y10T428/1383 , Y10T428/24994 , Y10T428/254 , Y10T428/31917 , Y10T428/31928 , C08L2666/20
摘要： [PROBLEMS] To provide: an oxygen-absorbing barrier resin composition which has excellent oxygen-barrier properties even under high-humidity conditions and can give a multilayer structure having excellent peel strength; an oxygen-absorbing barrier film comprising the oxygen-absorbing barrier resin composition; a multilayer structure including a layer comprising the oxygen-absorbing barrier film; and a packaging container comprising the multilayer structure. [MEANS FOR SOLVING PROBLEMS] The oxygen-absorbing barrier resin composition comprises a matrix comprising a resin (A) having an oxygen permeability of 100 cc/m2·day·atm or lower and, dispersed in the matrix, a resin (B) having an oxygen absorption rate of 0.001 cc/cm2·day or higher, wherein the resin (B) is in the form of rods in which the average of the maximum diameters of sections perpendicular to the lengthwise direction is 1.0 µm or smaller. The resin (B) preferably is a product of cyclization of a conjugated diene polymer, the cyclization product having a percentage decrease in unsaturated-bond amount of 10% or higher.

3. 发明公开

EP1589037A1 POLAR GROUP-CONTAINING CYCLIZED RUBBER AND METHOD FOR PRODUCING SAME 有权
标题翻译：波士顿环球运动员克罗地亚
公开(公告)号：EP1589037A1
公开(公告)日：2005-10-26
申请号：EP04703497.0
申请日：2004-01-20
申请人： ZEON CORPORATION
发明人： KITAHARA, Shizuo , KASE, Toshio
IPC分类号： C08C19/00 , C08C19/10 , C08L101/00 , C08F36/04 , C09D109/00 , C09D5/00
CPC分类号： C08C19/10 , C08C19/44
摘要： A main object of the invention is to provide a polar-group-containing cyclized rubber making it possible to improve remarkably the adhesiveness between paint and a molded product made of a nonpolar polymer such as polypropylene or polyethylene, and a process for producing the same.
In order to attain the object, the invention provides a polar-group-containing cyclized rubber which has a polar group at a terminal of a polymer chain thereof, has a weight-average molecular weight of 1,000 to 1,000,000, and is obtained by cyclizing a conjugated diene polymer having the polar group at a terminal of a polymer chain thereof.
摘要翻译：本发明的主要目的是提供一种含极性基团的环化橡胶，可以显着提高涂料与由聚丙烯，聚乙烯等非极性聚合物构成的成型品的粘接性及其制造方法。为了达到上述目的，本发明提供了在其聚合物链末端具有极性基团的极性基团的环化橡胶，其重均分子量为1,000〜1,000,000，为通过在其聚合物链的末端环化具有极性基团的共轭二烯聚合物而获得。

4. 发明授权

EP1589037B1 POLAR GROUP-CONTAINING CYCLIZED RUBBER AND METHOD FOR PRODUCING SAME 有权
标题翻译：极性基团含环化橡胶及其制造方法
公开(公告)号：EP1589037B1
公开(公告)日：2010-04-14
申请号：EP04703497.0
申请日：2004-01-20
申请人： Zeon Corporation
发明人： KITAHARA, Shizuo , KASE, Toshio
IPC分类号： C08C19/00 , C08C19/10 , C08L101/00 , C08F36/04 , C09D109/00 , C09D5/00
CPC分类号： C08C19/10 , C08C19/44

5. 发明公开

EP1950251A1 OXYGEN-ABSORBING RESIN COMPOSITIONS, OXYGEN-ABSORBING FILM, AND OXYGEN-ABSORBING MULTILAYER STRUCTURE 审中-公开
标题翻译： SAUERSTOFFABSORBIERENDE HARZZUSAMMENSETZUNGEN，SAUERSTOFFABSORBIERENDER FILM UND SAUERSTOFFABSORBIERENDE MEHRSCHICHTSTRUKTUR
公开(公告)号：EP1950251A1
公开(公告)日：2008-07-30
申请号：EP06822453.4
申请日：2006-10-27
申请人： Zeon Corporation
发明人： KITAHARA, Shizuo , TERAISHI, Kazuo
IPC分类号： C08L101/00 , B32B27/00 , C08J5/18 , C08L15/00 , C08L45/00 , C08L65/00
CPC分类号： B32B27/08 , A23L3/3436 , C08L9/00 , C08L15/00 , C08L23/0807 , C08L23/0823 , C08L25/06 , C08L2666/04 , C08L2666/02
摘要： [PROBLEMS] To provide an oxygen absorbing resin composition which is excellent in oxygen absorption at room temperature, reduced in metal content, and reduced in odor emission after oxygen absorption; an oxygen-absorbing film comprising one of the oxygen-absorbing resin compositions; and an oxygen-absorbing multilayer structure including an oxygen-absorbing layer comprising one of the oxygen-absorbing resin compositions.
[MEANS FOR SOLVING PROBLEMS] One of the oxygen-absorbing resin compositions comprises a resin (A1) having a C-H bond in which the bond dissociation energy is at most 3.70 eV and a resin (B1) having a C-H bond in which the bond dissociation energy is larger than 3.70 eV but at most 4.20 eV. The other composition comprises a resin (A2) having a C-H bond capable of yielding a carbon radical in which the energy of reaction with oxygen is at most 10.0 kcal/mol and a resin (B2) having a C-H bond capable of yielding a carbon radical in which the energy of reaction with oxygen is larger than 10.0 kcal/mol but at most 22.0 kcal/mol.
摘要翻译：本发明提供一种氧吸收性树脂组合物，其在室温下的氧吸收性优异，金属含量降低，氧吸收后的臭气发生减少; 包含氧吸收性树脂组合物之一的氧吸收膜; 以及包含氧吸收层的氧吸收性多层结构，所述氧吸收层包含氧吸收性树脂组合物之一。 [解决问题的手段]氧吸收性树脂组合物中的一种包含具有键解离能最多为3.70eV的CH键的树脂（A1）和具有键键解离的CH键的树脂（B1）能量大于3.70eV，但最多为4.20eV。另一种组合物包含具有能够产生与氧的反应能为至多10.0kcal / mol的碳自由基的CH键的树脂（A2）和具有能够产生碳自由基的CH键的树脂（B2）其中与氧反应的能量大于10.0kcal / mol，但至多为22.0kcal / mol。

6. 发明授权

EP0894815B1 POLYESTER, PROCESS FOR THE PRODUCTION OF THE SAME, RESIN OR RUBB ER COMPOSITIONS CONTAINING THE SAME, AND MOLDINGS OF THE COMPOSITIONS 失效
标题翻译：聚酯; 用于生产，树脂或橡胶组合物该聚酯含有并形物由这些组合物
公开(公告)号：EP0894815B1
公开(公告)日：2002-12-18
申请号：EP97917403.4
申请日：1997-04-16
申请人： ZEON CORPORATION
发明人： KITAHARA, Shizuo , IKEDA, Shinya
IPC分类号： C08G63/181 , C08L101/00 , C08J5/00
CPC分类号： C08G63/181 , C08G63/20 , C08L21/00 , C08L23/16 , C08L2666/14 , C08L67/00

7. 发明公开

EP2520513A1 RESIN COMPOSITION FOR PACKAGES SUBJECTED TO HEAT STERILIZATION, FILM FOR PACKAGES SUBJECTED TO HEAT STERILIZATION, AND PROCESS FOR PRODUCING SAME 审中-公开
标题翻译：树脂组合物热灭菌包装，薄膜热稳定套餐及其制造方法
公开(公告)号：EP2520513A1
公开(公告)日：2012-11-07
申请号：EP10840999.6
申请日：2010-12-27
申请人： Zeon Corporation
发明人： KITAHARA, Shizuo , FUJII, Kensaku
IPC分类号： B65D81/26 , B32B27/18 , B65D65/02 , C08L29/04 , C08L77/00
CPC分类号： C08L23/0861 , B32B7/12 , B32B25/08 , B32B27/08 , B32B2250/24 , B32B2270/00 , B32B2307/31 , B32B2307/7244 , B32B2307/74 , B32B2439/00 , C08L29/04 , C08L77/00 , Y10T428/1383 , Y10T428/31551 , Y10T428/31924 , C08L2666/02 , C08L2666/04 , C08L9/00
摘要： An object of the present invention is to provide a packaging material for heat sterilization treatment, in which a decrease in the oxygen absorption capacity until the time of a heat sterilization treatment is prevented, a sufficient oxygen absorption capacity is exhibited at the time of a heat sterilization treatment, and odor that is generated along with oxygen absorption is suppressed. To attain the object, the present invention provides a resin composition for a package to be subjected to heat sterilization, comprising an oxygen absorptive resin composition dispersed in an oxygen barriering matrix resin, wherein the oxygen absorptive resin composition comprises a conjugated diene polymer cyclized product, the oxygen absorptive resin composition has a glass transition temperature of 31°C to 55°C, and the oxygen barriering matrix resin is at least one resin selected from an ethylene-vinyl alcohol copolymer resin and a polyamide resin.
摘要翻译：本发明的一个目的是提供一种用于加热杀菌处理的包装材料，其中，在所述氧吸收能力，直到加热杀菌处理的时间的减少，防止，充分的氧吸收能力是在一热的时间展出杀菌处理，和气味地连同氧吸收被抑制没有被生成。为了达到上述目的，本发明提供了一种封装的树脂组合物以进行加热杀菌处理，其包括在氧巴里环基质树脂分散在氧吸收性树脂组合物的，worin的氧吸收性树脂组合物包括共轭用作聚合物环化物，氧吸收性树脂组合物具有31℃的玻璃化转变温度至55℃，氧巴里环基质树脂是从树脂的乙烯 - 乙烯醇共聚物和聚酰胺树脂中选择的至少一种树脂。

8. 发明公开

EP1947147A1 OXYGEN-ABSORBING BARRIER RESIN COMPOSITION, FILM COMPRISING THE SAME, MULTILAYER STRUCTURE, AND PACKAGING CONTAINER 失效
标题翻译：吸氧阻隔树脂组合物含有这种薄膜，复合结构和包装容器
公开(公告)号：EP1947147A1
公开(公告)日：2008-07-23
申请号：EP06822454.2
申请日：2006-10-27
申请人： Zeon Corporation
发明人： KITAHARA, Shizuo , KURAKATA, Mako , ISHIHARA, Jun c/o ZEON CORPORATION
IPC分类号： C08L101/12 , B65D65/40 , C08J5/18
CPC分类号： B32B27/00 , C08L23/0861 , Y10T428/1379 , Y10T428/1383 , Y10T428/24994 , Y10T428/254 , Y10T428/31917 , Y10T428/31928 , C08L2666/20
摘要： [PROBLEMS] To provide an oxygen-absorbing barrier resin composition which has excellent oxygen-barrier properties even under high-humidity conditions and can give a multilayer structure having excellent peel strength; an oxygen-absorbing barrier film comprising the oxygen-absorbing barrier resin composition; a multilayer structure including a layer comprising the oxygen-absorbing barrier film; and a packing container comprising the multilayer structure.
[MEANS FOR SOLVING PROBLEMS] The oxygen-absorbing barrier resin composition comprises a resin (A) having an oxygen permeability of at most 100 cc/m 2 ·day·atm and a resin (B) having an oxygen absorption rate of at least 0.001 cc/cm 2 ·day, wherein the resin (B) is dispersed in the matrix of the resin (A) and the resin (B) is in the form of rods in which the average of the maximum diameters of cross sections perpendicular to the lengthwise direction is at most 1.0 µm. The resin (B) preferably is a product of cyclization of a conjugated diene polymer, the cyclization product having an unsaturated bond reduction ratio of at least 10 %.
摘要翻译： [问题]为了提供吸氧阻隔树脂组合物，即使在高湿度条件下具有优异的阻氧性，并且可以得到具有优异的剥离强度的多层结构; 吸氧阻隔薄膜，其包含氧吸收阻挡性树脂组合物; 多层结构包括含有吸氧阻隔成膜的层; 和包装容器，其包括多层结构。 [解决问题的手段]该吸氧阻隔树脂组合物含有树脂（A），其具有上至多为100cc / m 2·天·大气压的透氧性和树脂（B）具有以下各项中的至少0001氧吸收速度立方厘米/厘米2·天，worin树脂（B）分散在树脂（A）的基质中，树脂（B）是在杆中哪一个的横截面的最大合适直径的平均值垂直于的形式长度方向为至多1.0微米。所述树脂（B）优选是共轭聚合物的环化的产物服务，以至少10％的不饱和键减少率具有环化产物。

9. 发明授权

EP1862503B1 GAS BARRIER RESIN COMPOSITION HAVING OXYGEN-ABSORBING PROPERTY AND GAS BARRIER STRUCTURE HAVING OXYGEN-ABSORBING PROPERTY INCLUDING THE SAME 有权
标题翻译：与氧性能的气体阻隔树脂组合物和该组合物含阻气结构中的氧FEATURE
公开(公告)号：EP1862503B1
公开(公告)日：2014-03-05
申请号：EP06729326.6
申请日：2006-03-17
申请人： Zeon Corporation
发明人： KITAHARA, Shizuo
IPC分类号： C08L29/04 , C08L15/00 , B32B27/28 , C08J5/18 , B65D81/26 , C08L23/06 , C08L23/12 , C08L53/02
CPC分类号： C08L29/04 , B32B27/08 , C08C19/02 , C08C19/08 , C08K5/098 , C08K2201/008 , C08L9/06 , C08L15/00 , C08L23/02 , C08L23/06 , C08L23/0861 , C08L23/12 , C08L53/025 , Y10T428/1341 , Y10T428/249982 , C08L2666/06 , C08L2666/24 , C08L2666/02

10. 发明公开

EP2554604A1 RESIN COMPOSITION 审中-公开
标题翻译： HARZZUSAMMENSETZUNG
公开(公告)号：EP2554604A1
公开(公告)日：2013-02-06
申请号：EP11762772.9
申请日：2011-03-28
申请人： Zeon Corporation
发明人： SAKURAI, Takuro , KITAHARA, Shizuo
IPC分类号： C08L101/00 , C08K5/09 , C08L15/00
CPC分类号： C08K5/0016 , C08C19/10 , C08G2261/3327 , C08G2261/46 , C08J5/18 , C08J2367/02 , C08K5/09 , C08L15/00 , C08L65/00 , C08L67/02
摘要： An object of the invention is to provide a resin composition that exhibits sufficient oxygen absorption performance within a relatively short period after being placed in the presence of oxygen, even without including an oxidation catalyst such as a transition metal catalyst, and that furthermore suppresses the generation of malodor associated with oxygen absorption. The object is attained by providing a resin composition comprising an oxygen absorbing resin composition dispersed within a matrix resin, characterized in that the oxygen absorbing resin composition comprises a cyclized product of a conjugated diene polymer and a saturated fatty acid having 18 to 44 carbon atoms.
摘要翻译：本发明的目的是提供一种树脂组合物，即使在不含有过渡金属催化剂等氧化催化剂的情况下，也可以在放置有氧之后的较短时间内表现出足够的氧吸收性能，并且进一步抑制发生的恶臭与氧气吸收有关。该目的是通过提供一种包含分散在基质树脂中的吸氧树脂组合物的树脂组合物来实现的，其特征在于，所述氧吸收性树脂组合物包含共轭二烯聚合物和具有18至44个碳原子的饱和脂肪酸的环化产物。

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