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2. 发明公开

EP3157868A1 BANDGAP ENGINEERING OF CARBON QUANTUM DOTS 审中-公开
标题翻译：碳量子点的带隙工程
公开(公告)号：EP3157868A1
公开(公告)日：2017-04-26
申请号：EP15847060.9
申请日：2015-06-19
申请人： William Marsh Rice University
发明人： TOUR, James, M. , YE, Ruquan , METZGER, Andrew , STAVINOHA, Macy , ZHENG, Yonghao
IPC分类号： C01B32/336
CPC分类号： C01B32/184 , C01B32/15 , C01P2004/64
摘要： Embodiments of the present disclosure pertain to scalable methods of producing carbon quantum dots with desired bandgaps by the following steps: exposing a carbon source to an oxidant at a reaction temperature, where the exposing results in the formation of the carbon quantum dots; and selecting a desired size of the formed carbon quantum dots. In some embodiments, the selecting occurs by at least one of separating the desired size of the formed carbon quantum dots from other formed carbon quantum dots; selecting the reaction temperature that produces the desired size of the formed carbon quantum dots; and combinations of such steps. The desired size of carbon quantum dots can include a size range. The methods of the present disclosure can also include a step of purifying the formed carbon quantum dots prior to selecting a desired size.
摘要翻译：本公开的实施例涉及通过以下步骤制造具有期望带隙的碳量子点的可缩放方法：在反应温度下将碳源暴露于氧化剂，其中暴露导致形成碳量子点; 并选择所形成的碳量子点的期望尺寸。在一些实施例中，通过将所形成的碳量子点的期望尺寸与其他形成的碳量子点分开中的至少一种来进行选择; 选择产生所需尺寸的形成的碳量子点的反应温度; 以及这些步骤的组合。碳量子点的期望尺寸可以包括尺寸范围。本公开的方法还可以包括在选择期望尺寸之前纯化形成的碳量子点的步骤。

3. 发明公开

EP2807660A2 SYNTHESIS OF MAGNETIC CARBON NANORIBBONS AND MAGNETIC FUNCTIONALIZED CARBON NANORIBBONS 审中-公开
标题翻译：合成磁性碳纳米带和磁性功能化纳米波段
公开(公告)号：EP2807660A2
公开(公告)日：2014-12-03
申请号：EP13782176.5
申请日：2013-01-28
申请人： William Marsh Rice University , M.I L.L, C.
发明人： TOUR, James, M. , GENORIO, Bostjan , LU, Wei , PRICE-HOELSCHER, Brandi, Katherine
IPC分类号： H01F1/34 , C01B31/02
CPC分类号： H01F1/01 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/194 , C09K8/032 , C09K8/32 , C09K8/36 , C09K2208/10 , E21B21/00 , E21B47/12
摘要： Various embodiments of the present disclosure pertain to methods of making magnetic carbon nanoribbons. Such methods generally include: (1) forming carbon nanoribbons by splitting carbon nanomaterials; and (2) associating graphene nanoribbons with magnetic materials, precursors of magnetic materials, or combinations thereof. Further embodiments of the present disclosure also include a step of reducing the precursors of magnetic materials to magnetic materials. In various embodiments, the associating occurs before, during or after the splitting of the carbon nanomaterials. In some embodiments, the methods of the present disclosure further comprise a step of (3) functionalizing the carbon nanoribbons with functionalizing agents. In more specific embodiments, the functionalizing occurs in situ during the splitting of carbon nanomaterials. In further embodiments, the carbon nanoribbons are edge-functionalized. Additional embodiments of the present disclosure pertain to magnetic carbon nanoribbon compositions that were formed in accordance with the methods of the present disclosure.

4. 发明公开

EP2665563A1 GRAPHENE-BASED THIN FILMS IN HEAT CIRCUITS AND METHODS OF MAKING THE SAME 审中-公开
标题翻译：热CIRCUITS基于图形的薄膜及其制造方法
公开(公告)号：EP2665563A1
公开(公告)日：2013-11-27
申请号：EP12737015.3
申请日：2012-01-20
申请人： William Marsh Rice University , Lockheed Martin Corporation
发明人： TOUR, James, M. , VOLMAN, Vladimir , ZHU, Yu
IPC分类号： B05D5/12 , B32B9/04
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B32/18 , C01B32/194 , H01B1/04 , Y10T428/265 , Y10T428/31511 , Y10T428/31551 , Y10T428/31721 , Y10T428/31855
摘要： In various embodiments, the present invention provides electrically conductive and radio frequency (RF) transparent films that include a graphene layer and a substrate associated with the graphene layer. In some embodiments, the graphene layer has a thickness of less than about 100 nm. In some embodiments, the graphene layer of the film is adhesively associated with the substrate. In more specific embodiments, the graphene layer includes graphene nanoribbons that are in a disordered network. Further embodiments of the present invention pertain to methods of making the aforementioned electrically conductive and RF transparent films. Such methods generally include associating a graphene composition with a substrate to form a graphene layer on a surface of the substrate.

5. 发明公开

EP3386913A1 FORMATION OF THREE-DIMENSIONAL MATERIALS BY COMBINING CATALYTIC AND PRECURSOR MATERIALS 审中-公开
公开(公告)号：EP3386913A1
公开(公告)日：2018-10-17
申请号：EP16869339.8
申请日：2016-11-25
申请人： William Marsh Rice University , Tianjin University
发明人： TOUR, James, M. , SHA, Junwei , ZHAO, Naiqin
IPC分类号： C01B32/15 , C01B32/162 , C01B32/184 , B01J35/02 , C23F4/04 , B82Y40/00 , B82Y30/00
CPC分类号： C01B32/184 , B82Y30/00 , B82Y40/00 , C01P2006/12 , C01P2006/16 , C25B11/12 , H01G11/36 , H01M4/583 , H01M4/663 , H01M4/666 , H01M4/808 , H01M4/8621 , H01M4/96 , H01M2004/021
摘要： Embodiments of the present disclosure pertain to methods of making three-dimensional materials by combining a catalytic material with a precursor material and forming the three-dimensional material from the precursor material in the presence of the catalytic material. The three-dimensional material may be formed on surfaces and internal cavities of the catalytic material. The formed three-dimensional material includes a plurality of connected units that are derived from the precursor materials. The methods of the present disclosure may also include steps of separating catalytic materials from the formed three-dimensional materials and incorporating the three-dimensional materials as a component of an energy storage device (e.g., as an electrode in a capacitor). Additional embodiments of the present disclosure pertain to the formed three-dimensional materials.

6. 发明公开

EP3360180A1 HIGH SURFACE AREA POROUS CARBON MATERIALS AS ELECTRODES 审中-公开
公开(公告)号：EP3360180A1
公开(公告)日：2018-08-15
申请号：EP16854534.1
申请日：2016-10-10
申请人： William Marsh Rice University
发明人： TOUR, James, M. , WANG, Tuo , SALVATIERRA, Rodrigo, Villegas , JALILOV, Almaz, S.
IPC分类号： H01M4/13 , H01M4/58 , H01M4/80
CPC分类号： H01M4/663 , H01M4/0404 , H01M4/0409 , H01M4/0414 , H01M4/0419 , H01M4/0459 , H01M4/133 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M4/587 , H01M4/625 , H01M4/66 , H01M4/662 , H01M10/052 , H01M10/0525
摘要： Embodiments of the present disclosure pertain to an electrode that includes: a porous carbon material; a metal (e.g., Li) associated with the porous carbon material; and a conductive additive (e.g., graphene nanoribbons) associated with the porous carbon material. The metal may be in the form of a non-dendritic or non-mossy coating on a surface of the porous carbon material. The electrodes may also be associated with a substrate, such as a copper foil. The electrodes may be utilized as anodes or cathodes in energy storage devices, such as lithium ion batteries. Additional embodiments pertain to energy storage devices that contain the electrodes of the present disclosure. Further embodiments pertain to methods of making the electrodes by associating porous carbon materials with a conductive additive, a metal, and optionally a substrate. The electrode may then be incorporated as a component of an energy storage device.

7. 发明公开

EP3148925A2 GRAPHENE QUANTUM DOT-POLYMER COMPOSITES AND METHODS OF MAKING THE SAME 无效
标题翻译：维多利亚州立大学维多利亚州立大学
公开(公告)号：EP3148925A2
公开(公告)日：2017-04-05
申请号：EP15831742.0
申请日：2015-05-22
申请人： William Marsh Rice University
发明人： TOUR, James, M. , KOVALCHUK, Anton , XIANG, Changsheng
IPC分类号： B82Y20/00 , H01L29/15 , H01L31/0264 , H01L51/54
CPC分类号： C08F2/44 , C08J5/18 , C08J2329/04 , C08K3/042 , C08K2201/011 , C08L29/04
摘要： Various embodiments of the present disclosure pertain to methods of forming polymer composites that include polymers and graphene quantum dots. The methods occur by mixing a polymer component (e.g., polymers, polymer precursors and combinations thereof) with graphene quantum dots. In some embodiments, the polymers are in the form of a polymer matrix, and the graphene quantum dots are homogenously dispersed within the polymer matrix. In some embodiments, the graphene quantum dots include, without limitation, coal-derived graphene quantum dots, coke-derived graphene quantum dots, unfunctionalized graphene quantum dots, functionalized graphene quantum dots, pristine graphene quantum dots, and combinations thereof. Additional embodiments of the present disclosure pertain to polymer composites that are formed by the methods of the present disclosure. In some embodiments, the polymer composites of the present disclosure are fluorescent and optically transparent. In some embodiments, the polymer composites of the present disclosure are in the form of a film.
摘要翻译：本公开的各种实施方案涉及形成包括聚合物和石墨烯量子点的聚合物复合材料的方法。该方法通过将聚合物组分（例如聚合物，聚合物前体及其组合）与石墨烯量子点混合而发生。在一些实施方案中，聚合物是聚合物基质的形式，并且石墨烯量子点均匀地分散在聚合物基质内。在一些实施方案中，石墨烯量子点包括但不限于由煤衍生的石墨烯量子点，焦炭衍生的石墨烯量子点，未官能化石墨烯量子点，官能化石墨烯量子点，原始石墨烯量子点及其组合。本公开的另外的实施方案涉及通过本公开的方法形成的聚合物复合材料。在一些实施方案中，本公开的聚合物复合材料是荧光和光学透明的。在一些实施方案中，本公开的聚合物复合材料为膜的形式。

8. 发明公开

EP2443062A1 GRAPHENE NANORIBBONS PREPARED FROM CARBON NANOTUBES VIA ALKALI METAL EXPOSURE 审中-公开
标题翻译：碳纳米管碱金属吊顶生产的石墨烯纳米带
公开(公告)号：EP2443062A1
公开(公告)日：2012-04-25
申请号：EP10789979.1
申请日：2010-06-11
申请人： William Marsh Rice University
发明人： TOUR, James, M. , KOSYNKIN, Dmitry, V.
IPC分类号： C01B31/04
CPC分类号： C01B31/0446 , B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/184 , C01B32/19 , C01B2204/06 , C07C1/32 , C07C15/20 , Y10S977/896
摘要： In various embodiments, the present disclosure describes processes for preparing functionalized graphene nanoribbons from carbon nanotubes. In general, the processes include exposing a plurality of carbon nanotubes to an alkali metal source in the absence of a solvent and thereafter adding an electrophile to form functionalized graphene nanoribbons. Exposing the carbon nanotubes to an alkali metal source in the absence of a solvent, generally while being heated, results in opening of the carbon nanotubes substantially parallel to their longitudinal axis, which may occur in a spiralwise manner in an embodiment. The graphene nanoribbons of the present disclosure are functionalized on at least their edges and are substantially defect free. As a result, the functionalized graphene nanoribbons described herein display a very high electrical conductivity that is comparable to that of mechanically exfoliated graphene.

9. 发明公开

EP2294459A1 METHODS FOR MAGNETIC IMAGING OF GEOLOGICAL STRUCTURES 审中-公开
标题翻译：方法地质构造磁图片
公开(公告)号：EP2294459A1
公开(公告)日：2011-03-16
申请号：EP09751010.1
申请日：2009-01-09
申请人： William Marsh Rice University
发明人： SCHMIDT, Howard, K. , TOUR, James, M.
IPC分类号： G01V3/26
CPC分类号： G01V3/26
摘要： Methods for imaging geological structures include injecting magnetic materials into the geological structures, placing at least one magnetic probe in a proximity to the geological structures, generating a magnetic field in the geological structures and detecting a magnetic signal. The at least one magnetic probe may be on the surface of the geological structures or reside within the geological structures. The methods also include injecting magnetic materials into the geological structures, placing at least one magnetic detector in the geological structures and measuring a resonant frequency in the at least one magnetic detector. Methods for using magnetic materials in dipole-dipole, dipole-loop and loop-loop transmitter-receiver configurations for geological structure electromagnetic imaging techniques are also disclosed.

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