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    • 1. 发明公开
    • Method for removing cyanide compounds from wastewater
    • Verfahren zur Entfernung von Cyanid-Verbindungen aus Abwasser
    • EP3050853A1
    • 2016-08-03
    • EP15152980.7
    • 2015-01-29
    • Universiteit van Amsterdam
    • Oulego Blanco, PaulaShiju, Nirappurackal RaveendranRothenberg, Gad
    • C02F1/72C02F101/18C02F101/20C02F101/38C02F103/16
    • C02F1/725C02F1/722C02F2101/18C02F2101/203C02F2101/38C02F2103/16
    • The invention pertains to a method for reduction of the cyanide content of a metals-containing wastewater fraction by contacting a wastewater fraction comprising cyanide compounds and metal compounds, with a metals content of at least 100 ppm, with hydrogen peroxide and a solid catalyst comprising at least 50 wt.% of a copper salt with a solubility of less than 10 exp(-5) mol/liter (in water at 20°C, 1 atm).
      It has been found that when a solid catalyst comprising at least 50 wt.% of a copper salt with a solubility of less than 10 exp(-5) mol/liter (in water at 20°C, 1 atm) is used in combination with hydrogen peroxide in the reduction of the cyanide content of a cyanide compound-containing wastewater fraction having a metal compound content of at least 100 ppm, a method is obtained which shows an efficient removal of cyanide compounds from a difficult to treat fraction.
    • 本发明涉及通过使包含氰化物化合物和金属化合物的金属含量至少为100ppm的废水部分与过氧化氢和固体催化剂接触来降低含金属废水部分的氰化物含量的方法,所述固体催化剂包括 至少50重量%的溶解度小于10埃(-5)摩尔/升的铜盐(在20℃的水中,1个大气压)。 已经发现,当组合使用包含至少50重量%的溶解度小于10埃(-5)摩尔/升(在20℃的水中,1个大气压)的铜盐的固体催化剂时 与过氧化氢相比,含有金属化合物含量至少为100ppm的含氰化合物的废水馏分的氰化物含量降低,得到了从难处理馏分中有效除去氰化物的方法。
    • 2. 发明公开
    • Laminate comprising carrier and coating layer
    • Laminat mitTräger-und Deckschicht
    • EP2511354A1
    • 2012-10-17
    • EP11162437.5
    • 2011-04-14
    • Universiteit van Amsterdam
    • Alberts, Albert HenderikusRothenberg, Gad
    • C09D167/00C09D167/02C09J167/00C09J167/02C08J7/04C09J5/06
    • C09J167/00C08J7/047C08J2467/02C09D167/00C09D167/02C09J167/02
    • Laminate comprising a carrier and a coating layer, wherein the coating layer is applied over at least part of the carrier, the coating layer comprising a polyester derived from an aliphatic polyalcohol with 2-15 carbon atoms and a polyacid, the coating layer having a thickness in the range of 10-4000 microns. Optionally a second carrier may be applied over at least part of the coating layer. If so desired, a further coating layer is applied over at least part of the second carrier, with optional further carrier-coating stacks applied over the further carrier.
      preferably the polyacohol is secelected from one or more of glycerol, sorbitol, xylitol, and mannitol, in particular glycerol. The polyacid preferably is an aliphatic diacid or triacid with 3-15 carbon atoms. Examples of suitable acids include citric acid, succinic acid, and itaconic acid.
      The laminate according to the invention may be, e.g., a multiplex-type material.
    • 包含载体和涂层的层压体,其中所述涂层涂覆在所述载体的至少一部分上,所述涂层包含衍生自具有2-15个碳原子的脂族多元醇的聚酯和多酸,所述涂层具有厚度 在10-4000微米的范围内。 任选地,第二载体可以施加在涂层的至少一部分上。 如果需要,在第二载体的至少一部分上施加另外的涂层,可选的另外的载体涂层叠层施加在另外的载体上。 优选地,从甘油,山梨糖醇,木糖醇和甘露醇中的一种或多种,​​特别是甘油中选择多糖。 多酸优选为具有3-15个碳原子的脂族二酸或三酸。 合适的酸的实例包括柠檬酸,琥珀酸和衣康酸。 根据本发明的层压体可以是例如多重型材料。
    • 4. 发明公开
    • Composite material comprising synthetic filler and specific polymer
    • Verbundwerkstoff mit SynthetischemFüllstoffund spezifischem Polymer
    • EP2511324A1
    • 2012-10-17
    • EP11162442.5
    • 2011-04-14
    • Universiteit van Amsterdam
    • Alberts, Albert HenderikusRothenberg, Gad
    • C08J5/04C08K3/40C08K7/14C08L67/02C03C25/10
    • C08J5/043C03C25/1095C08J5/24C08J2367/00C08K3/40C08K7/14
    • A composite material comprising 20-98 wt.% of a synthetic particulate or fibrous filler and at least 2 wt.% of a polyester derived from an aliphatic polyalcohol with 2-15 carbon atoms and a polyacid.
      Preferably, the filler is in the form of particles, fibers, and/or random or non-random layers. Preferably, the filler is based on one or more of ceramic, including glass, in particular glass fibers, polymer, in particular polymer fibers, and carbon, in particular carbon fibers. The use of glass fiber based sheet-like material as filler is a particular embodiment of the invention.
      Preferably the polyacohol is selected from one or more of glycerol, sorbitol, xylitol, mannitol, 1,2-propane diol, 1,3-propane diol, and 1,2-ethane diol, in particular glycerol. The polyacid preferably is an aliphatic diacid or triacid with 3-15 carbon atoms. Examples of suitable acids include citric acid, succinic acid, and itaconic acid.
    • 一种复合材料,其包含20-98重量%的合成颗粒或纤维填料和至少2重量%的衍生自具有2-15个碳原子的脂肪族多元醇和多酸的聚酯。 优选地,填料是颗粒,纤维和/或随机或非随机层的形式。 优选地,填料基于一种或多种陶瓷,包括玻璃,特别是玻璃纤维,聚合物,特别是聚合物纤维,以及碳,特别是碳纤维。 使用玻璃纤维基片状材料作为填料是本发明的一个具体实施方案。 优选地,多糖选自甘油,山梨醇,木糖醇,甘露醇,1,2-丙二醇,1,3-丙二醇和1,2-乙二醇中的一种或多种,​​特别是甘油。 多酸优选为具有3-15个碳原子的脂族二酸或三酸。 合适的酸的实例包括柠檬酸,琥珀酸和衣康酸。