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1. 发明公开

EP0129723A3 Curable poly(acrylate) molding compositions containing a thermoplastic polymer low profile additive 失效
标题翻译：包含热塑性聚合物的可固化聚（丙烯酸酯）成型组合物低型添加剂
公开(公告)号：EP0129723A3
公开(公告)日：1986-04-23
申请号：EP84106003
申请日：1984-05-25
申请人： UNION CARBIDE CORPORATION
发明人： Domeier, Linda Ann
IPC分类号： C08F220/20 , C08F291/00 , C08F263/04 , C08F212/36
CPC分类号： C08F291/00 , C08F222/1006 , C08F257/02 , C08F263/04 , C08F212/34 , C08F220/12 , C08F220/20
摘要： This invention is directed to curable molding compositions containing a mixture of a poly(acrylate), a polymerizable ethylenically unsaturated monomerwhich servesto crosslink the poly(acrylate) to a thermoset product, and a thermoplastic polymer low profile additive. The curable molding compositions can also contain unsubstituted or substituted meta- and/or para-divinylbenzene and/or a free radical initiator mixture containing at least one initiator with a 10-hour half-life temperature (t1/2) of greater than about 90°C and at least one initiator with a 10-hour half-life temperature (t1/2) of less than about 90°C. The curable molding compositions exhibit improved shrink control during the curing reaction. This invention is also directed to fiber reinforced thermoset resin articles which exhibit generally improved surface appearance quality and can be produced by a rapid injection molding process from the curable molding compositions.

2. 发明公开

EP0069340A1 Curable molding compositions containing a poly(acrylate) 失效
标题翻译： Vernetzbare Formzusammensetzungen welche ein Polyacrylat enthalten。
公开(公告)号：EP0069340A1
公开(公告)日：1983-01-12
申请号：EP82105841.9
申请日：1982-06-30
申请人： UNION CARBIDE CORPORATION
发明人： Domeier, Linda Ann , Peters, Edward Norman , Michno, Michael John, Jr.
IPC分类号： C08F220/20 , C08J5/04 , C08J5/24
CPC分类号： C08J5/04 , C08F222/1006 , C08J2333/06 , C08F220/20 , C08F220/06
摘要： Described herein are curable molding compositions comprising a mixture of:

(a) a poly(acrylate) characterized by the following empirical formula:
wherein R is the hydroxy-free residue of an organic polyhydric alcohol which contained alcoholic hydroxyl groups bonded to different carbon atoms, R, and R 2 are independently hydrogen or methyl, and n is 1 to 3,
(b) acrylic or methacrylic acid or a functionalized derivative thereof having a molecular weight of less than 300 which is different from (a), and
(c) an ethylenically unsaturated monomer which is soluble in and copolymerizable with (a) and (b) and which is different from (a) and (b).

The compositions can also contain one or more fibers with a melting point or glass transition temperature above about 130°C.
摘要翻译：本文描述的是可固化模塑组合物，其包含以下混合物的混合物：（a）由以下经验式表征的聚（丙烯酸酯）：其中R是含有与不同键合的醇羟基的有机多元醇的无羟基残基碳原子，R1和R2独立地为氢或甲基，n为1至3，（b）分子量小于300的丙烯酸或甲基丙烯酸或其官能化衍生物，其不同于（a）和（c ）烯属不饱和单体，其可溶于（a）和（b）并且可与（a）和（b）共聚并且不同于（a）和（b）。组合物还可以含有一种或多种熔点或玻璃化转变温度高于约130℃的纤维。

3. 发明公开

EP0052881A3 Curable molding composition and its use for producing thermoset fiber-reinforced molded articles 失效
标题翻译：可固化成型组合物及其用于生产热固纤维增强塑料制品的用途
公开(公告)号：EP0052881A3
公开(公告)日：1982-08-04
申请号：EP81109842
申请日：1981-11-23
申请人： UNION CARBIDE CORPORATION
发明人： Domeier, Linda Ann
IPC分类号： C08L75/04 , C08G18/63 , C08L33/04 , C08J05/04 , C08F283/00 , C08K07/02 , C08L77/10
CPC分类号： C08L33/08 , C08G18/637 , C08G2120/00 , C08K7/02 , C08L33/04 , C08L75/04 , C08L77/00 , C08L2205/16 , C08L2666/14 , C08L33/00
摘要： Curable molding compositions comprising a mixture of:
I. from about 25 to about 90 weight percent of a thermosetting resin containing:
(a) from about 5 to about 95 weight percent of a polyester resin derived from the reaction of a poly(acrylate) and a vinyl monomer, said poly(acrylate) and vinyl monomer essentially free from functional groups reactive with the polyol of the polyisocyanate of (b); (b) from about 95 to about 5 weight percent of a polyurethane derived from the reaction of a saturated polyol and a polyisocyanate, said polyol and polyisocyanate free from unsaturated groups capable of copolymerizing with the poly(acrylate) or vinyl monomer of (a); and II. from about 75 to about 10 weight percent of one or more fibers with a melting point or a glass transition temperature above about 130°C; wherein (b) constitutes less than 40 weight percent of (I) and (II). These compositions are especially suited to produce thermoset fiber-reinforced molded articles by rapid injection molding techniques.

4. 发明授权

EP0108372B1 Compositions containing a reactive monomer derived from a lactone 失效
标题翻译：含有从Lactone衍生的反应性单体的组合物
公开(公告)号：EP0108372B1
公开(公告)日：1989-02-08
申请号：EP83110880.8
申请日：1983-10-31
申请人： UNION CARBIDE CORPORATION
发明人： Koleske, Joseph Victor , Domeier, Linda Ann
IPC分类号： C08F299/04 , C08F220/28 , C08F220/20 , C08L67/06
CPC分类号： C08G63/08 , C08F220/28 , C08F299/026

5. 发明公开

EP0108372A2 Compositions containing a reactive monomer derived from a lactone 失效
标题翻译： Zusammensetzungen，死亡ein von einem Lacton abgeleitetes reaktives单体乞丐。
公开(公告)号：EP0108372A2
公开(公告)日：1984-05-16
申请号：EP83110880.8
申请日：1983-10-31
申请人： UNION CARBIDE CORPORATION
发明人： Koleske, Joseph Victor , Domeier, Linda Ann
IPC分类号： C08F299/04 , C08F220/28 , C08F220/20 , C08L67/06
CPC分类号： C08G63/08 , C08F220/28 , C08F299/026
摘要： Described herein are compositions containing a reactive monomer derived from the reaction product of a hydroxyalkyl acrylate or methacrylate and a lactone. These compositions can be reacted with other ethylenically unsaturated monomers to produce curable oligomers and polymers than can be made into high quality industrial finishes by incorporation of various conventional crosslinking agents, plus other normally used formulating ingredients.
摘要翻译：本文描述的是含有源自丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯和内酯的反应产物的反应性单体的组合物。这些组合物可以与其它烯键式不饱和单体反应以制备可固化的低聚物和聚合物，可以通过掺入各种常规的交联剂加上其它通常使用的配方成分制成高质量的工业涂饰。

6. 发明公开

EP0068487A3 Curable molding compositions 无效
标题翻译：可固化成型组合物
公开(公告)号：EP0068487A3
公开(公告)日：1983-10-05
申请号：EP82105734
申请日：1982-06-28
申请人： UNION CARBIDE CORPORATION
发明人： Domeier, Linda Ann
IPC分类号： C08F299/02 , C08F299/04 , C08L101/00 , C08F299/06 , C08F220/20 , C08F220/56 , B29F01/00
CPC分类号： C08F299/04 , C08F290/14
摘要： Descriped herein are curable molding compositions used for the rapid fabrication of fiber-reinforced thermoset resin articles having improved mechanical properties comprising a mixture of:
(a) a thermosettable organic material containing two or more polymerizable carbon-carbon double bonds, (b) acrylic or methacrylic acid or a functionalized derivative thereof having a molecular weight of less than 300 which is different from (a), and (c) an ethylenically unsaturated monomer which is soluble in and copolymerizable with (a) and (b) and which is different from (a) and (b). The compositions can also contain one or more fibers with a melting point or a glass transition tempe- I rature above about 130°C.
摘要翻译：本文描述的是用于快速制造具有改进的机械性能的纤维增强热固性树脂制品的可固化模塑组合物，其包括以下混合物：（a）含有两个或多个可聚合碳 - 碳双键的可热固的有机材料，（b）丙烯酸或甲基丙烯酸或其与（a）不同的分子量小于300的官能化衍生物，和（c）可溶于（a）和（b）并且可与（a）和（b）共聚的烯属不饱和单体）（a）和（b）。组合物还可以含有一种或多种熔点或玻璃化转变温度高于约130℃的纤维。

7. 发明公开

EP0068512A2 Process for preparing fiber reinforced molded articles 失效
标题翻译：一种用于生产纤维增强模塑制品的过程。
公开(公告)号：EP0068512A2
公开(公告)日：1983-01-05
申请号：EP82105844.3
申请日：1982-06-30
申请人： UNION CARBIDE CORPORATION
发明人： Domeier, Linda Ann , Angell, Richard Gordon
IPC分类号： B29D3/02 , C08F299/02 , C08L101/00 , C08F220/20
CPC分类号： B29C70/48 , B29C33/34 , B29C41/08 , B29C43/50 , B29C70/345 , B29K2105/24
摘要： Described herein is an improved process for rapidly fabricating fiber reinforced thermoset resin articles comprising: (a) providing in a heatable matched metal die mold a bonded web of one or more fibers with a melting point or a glass transition temperature above about 130°C, (b) providing in an accumulator zone a liquid body of a thermosettable organic material having a viscosity determined at 120°C, in the absence of curing agent, of less than about 50 centipoises. which is curable upon heating to a thermoset resin composition, the viscosity of said liquid body being maintained essentially constant in the accumulator zone by keeping its temperature below that at which curing of said materials is substantial, (c) closing said mold containing said web, (d) injecting at least a portion of said thermosettable organic material under pressure from said accumulator zone into the mold to thereby fill the cavity in said mold, (e) initiating the curing of said materials by subjecting the materials to a temperature by heating the mold, which is above the temperature at which the curing of said materials is initiated, and (f) opening said molding and removing the cured thermoset article therefrom, wherein the improvement comprises improving the release of the cured article from the mold by increasing the cross-link density of the cured thermosettable organic material in the molded article. Also described herein are curable molding compositions used for the rapid fabrication of fiber-reinforced thermoset resin articles having improved mold release characteristics.
摘要翻译：描述为包括快速制造纤维增强的热固性树脂制品的改进的方法：（a）在可加热的匹配金属提供具有的熔点或玻璃化转变温度高于约130℃到模具的一个或多个纤维的粘合纤网，（b）在蓄能器区提供在具有在120℃下采，在不存在固化剂，小于约50厘泊的确定性的粘度的热固性有机材料，所有这些是可固化在加热时热固性树脂组合物的液状体，所述液体体的粘度被保持在蓄能器区基本上是恒定的通过保持其温度低于没有在所述的在固化材料是可观的（c）中封闭所述模具含有所述幅材，（d）中注入至少所述热固性有机的一部分材料从所述储液器区压力下进入模具，从而填充在所述模具（e）通过使吨启动所述材料的固化腔室，哎通过加热模具材料的温度，所有这些是上述在所述材料的固化开始温度，和（f）打开所述模制和从除去固化的热固性制品那里，worin改进之处包括改善固化的释放通过在模塑制品中提高固化热固性有机材料的交联密度从模具的制品。因此，在描述的是用于具有改进的脱模特性的纤维增强的热固性树脂制品的快速制造可固化的模塑组合物。

8. 发明公开

EP0068511A2 Process of manufacturing fiber-reinforced thermoset articles 失效
标题翻译： Verfahren zur Herstellung von vernetzten，fäserverstärktenFormstücken。
公开(公告)号：EP0068511A2
公开(公告)日：1983-01-05
申请号：EP82105843.5
申请日：1982-06-30
申请人： UNION CARBIDE CORPORATION
发明人： Gardner, Hugh Chester , Domeier, Linda Ann
IPC分类号： C08F299/02 , C08F299/04 , C08F4/00 , C08L101/00 , C08F220/20 , C08F220/56
CPC分类号： C08F4/00 , C08F290/14 , C08F299/0442
摘要： Described herein are curable molding compositions used for the rapid production of fiber-reinforced thermoset resin articles having improved mechanical properties, which composition comprises:

(a) a thermosettable organic material containing two or more polymerizable carbon-carbon double bonds,
(b) an ethylenically unsaturated monomer which forms a liquid homogeneous mixture with and is copolymerizable with (a) and is different from (a), and
(c) an effective amount of an initiator or a mixture of initiators characterized by a ten-hour half life temperature, or in the case of a mixture of initiators, an average ten-half hour life temperature, of greater than about 50°C and less than 105°C, which produces on decomposition less than 1.0 milliliter of gas per gram of resin as measured at a temperature of 25°C and a pressure of one atmosphere.
摘要翻译：本文描述了用于快速生产具有改进的机械性能的纤维增强热固性树脂制品的可固化模塑组合物，该组合物包含：（a）含有两个或更多个可聚合碳 - 碳双键的可热固的有机材料，（b）烯属形成与（a）并且可与（a）不同的液体均匀混合物的不饱和单体，和（c）有效量的以十小时半衰期为特征的引发剂或引发剂的混合物，或在引发剂的混合物的情况下，平均半小时寿命大于约50℃且小于105℃，其在分解时产生小于1.0毫升气体，每克树脂在温度下测量 25℃和一个大气压。

9. 发明授权

EP0129723B1 Curable poly(acrylate) molding compositions containing a thermoplastic polymer low profile additive 失效
标题翻译：含有热塑性聚合物的可固化聚（丙烯酸酯）成型组合物低配方添加剂
公开(公告)号：EP0129723B1
公开(公告)日：1991-12-18
申请号：EP84106003.1
申请日：1984-05-25
申请人： UNION CARBIDE CORPORATION
发明人： Domeier, Linda Ann
IPC分类号： C08F220/20 , C08F291/00 , C08F263/04
CPC分类号： C08F291/00 , C08F222/1006 , C08F257/02 , C08F263/04 , C08F212/34 , C08F220/12 , C08F220/20

10. 发明授权

EP0068511B1 Process of manufacturing fiber-reinforced thermoset articles 失效
标题翻译：制造纤维增强热塑性制品的工艺
公开(公告)号：EP0068511B1
公开(公告)日：1989-02-01
申请号：EP82105843.5
申请日：1982-06-30
申请人： UNION CARBIDE CORPORATION
发明人： Gardner, Hugh Chester , Domeier, Linda Ann
IPC分类号： C08F299/02 , C08F299/04 , C08F4/00 , C08L101/00 , C08F220/20 , C08F220/56
CPC分类号： C08F4/00 , C08F290/14 , C08F299/0442

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