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    • 2. 发明公开
    • CERMET AND COATED CERMET
    • CERMET UND BESCHICHTETES CERMET
    • EP2407263A1
    • 2012-01-18
    • EP10750847.5
    • 2010-03-10
    • Tungaloy Corporation
    • TAMURA, KeitaroTAKESAWA, DaisukeHARA, HirokiKITAMURA, KozoTANIGUCHI, YasuroHAYASHI, KojiMATSUMOTO, AkihiroCHO, Sung-Pyo
    • B23B27/14C22C1/05C22C29/04
    • C22C29/04C22C2204/00C23C14/06C23C16/30Y10T428/26Y10T428/30Y10T428/31678
    • The present invention is to provide a cermet which comprising a hard phase which contains W and nitrogen, and comprises at least one selected from a carbide, nitride and carbonitride of a metal comprising Ti as a main component, and a binder phase comprising an iron group metal as a main component, wherein a W amount contained in the whole cermet is 5 to 40% by weight, an interfacial phase comprising a complex carbonitride with a larger W amount than a W amount of the hard phase being present between the hard phase and the hard phase, and when a W amount contained in the interfacial phase based on the whole metal element is represented by Wb (atomic %), and a W amount contained in the hard phase based on the whole metal element is represented by Wh (atomic %), then, an atomic ratio of Wb to Wh (Wb/Wh) being 1.7 or more, which is excellent in fracture resistance and wear resistance.
    • 本发明提供一种金属陶瓷,其包含含有W和氮的硬相,并且包含选自包含Ti作为主要成分的金属的碳化物,氮化物和碳氮化物中的至少一种,以及包含铁基团的粘结相 金属作为主要成分,其中包含在整个金属陶瓷中的W含量为5〜40重量%,界面相包含复合碳氮化物,其中W量大于硬相的W量在硬相和 硬质相,并且当基于整个金属元素包含在界面相中的W量由Wb(原子%)表示时,并且基于整个金属元素包含在硬质相中的W量由Wh(原子)表示 %),则Wb与Wh(Wb / Wh)的原子比为1.7以上,耐断裂性和耐磨性优异。
    • 3. 发明公开
    • CERMET AND COATED CERMET
    • CERMET UND BESCHICHTETES CERMET
    • EP2564958A1
    • 2013-03-06
    • EP11774978.8
    • 2011-04-26
    • Tungaloy Corporation
    • TAMURA, KeitaroTANIGUCHI, YasuroHAYASHI, Koji
    • B23B27/14C22C29/04C22C1/05
    • C22C29/04B22F3/101B22F3/1021
    • This is to provide a cermet excellent in wear resistance and fracture resistance, and its tool life is stable.
      The cermet comprises First hard phase of a complex carbonitride solid solution, Second hard phase of WC, and a binder phase mainly comprising Co and Ni as a main component(s), First hard phase comprises core/rim structure wherein the core is a complex carbonitride solid solution represented by (Ti 1-x- yL x Mo y )(C 1-z N z ), wherein L represents at least one element selected from the group consisting of Zr, Hf, Nb and Ta, x, y and z each satisfy 0.01≦x≦0.5, 0≦y≦0.05 and 0.05≦z≦0.75, and the rim is a complex carbonitride solid solution represented by (Ti 1-a-b-d R a Mo b W d )(C 1-e N e ), wherein R represents at least one element selected from the group consisting of Zr, Hf, Nb and Ta, a, b, d and e each satisfy 0.01≦a≦0.5, 0≦b≦0.05, 0.01≦d≦0.5 and 0.05≦e≦0.75, and a number of the core/rim structure grains of First hard phase which satisfy the maximum thickness r max of the rim of the core/rim structure grains of First hard phase and the minimum thickness r min of the rim of the core/rim structure grains of First hard phase being 0.2≦(r mix /r max )≦1 is 85% or more based on the total number of the core/rim structure grains of First hard phase.
    • 这是为了提供耐磨性和耐断裂性优异的金属陶瓷,其使用寿命是稳定的。 金属陶瓷包括复合碳氮化物固溶体的第一硬质相,WC的第二硬质相和主要包含Co和Ni作为主要成分的粘结相。第一硬质相包括芯/边缘结构,其中核是复合物 (Ti 1-x-yL x Mo y)(C 1-z N z)表示的碳氮化物固溶体,其中L表示选自Zr,Hf,Nb和Ta中的至少一种元素,x,y和 z分别满足0.01‰| x‰|0.5,0‰|‰| 0.05和0.05‰| z‰|0.75,边缘是由(Ti 1-abd R a Mo b W d)表示的复杂碳氮化物固溶体, (C 1-e N e),其中R表示选自Zr,Hf,Nb和Ta中的至少一种元素,a,b,d和e各自满足0.01‰| a‰|0.5,0‰| b‰|0.05,0.01‰| d‰| 0.5和0.05‰|‰|0.75,第一硬质相的芯/边缘结构晶粒数满足芯/边缘边缘的最大厚度r max 第一硬石的结构颗粒 e和第一硬质相的芯/边缘结构晶粒边缘的最小厚度r min为0.2‰|(r mix / r max)‰|1为85%以上,基于芯/边缘的总数 第一硬相结构晶粒。