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    • 6. 发明公开
    • POLYMER ELECTROLYTE COMPOSITION AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE-ELECTROLYTE ASSEMBLY, AND SOLID POLYMER FUEL CELL USING SAME
    • 聚对苯二甲酸丁二醇酯,聚乙烯醇缩丁醛,聚乙烯醇缩丁醛
    • EP3131145A1
    • 2017-02-15
    • EP15776250.1
    • 2015-04-03
    • Toray Industries, Inc.
    • UMEDA, HiroakiIZUHARA, DaisukeKUNITA, Tomoyuki
    • H01M8/02C08K5/34C08K5/3445C08K5/3462C08K5/49C08L71/08C08L101/02H01B1/06H01M8/10
    • H01M8/1051H01M8/1004H01M8/1025H01M8/1044H01M8/1046H01M8/1048H01M2008/1095H01M2300/0082
    • [Problem]
      To provide: a polymer electrolyte composition that has excellent chemical stability that makes it possible to withstand a strong oxidizing atmosphere during fuel cell operation, that makes it possible to achieve excellent protonic conductivity under low humidity conditions, excellent mechanical strength, and excellent physical durability, and that is highly practical; and a polymer electrolyte membrane, a membrane-electrode assembly, and a solid polymer fuel cell that use the polymer electrolyte composition. [Solution] A polymer electrolyte composition that comprises at least an ionic group-containing polymer (A), an organic phosphorus-based additive (C), and a nitrogen-containing heteroaromatic ring system additive (D) and that is characterized by the nitrogen-containing heteroaromatic ring system additive (D) comprising at least three nitrogen-containing heteroaromatic rings within a molecule thereof. In addition, the polymer electrolyte membrane, the catalyst layer-equipped electrolyte membrane, the membrane-electrode assembly, and the solid polymer fuel cell of the present invention are characterized by being configured using the polymer electrolyte composition.
    • 本发明提供一种具有优异的化学稳定性的高分子电解质组合物,能够在燃料电池运转时耐受强氧化气氛,能够在低湿度条件下获得优异的质子传导性,优异的机械强度,优异的 物理耐久性高,实用性强; 以及使用高分子电解质组合物的高分子电解质膜,膜 - 电极组件和固体高分子型燃料电池。 [溶液]至少含有含离子性基团的聚合物(A),有机磷系添加剂(C)和含氮杂芳环系添加剂(D)的高分子电解质组合物,其特征在于,所述氮 (D),其在其分子内包含至少三个含氮杂芳环。 此外,本发明的高分子电解质膜,装有催化剂层的电解质膜,膜电极接合体以及固体高分子型燃料电池的特征在于,使用高分子电解质组合物构成。