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    • 1. 发明公开
    • LIQUID CRYSTAL POLYESTER FIBERS, AND PRODUCTION METHOD THEREFOR
    • 赫尔辛基广播公司
    • EP3101161A1
    • 2016-12-07
    • EP15742762.6
    • 2015-01-21
    • Toray Industries, Inc.
    • FUNATSU YoshitsuguMASUDA MasatoKAWAMATA Chieko
    • D01F6/84D01F6/62
    • D01F6/62D01D5/08D01F6/84D10B2331/04
    • Provided is a liquid crystal polyester fiber having high strength, high elastic modulus, high abrasion resistance, excellent processability, and little thermal deformation at high temperature, and also provided is a production method thereof. A liquid crystal polyester fiber, characterized in that the peak half-value width of the endothermic peak (Tm1) observed when measuring by differential calorimetry under rising temperature conditions starting at 50°C and increasing 20°C/min is 15°C or higher, the polystyrene-converted weight-average molecular weight is between 250,000 and 2,000,000 inclusive, the peak temperature of the loss tangent (tanδ) is between 100°C and 200°C inclusive, and the peak value of the loss tangent (tanδ) is between 0.060 and 0.090 inclusive. A mesh fabric comprising the liquid crystal polyester fiber. A production method for melt liquid crystal polyester fiber, characterized in that liquid crystal polyester fiber obtained by melt-spinning is subject to solid-phase polymerization, and subsequently heat treated at a stretch ratio of at least 0.1% and under 3.0% at a temperature at least 50°C higher than the endothermic peak temperature (Tm1) as observed when measuring by differential calorimetry under rising temperature conditions starting at 50°C and increasing 20°C/min.
    • 本发明提供高强度,高弹性模量,高耐磨性,优异的加工性,高温下的热变形少的液晶聚酯纤维。 一种液晶聚酯纤维,其特征在于,在从50℃开始升高20℃/分钟的上升温度条件下通过差示量热法测定时观察到的吸热峰(Tm1)的峰值半值宽度为15℃以上 ,聚苯乙烯换算的重均分子量在250,000和2,000,000之间,损耗角正切(tan')的峰值温度在100℃和200℃之间,损耗角正切(tan')的峰值 )在0.060和0.090之间。 包含液晶聚酯纤维的网状织物。 熔融液晶聚酯纤维的制造方法,其特征在于,将通过熔融纺丝得到的液晶聚酯纤维进行固相聚合,然后在温度为0.1%以上且3.0%以下的拉伸倍率进行热处理 比起在50℃开始升高20℃/分钟的上升温度条件下通过差示量热法测得的吸热峰温度(Tm1)高至少50℃。
    • 4. 发明公开
    • LIQUID CRYSTAL POLYESTER FIBERS AND METHOD FOR PRODUCING THE SAME
    • R R R R R R R R R R R R R R R R R R R
    • EP2407583A1
    • 2012-01-18
    • EP10750740.2
    • 2010-03-04
    • Toray Industries, Inc.
    • FUNATSU YoshitsuguMAEDA YuheiSUZUKI NorioKATSUTA Hiroo
    • D02J13/00D01F6/62D06M15/643
    • D06M15/643C09K19/3809D01D10/02D01F6/62D01F6/84D02J13/00Y10T428/298Y10T442/183
    • Disclosed are liquid crystal polyester fibers, which have a peak half-width of 15°C or greater at an endothermic peak (Tm1) observed by differential calorimetry under a temperature elevation of 20°C/minute from 50°C, polystyrene equivalent weight average molecular weight of 250,000 or more and 2,000,000 or less, and a variable waveform of less than 10% in terms of the half inert diagram mass waveform determined by a Uster yarn irregularity tester. Also disclosed is a method for producing liquid crystal polyester fibers, wherein liquid crystal polyester fibers are formed into a package, the fibers are then subjected to solid-phase polymerization, and the solid-phase polymerized liquid crystal polyester fibers are unrolled from the package and successively heat treated without being once taken up. The heat treatment temperature is controlled at a temperature of the endothermic peak temperature (Tm1) of the solid-phase polymerized liquid crystal polyester fibers + 60°C or higher, and the speeds of the fibers before and after heat treatment are regulated, respectively, by first and second rollers.
    • 公开了在50℃的温度升高20℃/分钟下通过差示量热法观察到的吸热峰(Tm1)的峰值半宽度为15℃以上的液晶聚酯纤维,聚苯乙烯换算重量平均值 分子量为25万以上且2,000,000以下,以及由乌斯特纱线不均匀性测定仪确定的半惰性图质量波形的小于10%的可变波形。 还公开了一种液晶聚酯纤维的制造方法,其中将液晶聚酯纤维形成包装,然后将纤维进行固相聚合,并将固相聚合的液晶聚酯纤维从包装上展开, 连续热处理而不被一次吸收。 将热处理温度控制在固相聚合液晶聚酯纤维的吸热峰温度(Tm1)+ 60℃以上的温度下,分别调节热处理前后的纤维速度, 通过第一和第二辊。