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    • 1. 发明公开
    • METALLIZED CERAMIC MOLDING, PROCESS FOR PRODUCING THE SAME AND PELTIER DEVICE
    • METALLISIERTERKERAMIKFORMKÖRPER,HERSTELLUNGSVERFAHRENDAFÜRUND PELTIER-VORRICHTUNG
    • EP1721880A1
    • 2006-11-15
    • EP05709838.6
    • 2005-02-07
    • TOKUYAMA CORPORATIONThe circle for the promotion of science and engineering
    • FUKUYAMA, Hiroyuki c/o Inst. MultidisciplinaryYONEDA, TakehikoKIKUTANI, Shingo
    • C04B41/90C04B41/88H01L35/34
    • H01L35/34C04B41/009C04B41/52C04B41/90C04B2111/00844H01L35/32C04B41/0072C04B41/4519C04B41/4556C04B41/5031C04B41/51C04B35/581
    • [PROBLEMS] To provide a metallized non-oxide ceramic shaped article having high adhesive strength between a metal layer and a substrate and the adhesion durability and to provide a process for producing the same.
      [MEANS FOR SOLVING PROBLEMS] The process for producing a metallized shaped article includes: a heating step of heating a non-oxide ceramic shaped article to a temperature at or above a temperature, which is 300°C below the oxidation start temperature of the non-oxide ceramics, without substantial dissolution of oxygen in a solid solution form during heating; an oxidation step of bringing the non-oxide ceramic substrate heated in the heating step into contact with an oxidizing gas and then holding the non-oxide ceramic substrate at a temperature above the oxidation start temperature of the non-oxide ceramics to oxidize the surface of the non-oxide ceramic shaped article and thus to form an oxide layer on the surface of the non-oxide ceramic substrate; and a metallization step of forming a metal layer on the surface of the oxide layer in the non-oxide ceramic shaped article having an oxide layer on its surface produced in the oxidation step.
    • 本发明提供一种在金属层和基材之间具有高粘合强度的金属化非氧化物陶瓷成型制品和粘合耐久性,并提供其制造方法。 解决问题的方法金属化成型制品的制造方法包括:将非氧化物陶瓷成型制品加热至低于非氧化物陶瓷成形制品的氧化开始温度300℃以下的温度的加热步骤, 氧化物陶瓷,在加热期间没有固体溶液形式的氧的实质溶解; 使在加热步骤中加热的非氧化物陶瓷基板与氧化气体接触,然后将非氧化物陶瓷基板保持在高于非氧化物陶瓷的氧化开始温度的温度下氧化表面的氧化步骤 非氧化物陶瓷成形体,从而在非氧化物陶瓷基板的表面形成氧化物层; 以及金属化步骤,在氧化步骤中产生的在其表面上具有氧化物层的非氧化物陶瓷成型制品的氧化物层的表面上形成金属层。