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1. 发明公开

EP2152763A2 CONTROLLED FREE RADICAL GRAFTING FROM POLYOLEFINS 有权
标题翻译：聚烯烃的可控自由基接枝
公开(公告)号：EP2152763A2
公开(公告)日：2010-02-17
申请号：EP07853260.3
申请日：2007-12-06
申请人： The Regents of the University of California
发明人： BAZAN, Guillermo, C. , COFFIN, Robert, C.
IPC分类号： C08F4/44
CPC分类号： C08F297/02 , C08F255/00 , C08F255/02 , C08F297/08 , C08L51/006 , C08L51/06 , C08L53/00 , C08L53/005 , C08L2666/02
摘要： Described are novel monomers bearing functionalities capable of initiating control free radical reactions, and a novel process using these initiating monomers in the co-polymerization of an olefin for the formation of well-controlled polyethylene graft polymers where the graft component is derived from controlled free radical polymerization reactions. The initiating monomers are produced by combining an amount of 5-norbornen-2-ol with a hydride or amine for a predetermined amount of time to form a mixture; and adding an amount of an alkyl or acyl halide to said mixture. Polymerization of an olefin with an initiating monomer is conducted in the presence of a metal compound, where the metal compound is comprised of a Group VIII transition metal complex.

2. 发明公开

EP1673410A2 CONFORMATIONALLY FLEXIBLE CATIONIC CONJUGATED POLYMERS 有权
标题翻译： KONFORMATIONSFLEXIBLE阳离子共轭聚合物
公开(公告)号：EP1673410A2
公开(公告)日：2006-06-28
申请号：EP04821601.4
申请日：2004-09-17
申请人： The Regents of the University of California
发明人： BAZAN, Guillermo, C. , LIU, Bin
IPC分类号： C08L35/06
CPC分类号： H01B1/122 , C08G61/02 , C08G61/10 , C08G61/123 , C08G61/126 , C08G73/02 , C08G73/08 , C40B40/04
摘要： Methods, compositions and articles of manufacture involving cationic conjugated conformationally flexible polymers are provided. A method for the synthesis of cationic water-soluble polymers with linkages along the polymer main chain structure which disrupt the ability of the polymers to form extended-rod structures is provided. Such polymers may serve in the fabrication of novel optoelectronic devices and in the development of highly efficient biosensors. The invention further relates to the application of these polymers in assay methods.

3. 发明授权

EP2152763B1 CONTROLLED FREE RADICAL GRAFTING FROM POLYOLEFINS 有权
标题翻译：聚烯烃的可控自由基接枝
公开(公告)号：EP2152763B1
公开(公告)日：2016-05-04
申请号：EP07853260.3
申请日：2007-12-06
申请人： The Regents of the University of California
发明人： BAZAN, Guillermo, C. , COFFIN, Robert, C.
IPC分类号： C08F4/44 , C08F255/00 , C08F255/02 , C08F297/08 , C08L51/00 , C08L51/06 , C08L53/00 , C08F210/00
CPC分类号： C08F297/02 , C08F255/00 , C08F255/02 , C08F297/08 , C08L51/006 , C08L51/06 , C08L53/00 , C08L53/005 , C08L2666/02

4. 发明公开

EP1597290A2 A METAL CATALYST FOR OLEFIN POLYMERIZATION AND CO-POLYMERIZATION WITH FUNCTIONAL MONOMERS 有权
标题翻译：金属催化剂烯烃聚合和共聚功能性单体
公开(公告)号：EP1597290A2
公开(公告)日：2005-11-23
申请号：EP04715669.0
申请日：2004-02-27
申请人： The Regents of the University of California
发明人： BAZAN, Guillermo, C. , GHOSH, Prasenjit
IPC分类号： C08F10/02 , C08F4/80
CPC分类号： C08F10/02 , C08F110/02 , C08F210/02 , C08F4/80 , C08F2500/03 , C08F2500/10 , C08F216/02 , C08F2500/25
摘要： A catalyst is disclosed for the polymerization and co-polymerization of olefins with functionalized monomers. The catalyst is formed from a combination of two neutral metal complexes, L(iPr2)M(CH2Ph)(PMe3) [L = N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)propanamide] and M(COD)2 (COD = cyclooctadiene). The catalyst displays a unique mode of action and performs at ambient conditions producing high molecular weight polyolefins and co-polymers with functional groups. The polymerized olefins include ethylene, α-olefins and functionalized olefins.

5. 发明公开

EP1534857A2 METHODS AND COMPOSITIONS FOR DETECTION AND ANALYSIS OF POLYNUCLEOTIDES USING LIGHT HARVESTING MULTICHROMOPHORES 有权
标题翻译：使用轻收获多色流变仪检测和分析多核苷酸的方法和组合物
公开(公告)号：EP1534857A2
公开(公告)日：2005-06-01
申请号：EP03761235.5
申请日：2003-06-20
申请人： The Regents of the University of California
发明人： BAZAN, Guillermo, C. , GAYLORD, Brent, S.
IPC分类号： C12Q1/68 , C07H21/02
CPC分类号： C12Q1/6818 , C12Q1/682 , Y10T436/143333 , C12Q2565/107 , C12Q2525/107 , C12Q2527/125
摘要： Methods, compositions and articles of manufacture for assaying a sample for a target polynucleotide are provided. A sample suspected of containing the target polynucleotide is contacted with a polycationic multichromophore and a sensor PNA complementary to the target polynucleotide. The sensor PNA comprises a signaling chromophore to absorb energy from the excited multichromophore and emit light in the presence of the target polynucleotide. The methods can be used in multiplex form. Kits comprising reagents for performing such methods are also provided.
摘要翻译：提供了用于测定靶标多核苷酸的样品的方法，组合物和制品。将怀疑含有靶多核苷酸的样品与聚阳离子多发色团和与靶多核苷酸互补的传感器PNA接触。传感器PNA包含信号发色团以吸收来自激发的多发色团的能量并在靶多核苷酸存在下发光。这些方法可以以多重形式使用。还提供了包含用于执行这种方法的试剂的试剂盒。

6. 发明授权

EP2643865B1 ORGANIC SMALL MOLECULE SEMICONDUCTING CHROMOPHORES FOR USE IN ORGANIC ELECTRONIC DEVICES 有权
公开(公告)号：EP2643865B1
公开(公告)日：2020-09-09
申请号：EP11845839.7
申请日：2011-11-22
申请人： The Regents of the University of California
发明人： WELCH, Gregory, C. , HOVEN, Corey, V. , NGUYEN, Thuc-quyen , BAZAN, Guillermo, C.
IPC分类号： H01L51/46

7. 发明授权

EP1838752B1 CATIONIC CONJUGATED POLYMERS SUITABLE FOR STRAND-SPECIFIC POLYNUCLEOTIDE DETECTION IN HOMOGENEOUS AND SOLID STATE ASSAYS 有权
标题翻译：阳离子共轭聚合物适用于均匀和固态测定中特异性多核苷酸检测
公开(公告)号：EP1838752B1
公开(公告)日：2017-10-04
申请号：EP06718009.1
申请日：2006-01-10
申请人： The Regents of the University of California
发明人： BAZAN, Guillermo, C. , LIU, Bin, National University of Singapore
IPC分类号： C08G61/10 , G01N21/64
CPC分类号： C08G61/02 , C08G61/122 , C08G61/123 , C12Q1/6818 , C12Q1/6837 , G01N21/6428 , G01N21/6452 , G01N2021/6419 , G01N2021/6439 , C12Q2563/131 , C12Q2537/119 , C12Q2525/107

8. 发明授权

EP1673410B1 CONFORMATIONALLY FLEXIBLE CATIONIC CONJUGATED POLYMERS 有权
标题翻译： KONFORMATIONSFLEXIBLE阳离子共轭聚合物
公开(公告)号：EP1673410B1
公开(公告)日：2016-06-15
申请号：EP04821601.4
申请日：2004-09-17
申请人： The Regents of the University of California
发明人： BAZAN, Guillermo, C. , LIU, Bin
IPC分类号： C08L35/06 , C08G61/00 , C08G73/00 , H01B1/12
CPC分类号： H01B1/122 , C08G61/02 , C08G61/10 , C08G61/123 , C08G61/126 , C08G73/02 , C08G73/08 , C40B40/04

9. 发明公开

EP1838752A2 CATIONIC CONJUGATED POLYMERS SUITABLE FOR STRAND-SPECIFIC POLYNUCLEOTIDE DETECTION IN HOMOGENEOUS AND SOLID STATE ASSAYS 有权
标题翻译：阳离子聚合物共轭培养特异性多核苷酸检测中的介质固状态测试安排
公开(公告)号：EP1838752A2
公开(公告)日：2007-10-03
申请号：EP06718009.1
申请日：2006-01-10
申请人： The Regents of the University of California
发明人： BAZAN, Guillermo, C. , LIU, Bin, National University of Singapore
IPC分类号： C08G61/10 , G01N21/64
CPC分类号： C08G61/02 , C08G61/122 , C08G61/123 , C12Q1/6818 , C12Q1/6837 , G01N21/6428 , G01N21/6452 , G01N2021/6419 , G01N2021/6439 , C12Q2563/131 , C12Q2537/119 , C12Q2525/107
摘要： The invention further relates to polycationic multichromophores, which may be conjugated polymers, and methods, articles and compositions employing them as described herein. In some aspects, the invention relates to methods, articles and compositions for the detection and analysis of biomolecules in a sample. Provided assays include those determining the presence of a target biomolecule in a sample or its relative amount, or the assays may be quantitative or semi-quantitative. The methods can be performed on a substrate. The methods can be performed in an array format on a substrate, which can be a sensor. In some embodiments, detection assays are provided employing sensor biomolecules that do not comprise a fluorophore that can exchange energy with the cationic multichromophore. In some aspects biological assays are provided in which energy is transferred between one or more of the multichromophore, a label on the target biomolecule, a label on the sensor biomolecule, and/or a fluorescent dye specific for a polynucleotide, in all permutations. The multichromophore may interact at least in part electrostatically with the sensor and/or the target, and an increase in energy transfer with the polymer may occur upon binding of the sensor and the target. Other variations of the inventions are described further herein.
摘要翻译：本发明还涉及到聚阳离子multichromophores，其可以是共轭聚合物，与方法，制品和组合物使用它们中的说明。在一些方面，本发明涉及用于在样品中检测和生物分子分析方法，制品和组合物。提供测定包括那些确定性采矿靶生物分子的样品中的存在或它的相对量，或测定法可以是定量或半定量的。该方法可以在衬底上执行。该方法可以以阵列来执行，在格式的基材，它可以是一个传感器。在一些实施方案中，提供了检测分析用人传感器的生物分子确实不包括荧光团也可以与阳离子交换多发能量。在一些方面中，其中能量被提供生物测定中的一个或多个多发的之间传送，在目标生物分子的标记，在传感器上生物分子的标记，和/或特异于多核苷酸的荧光染料，在所有排列。的多发色可以至少部分地静电与所述传感器和/或靶相互作用，并与能量转移以增加聚合物可以在所述传感器和所述靶标的结合好发。本发明的其它变型在进一步描述。

10. 发明授权

EP2721087B1 REGIOREGULAR PYRIDAL[2,1,3]THIADIAZOLE PI-CONJUGATED COPOLYMERS FOR ORGANIC SEMICONDUCTORS 有权
标题翻译：用于有机半导体的非对称吡啶[2,1,3]噻二唑共轭聚合物
公开(公告)号：EP2721087B1
公开(公告)日：2018-03-07
申请号：EP12801086.5
申请日：2012-06-18
申请人： The Regents of the University of California
发明人： TSENG, Hsin-Rong , BAZAN, Guillermo, C. , YING, Lei , HSU, Ben, B., Y. , WEN, Wen , WELCH, Gregory, C.
IPC分类号： H01L51/44 , C08G61/12 , C08G73/06
CPC分类号： H01L51/0036 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/148 , C08G2261/1646 , C08G2261/212 , C08G2261/3241 , C08G2261/3246 , C08G2261/344 , C08G2261/414 , C08G2261/91 , C08G2261/92 , H01L51/0043 , H01L51/0094 , H01L51/0533 , H01L51/0545 , Y02E10/549
摘要： A method of regioselectively preparing a pyridine-containing compound is provided. In particular embodiments, the method includes reacting halogen-functionalized pyridal[2,1,3]thiadiazole with organotin-functionalized cyclopenta[2,1-b:3,4-b′]dithiophene or organotin-functionalized indaceno[1,2-b:5,6-b′]dithiophene. Also provided is a method of preparing a polymer. The method includes regioselectively preparing a monomer that includes a pyridal[2,1,3]thiadiazole unit; and reacting the monomer to produce a polymer that includes a regioregular conjugated backbone section, wherein the section includes a repeat unit containing the pyridal[2,1,3]thiadiazole unit. A polymer that includes a regioregular conjugated backbone section, and electronic devices that include the polymer, are also provided.

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