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    • 2. 发明公开
    • Resin-coated seamless can
    • Harzbeschichtete nahtlose剂量
    • EP1149772A2
    • 2001-10-31
    • EP01301927.8
    • 2001-03-02
    • TOYO SEIKAN KAISHA LIMITED
    • Sato, KazuhiroFunagi, YujiMorofuji, Akihiko
    • B65D25/14B65D25/34B65D1/16
    • B32B15/08B32B27/36Y10T428/1355Y10T428/1359Y10T428/24942Y10T428/31681
    • A resin-coated seamless can satisfying such properties as high degree of workability, adhesiveness of film, resistance against high temperatures and wet heated condition, corrosion resistance and resistance against being dented. The resin-coated seamless can is formed of a resin-coated metal plate having substantially unoriented two layers including a surface layer and a lower layer serving as a resin layer on the inner surface side of the can, wherein the surface layer comprises a polyethylene terephthalate/isophthalate containing an isophthalic acid in an amount of from 3 to 13 mol% and having an intrinsic viscosity [η] of not smaller than 0.7, and the lower layer comprises a polyethylene terephthalate/isophthalate containing the isophthalic acid in an amount of from 8 to 25 mol%, which is larger than that of the surface layer, and having an intrinsic viscosity [η] of not smaller than 0.7, the resin layer of the upper part of the can on the inner surface side satisfying the following formula (1), Cs > Ca    where Cs = Is 973 /Is 795 , Ca = Ia 973 /Ia 795 , Is 973 is an infrared absorption intensity at 973 cm -1 measured for the surface layer, Is 795 is an infrared absorption intensity at 795 cm -1 measured for the surface layer, Ia 973 is an infrared absorption intensity at 973 cm -1 measured for the lower layer and Ia 795 is an infrared absorption intensity at 795 cm -1 measured for the lower layer,
      and, preferably, the coefficient of surface orientation of the resin layer on the inner surface side on the bottom of the can being not larger than 0.05.
    • 可以满足树脂涂层的无缝化,可以满足高加工性,膜的粘合性,耐高温性和湿热条件,耐腐蚀性和耐凹陷性等特性。 树脂涂覆的无缝罐由具有基本上未定向的两层的树脂涂覆的金属板形成,包括在罐的内表面侧上具有表层和作为树脂层的下层,其中表面层包括聚对苯二甲酸乙二醇酯 /间苯二甲酸酯,其含有3〜13摩尔%的间苯二甲酸,其特性粘度Ä不小于0.7,下层包含含有间苯二甲酸的聚对苯二甲酸乙二醇酯/间苯二甲酸酯,其含量为8 至25mol%,其特征粘度Ä等于0.7以上,表面侧的罐的上部的树脂层满足下式(1) ), Cs> Ca 其中Cs = Is973 / Is795,Ca = Ia973 / Ia795,Is973是在表面层测量的973cm -1处的红外吸收强度 ,Is795是红外吸收强度 对于表面层测量为795cm​​ -1,Ia973是对于下层测量的在973cm -1处的红外吸收强度,Ia795是对于下层测量的795cm​​ -1处的红外吸收强度, 并且优选地,罐底部的内表面侧的树脂层的表面取向系数不大于0.05。
    • 4. 发明公开
    • Resin-coated seamless can
    • 的树脂被覆无缝罐
    • EP1149772A3
    • 2004-04-14
    • EP01301927.8
    • 2001-03-02
    • TOYO SEIKAN KAISHA LIMITED
    • Sato, KazuhiroFunagi, YujiMorofuji, Akihiko
    • B65D25/14B65D25/34B65D1/16B32B27/36B32B15/08
    • B32B15/08B32B27/36Y10T428/1355Y10T428/1359Y10T428/24942Y10T428/31681
    • A resin-coated seamless can satisfying such properties as high degree of workability, adhesiveness of film, resistance against high temperatures and wet heated condition, corrosion resistance and resistance against being dented. The resin-coated seamless can is formed of a resin-coated metal plate having substantially unoriented two layers including a surface layer and a lower layer serving as a resin layer on the inner surface side of the can, wherein the surface layer comprises a polyethylene terephthalate/isophthalate containing an isophthalic acid in an amount of from 3 to 13 mol% and having an intrinsic viscosity [η] of not smaller than 0.7, and the lower layer comprises a polyethylene terephthalate/isophthalate containing the isophthalic acid in an amount of from 8 to 25 mol%, which is larger than that of the surface layer, and having an intrinsic viscosity [η] of not smaller than 0.7, the resin layer of the upper part of the can on the inner surface side satisfying the following formula (1),Cs > Ca    where Cs = Is 973 /Is 795 , Ca = Ia 973 /Ia 795 , Is 973 is an infrared absorption intensity at 973 cm -1 measured for the surface layer, Is 795 is an infrared absorption intensity at 795 cm -1 measured for the surface layer, Ia 973 is an infrared absorption intensity at 973 cm -1 measured for the lower layer and Ia 795 is an infrared absorption intensity at 795 cm -1 measured for the lower layer, and, preferably, the coefficient of surface orientation of the resin layer on the inner surface side on the bottom of the can being not larger than 0.05.