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    • 6. 发明公开
    • PROCESS FOR PREPARING COMPOSITES BASED ON ORIENTED MESOGENIC THERMOSET RESINS
    • 用于生产热固性中介,基塑料含复合材料
    • EP0708796A1
    • 1996-05-01
    • EP93917218.0
    • 1993-07-15
    • THE DOW CHEMICAL COMPANY
    • JONES, Robert, E., Jr.EARLS, Jimmy, D.HEFNER, Robert, E., Jr.
    • C08J5C07D303C08G59C09K19
    • C08J5/24C07D303/24C08G59/22Y10T428/1059Y10T428/1073
    • Continuous fiber reinforced oriented mesogen-containing resin matrix composites are prepared by (A) saturating a continuous fiber substrate material with a curable composition comprising (1) at least one mesogen-containing resin which contains an average of more than one vicinal epoxide group, thiirane group, cyanate group or vinyl ester group per molecule; and, optionally, (2) a curing amount of at least one curing agent and/or curing catalyst therefor; (B) arranging one or more saturated continuous fiber substrate material(s) formed in step (A) into a desired configuration; (C) subjecting the arranged saturated continuous fiber substrate material(s) from step (B) to a temperature which causes the mesogen-containing resin to convert to a liquid crystalline state; (D) subjecting the heated arranged saturated continuous fiber substrate material(s) from step (C) to a pressure sufficient to cause flow induced shear in the interstices of said continuous fiber substrate; (E) subjecting the continuous fiber substrate material of step (D) to curing conditions either simultaneously with the application of pressure in step (D) and/or subsequent to said application of pressure; and (F) permitting the cured continuous fiber reinforced composite of step (E) to cool to room temperature; thereby forming a cured continuous fiber reinforced composite containing an oriented mesogen-containing resin matrix. These composites have improved properties as compared to composites which are not oriented.