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1. 发明公开

EP1070538A2 Metallo-organic polymers for gas separation and purification 无效
标题翻译： Metallorganische Polymere zur Gastrennung und Reinigung
公开(公告)号：EP1070538A2
公开(公告)日：2001-01-24
申请号：EP00306105.8
申请日：2000-07-18
申请人： THE BOC GROUP, INC.
发明人： Wang, Qing Min , Shen, Dongmin , Bülow, Martin , Lau, Miu Ling , Fitch, Frank R. , Deng, Shuguang
IPC分类号： B01J20/00 , B01J20/26 , B01D53/04 , B01D53/047
CPC分类号： B01D53/02 , B01D2253/202 , B01D2253/204 , B01D2257/402 , B01D2257/504 , B01D2257/702 , B01J20/226 , B01J20/26 , C08G79/00 , Y02C10/08 , Y02C20/10 , Y02P20/152 , Y02P20/153 , Y10S95/90
摘要： The present invention provides for methods and compositions for gas separation and purification utilizing a metallo-organic polymer adsorbent in processes for separating carbon dioxide, water, nitrogen oxides and hydrocarbons from gas streams. The metallo-organic polymer adsorbent composition has the formula:

[R(L) n ] m M n ,

wherein R represents an organic spacer selected from the group consisting of an organic cyclic or acyclic compound; L represents a ligation group substituted on the organic spacer selected from the group consisting of carboxylate group, -C(=O)O - ; dithiocarboxylate group, -C(=S)S - ; and β-diketonate group,
-C(=O)C(R')=C(-O - )-, wherein R' = H, or an aliphatic or aromatic group; M represents a transition metal or a rare earth metal m is the oxidation state of the transition or rare earth metal; and n is the number of the ligation group substituted on the organic spacer.
摘要翻译：本发明提供了在气流中分离二氧化碳，水，氮氧化物和烃的方法中利用金属有机聚合物吸附剂进行气体分离和净化的方法和组合物。金属有机聚合物吸附剂组合物具有下式：R（L）nmMn，其中R表示选自有机环状或非环状化合物的有机间隔物; L表示在选自羧酸酯基，-C（= O）O - 的有机间隔基上取代的连接基团。二硫代羧酸酯基，-C（= S）S - 和β-二酮基团，-C（= O）C（R'）= C（-O - ） - ，其中R'= H，或脂族或芳族基团; M表示过渡金属或稀土金属，m是过渡金属或稀土金属的氧化态; n是在有机间隔物上取代的连接基团的数目。

2. 发明公开

EP1717343A2 Method and apparatus for using solution based precursors for atomic layer deposition 审中-公开
标题翻译： Vorrichtung und Verfahren zurLösung-basierten Abscheidung von Atomschichten。
公开(公告)号：EP1717343A2
公开(公告)日：2006-11-02
申请号：EP06252213.1
申请日：2006-04-25
申请人： THE BOC GROUP, INC.
发明人： Ma, Ce , Wang, Qing Min , Helly, Patrick Joseph , Hogle, Richard Allen
IPC分类号： C23C16/455
CPC分类号： C23C16/45544 , C23C16/448 , C23C16/45525 , Y10T428/8305
摘要： A unique combination of solution stabilization and delivery technologies with special ALD operation is provided. A wide range of low volatility solid ALD precursors dissolved in solvents are used. Unstable solutes may be stabilized in solution and all of the solutions may be delivered at room temperature. After the solutions are vaporized, the vapor phase precursors and solvents are pulsed into a deposition chamber to assure true ALD film growth.
An ALD deposition system that can be used in the present invention includes solution vessel (10), for holding the dissolved precursor solution (precursor A), a liquid pump (20), to pump precursor A to a vaporizer (30), a vessel (40), for holding precursor B, such as water, a deposition chamber (50), having a monitoring device (60), therein, and an exhaust system (70).
摘要翻译：提供了具有特殊ALD操作的解决方案稳定和传送技术的独特组合。使用溶解在溶剂中的各种低挥发性固体ALD前体。不稳定的溶质可以在溶液中稳定，并且所有溶液可以在室温下输送。在溶液蒸发之后，气相前体和溶剂被脉冲进入沉积室以确保真正的ALD膜生长。可用于本发明的ALD沉积系统包括用于保持溶解的前体溶液（前体A）的溶液容器（10），液体泵（20），以将前体A泵送到蒸发器（30），容器（40），用于保持诸如水的前体B，其中具有监测装置（60）的沉积室（50）和排气系统（70）。

3. 发明授权

EP1070538B1 Metallo-organic polymers for gas separation and purification 无效
标题翻译：用于气体分离和纯化的有机金属聚合物
公开(公告)号：EP1070538B1
公开(公告)日：2004-09-22
申请号：EP00306105.8
申请日：2000-07-18
申请人： THE BOC GROUP, INC.
发明人： Wang, Qing Min , Shen, Dongmin , Bülow, Martin , Lau, Miu Ling , Fitch, Frank R. , Deng, Shuguang
IPC分类号： B01J20/00 , B01J20/26 , B01D53/04 , B01D53/047 , C08G79/00
CPC分类号： B01D53/02 , B01D2253/202 , B01D2253/204 , B01D2257/402 , B01D2257/504 , B01D2257/702 , B01J20/226 , B01J20/26 , C08G79/00 , Y02C10/08 , Y02C20/10 , Y02P20/152 , Y02P20/153 , Y10S95/90

4. 发明公开

EP1070537A3 Oxygen-selective adsorbents 有权
标题翻译：氧选择性Adsorben
公开(公告)号：EP1070537A3
公开(公告)日：2001-11-14
申请号：EP00306096.9
申请日：2000-07-18
申请人： THE BOC GROUP, INC.
发明人： Wang, Qing Min , Shen, Dongmin , Lau, Miu Ling , Bülow, Martin , Fitch, Frank R. , Lemcoff, Norberto O. , Connolly, Philip
IPC分类号： B01J20/00 , B01J20/32 , B01D53/02 , C01B13/02
CPC分类号： C07D487/22 , B01D53/02 , B01D2253/202 , B01D2257/104 , B01J20/22 , B01J20/26 , C01B13/0262 , C01B2210/0046 , C07C255/24 , C07C255/30 , Y10S95/90
摘要： The present invention provides for novel solid state O 2 -selective metal complex-based adsorbents and their utility for separating oxygen from a gas stream. In particular, the invention provides for an adsorption complex which contains four-coordinate O 2 -selective metal complexes including oligomeric/polymeric metal complexes, and organic base-containing polymers supported on porous materials. Examples of adsorbents according to the invention include (i) a composition of poly (4-vinylpyricline-co-styrene) and bis (3,5-di- tert -butylsalicylidene)-1,2- (1,2-dicyanoacetylene) diamino cobalt ((II) and (ii)) a composition of poly (4-vinylpyricline- co -styrene), silica gel, and bis (salicylidene)-12-ethylenediaminocobalt (II)

5. 发明公开

EP1005904A3 Adsorbents and adsorptive separation process 审中-公开
标题翻译：吸附剂和吸附分离过程
公开(公告)号：EP1005904A3
公开(公告)日：2000-06-14
申请号：EP99308288.2
申请日：1999-10-20
申请人： THE BOC GROUP, INC.
发明人： Su, Bao-Lian , Bülow, Martin , Blin, Jean-Luc , Ojo, Adeola F. , Jale, Sudhakar , Shen, Dongmin , Wang, Qing Min , Fitch, Frank R.
IPC分类号： B01J20/18 , B01D53/04
CPC分类号： B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/104 , B01D2253/108 , B01D2253/112 , B01D2256/12 , B01D2257/102 , B01D2257/402 , B01D2257/502 , B01D2257/504 , B01J20/186 , Y02C10/08 , Y02C20/10 , Y10S95/902
摘要： A composition comprising a molecular sieve material containing exchangeable cations, more than 50 % of the total exchangeable cations being at least one cation selected from the group Li, Ca, Ag, Cu and mixtures thereof, and having within its pore system at least one compound which is a metal oxide selected from Li 2 O, Ag 2 O, CuO, Cu 2 O, CaO, MgO, SrO, ZnO, CdO, B 2 O 3 , Al 2 O 3 , Ga 2 O 3 , TiO 2 , ZrO 2 , V 2 O 5 , MnO, MnO 2 , FeO, Fe 2 O 3 , NiO, and rare earth oxides, a precursor of said metal oxide, and mixtures thereof. The composition is useful in the separation by adsorption of gas mixtures, and in particular the separation of air to product an oxygen-enriched gas.
摘要翻译：一种组合物，其包含含有可交换阳离子的分子筛材料，超过50％的全部可交换阳离子为选自Li，Ca，Ag，Cu及其混合物中的至少一种阳离子，并且在其孔系统内具有至少一种化合物其选自Li2O，Ag2O，CuO，Cu2O，CaO，MgO，SrO，ZnO，CdO，B2O3，Al2O3，Ga2O3，TiO2，ZrO2，V2O5，MnO，MnO2，FeO，Fe2O3，NiO和稀土金属氧化物氧化物，所述金属氧化物的前体，以及它们的混合物。该组合物用于通过吸附气体混合物进行分离，特别是将空气分离以产生富氧气体。

6. 发明公开

EP1717343A3 Method and apparatus for using solution based precursors for atomic layer deposition 审中-公开
标题翻译：设备和方法，用于原子层的基于溶液的沉积。
公开(公告)号：EP1717343A3
公开(公告)日：2007-12-12
申请号：EP06252213.1
申请日：2006-04-25
申请人： THE BOC GROUP, INC.
发明人： Ma, Ce , Wang, Qing Min , Helly, Patrick Joseph , Hogle, Richard Allen
IPC分类号： C23C16/455
CPC分类号： C23C16/45544 , C23C16/448 , C23C16/45525 , Y10T428/8305
摘要： A unique combination of solution stabilization and delivery technologies with special ALD operation is provided. A wide range of low volatility solid ALD precursors dissolved in solvents are used. Unstable solutes may be stabilized in solution and all of the solutions may be delivered at room temperature. After the solutions are vaporized, the vapor phase precursors and solvents are pulsed into a deposition chamber to assure true ALD film growth.
An ALD deposition system that can be used in the present invention includes solution vessel (10), for holding the dissolved precursor solution (precursor A), a liquid pump (20), to pump precursor A to a vaporizer (30), a vessel (40), for holding precursor B, such as water, a deposition chamber (50), having a monitoring device (60), therein, and an exhaust system (70).

7. 发明公开

EP1560252A3 Deposition apparatus 有权转让
标题翻译：沉积装置
公开(公告)号：EP1560252A3
公开(公告)日：2006-03-29
申请号：EP04258095.1
申请日：2004-12-23
申请人： THE BOC GROUP, INC.
发明人： Bailey, Christopher Mark , Hogle, Richard , Purdon, Simon , Kasmalkar, Revati Pradhan , Sullivan, Aaron , Ma, Ce , Wang, Qing Min
IPC分类号： H01J37/32 , C23C16/44
CPC分类号： H01J37/3244 , C23C16/4405 , C23C16/4412 , H01J37/32844 , Y02C20/30 , Y02P70/605
摘要： A method and apparatus for introducing a fluorine-containing flow stream to a deposition process to maintain process by-product volatility and reduce or eliminate by-product formation and/or interference.

8. 发明公开

EP1005904A2 Adsorbents and adsorptive separation process 审中-公开
标题翻译：吸附剂和吸附剂Trennungsverfahren
公开(公告)号：EP1005904A2
公开(公告)日：2000-06-07
申请号：EP99308288.2
申请日：1999-10-20
申请人： THE BOC GROUP, INC.
发明人： Su, Bao-Lian , Bülow, Martin , Blin, Jean-Luc , Ojo, Adeola F. , Jale, Sudhakar , Shen, Dongmin , Wang, Qing Min , Fitch, Frank R.
IPC分类号： B01J20/18 , B01D53/04
CPC分类号： B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/104 , B01D2253/108 , B01D2253/112 , B01D2256/12 , B01D2257/102 , B01D2257/402 , B01D2257/502 , B01D2257/504 , B01J20/186 , Y02C10/08 , Y02C20/10 , Y10S95/902
摘要： A composition comprising a molecular sieve material containing exchangeable cations, more than 50 % of the total exchangeable cations being at least one cation selected from the group Li, Ca, Ag, Cu and mixtures thereof, and having within its pore system at least one compound which is a metal oxide selected from Li 2 O, Ag 2 O, CuO, Cu 2 O, CaO, MgO, SrO, ZnO, CdO, B 2 O 3 , Al 2 O 3 , Ga 2 O 3 , TiO 2 , ZrO 2 , V 2 O 5 , MnO, MnO 2 , FeO, Fe 2 O 3 , NiO, and rare earth oxides, a precursor of said metal oxide, and mixtures thereof. The composition is useful in the separation by adsorption of gas mixtures, and in particular the separation of air to product an oxygen-enriched gas.
摘要翻译：包含含有可交换阳离子的分子筛材料的组合物，超过50％的总可交换阳离子是选自Li，Ca，Ag，Cu及其混合物中的至少一种阳离子，并且在其孔隙体系内具有至少一种化合物其选自Li2O，Ag2O，CuO，Cu2O，CaO，MgO，SrO，ZnO，CdO，B2O3，Al2O3，Ga2O3，TiO2，ZrO2，V2O5，MnO，MnO2，FeO，Fe2O3，NiO和稀土中的金属氧化物氧化物，所述金属氧化物的前体及其混合物。该组合物可用于通过吸附气体混合物进行分离，特别是将空气与产物分离成富氧气体。

9. 发明公开

EP1560252A2 Deposition apparatus 有权转让
标题翻译： Abscheidungsgerät
公开(公告)号：EP1560252A2
公开(公告)日：2005-08-03
申请号：EP04258095.1
申请日：2004-12-23
申请人： THE BOC GROUP, INC.
发明人： Bayley, Christopher Mark , Hogle, Richard , Purdon, Simon , Kasmalkar, Revati Pradhan , Sullivan, Aaron , Ma, Ce , Wang, Qing Min
IPC分类号： H01J37/32
CPC分类号： H01J37/3244 , C23C16/4405 , C23C16/4412 , H01J37/32844 , Y02C20/30 , Y02P70/605
摘要： A method and apparatus for introducing a fluorine-containing flow stream to a deposition process to maintain process by-product volatility and reduce or eliminate by-product formation and/or interference.
摘要翻译：一种用于将含氟流动流引入沉积过程以维持过程副产物挥发性并减少或消除副产物形成和/或干扰的方法和装置。

10. 发明公开

EP1069211A3 Electroplating solutions 审中-公开
标题翻译：电镀
公开(公告)号：EP1069211A3
公开(公告)日：2003-12-17
申请号：EP00305941.7
申请日：2000-07-13
申请人： THE BOC GROUP, INC.
发明人： Wang, Qing Min , Huang, Weiji , Lau, Miu Ling , Liu, Carol Hsiuchin , Ma, Ce , Chang, Edward K. , Ho, Wenpin , Paciej, Richard C.
IPC分类号： C25D3/38
CPC分类号： C25D3/38
摘要： An acid copper electroplating composition comprising an aqueous solution of an acid and a copper salt, wherein at least one carrier compound, a water-soluble, mercapto-containing organic brightener compound and a leveller compound which comprises an organic compound containing single or multiple charged centres are present.

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