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1. 发明公开

EP0653404A1 Use of supported chromium catalyst in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
标题翻译：从叔丁基氢过氧化物制备叔丁醇的使用负载的铬催化剂。
公开(公告)号：EP0653404A1
公开(公告)日：1995-05-17
申请号：EP94308296.6
申请日：1994-11-10
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Sanderson, John Ronald , Duranleau, Roger George
IPC分类号： C07C29/132 , C07C29/88
CPC分类号： C07C29/88 , C07C29/132 , C07C31/12
摘要： A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of alumina having chromium deposited thereon and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.
摘要翻译：一种方法，其特征在于所说的溶剂SOLN。的叔。丁基过氧化氢的电荷股票在LIQ氢过氧化物分解反应区使其与催化有效AMT接触。氢过氧化物分解催化剂。在搅拌阶段的叔转换。丁基过氧化氢分解产物主要地，叔。丁醇。改进之处包括：a）使用，作为催化剂，负载过氧化氢分解。催化剂由...组成沉积在其上具有氧化铝铬; 和b）回收叔。从过氧化氢分解反应的产物丁醇。

2. 发明公开

EP0653403A1 Use of titania or zirconia in the preparation of tertiary butyl alcohol from tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
标题翻译：使用氧化钛或氧化锆的从Tertiärbutylhydroperoxide生产叔丁醇。
公开(公告)号：EP0653403A1
公开(公告)日：1995-05-17
申请号：EP94308295.8
申请日：1994-11-10
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Sanderson, John Ronald , Knifton, John Frederick , Marquis, Edward Thomas
IPC分类号： C07C29/132 , C07C29/88
CPC分类号： C07C29/132 , C07C29/88 , C07C31/12
摘要： A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of titania or zirconia and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.
摘要翻译：一种制备叔丁醇worin的原料包括叔丁基氢过氧化物的叔丁基醇的溶剂溶液或用异丁烷叔丁醇的混合物加至含有由催化有效量的过氧化氢分解催化剂的氢过氧化物分解反应区方法基本上氧化钛或氧化锆的和在液相中氢过氧化物分解反应的条件下接触与催化剂的叔丁基过氧化氢转化为分解产物，主要是叔丁醇。

3. 发明公开

EP0653401A1 Use of supported palladium, catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
标题翻译：生产从叔丁基过氧化氢叔丁醇的使用负载钯催化剂。
公开(公告)号：EP0653401A1
公开(公告)日：1995-05-17
申请号：EP94308293.3
申请日：1994-11-10
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Sanderson, John Ronald , Knifton, John Frederick , Duranleau, Roger George
IPC分类号： C07C29/132 , C07C29/88
CPC分类号： C07C29/88 , C07C29/132 , C07C31/12
摘要： A method for preparing tertiary butyl alcohol wherein a solution of a tertiary butyl hydroperoxide feedstock in tertiary butyl alcohol is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of palladium and gold supported on alumina, and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol and ditertiary butyl peroxide.
摘要翻译：一种制备叔丁醇worin在叔丁醇叔丁基过氧化氢原料的溶液的方法是加入到含有负载在氧化铝上的过氧化氢分解催化剂基本上由钯和金的催化有效量的过氧化氢分解反应区中，并且是使其与过氧化氢分解反应的条件下在液相中的催化剂接触的叔丁基氢过氧化物转化成分解产物，主要是叔丁醇和过氧化二叔丁基。

4. 发明授权

EP0266976B1 Catalytic removal of peroxide contaminants from tertiary butyl alcohol 失效
标题翻译：从叔丁醇中催化去除过氧化物污染物
公开(公告)号：EP0266976B1
公开(公告)日：1991-05-02
申请号：EP87309614.3
申请日：1987-10-30
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Sanderson, John Ronald , Gipson, Robert Malone , Keating, Kenneth Patrick , Marquis, Edward Thomas
IPC分类号： C07C31/12 , C07C29/88
CPC分类号： C07C29/88 , C07C31/12

5. 发明公开

EP0421034A1 Catalyst for removing peroxide contaminants from tertiary butyl alcohol 失效
标题翻译： Katalysator zur Entfernung von Peroxid-Verunreinigungen austertiäremButylalkohol。
公开(公告)号：EP0421034A1
公开(公告)日：1991-04-10
申请号：EP89310174.1
申请日：1989-10-04
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Sanderson, John Ronald , Larkin, John Michael, Sr.
IPC分类号： C07C29/88 , C10L1/02
CPC分类号： C07C29/88 , C07C31/12
摘要： Motor-fuel grade tertiary butyl alcohol contaminated with residual amounts of tertiary butyl hydroperoxide and ditertiary butyl peroxide (which is prepared, for example, by reacting propylene with tertiary butyl hydroperoxide to form propylene oxide and a motor fuel grade tertiary butyl alcohol reaction product) can be effectively catalytically treated under mild conversion conditions including a temperature of about 80° to 200°C with a catalyst consisting essentially of nickel, copper, chromium and barium to substantially selectively convert the two peroxide contaminants to tertiary butyl alcohol and to thereby provide a treated tertiary butyl alcohol product substantially free from contaminating quantities of such peroxides.
摘要翻译：被残留量的叔丁基氢过氧化物和二叔丁基过氧化物（其通过例如通过丙烯与叔丁基过氧化氢反应形成环氧丙烷和马达燃料级叔丁醇反应产物制备）的汽油燃料级叔丁醇可以在温和转化条件下，包括基本上由镍，铜，铬和钡组成的催化剂基本上选择性地将两种过氧化物污染物转化为叔丁醇，从而在温和转化条件下进行有效的催化处理，包括约80至200℃的温度，基本上没有污染量的这种过氧化物的叔丁醇产物。

6. 发明授权

EP0264184B1 Molybdenum/alkali metal/ethylene glycol complexes useful as epoxidation catalysts and method for making the same 失效
标题翻译：用作环氧化催化剂的莫尔晶/碱金属/乙烯甘油酯复合物及其制备方法
公开(公告)号：EP0264184B1
公开(公告)日：1990-12-19
申请号：EP87307819.0
申请日：1987-09-04
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Marquis, Edward Thomas , Sanderson, John Ronald , Keating, Kenneth Patrick
IPC分类号： B01J31/12 , C07D301/19
CPC分类号： C07D301/19 , B01J31/223 , B01J31/4092 , B01J2231/72 , B01J2531/64 , Y02P20/52 , Y02P20/584

7. 发明授权

EP0191993B1 Improved synthesis of molybdenum/alcohol complexes useful as epoxidation catalysts 失效
标题翻译：用作环氧化催化剂的钼/醇溶液复合物的改进合成
公开(公告)号：EP0191993B1
公开(公告)日：1990-08-16
申请号：EP85309371.4
申请日：1985-12-20
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Marquis, Edward Thomas , Sanderson, John Ronald , Keating, Kenneth Patrick , Smith, William Alan
IPC分类号： C07D301/19 , B01J31/22
CPC分类号： C07D301/19 , B01J31/2208 , B01J31/2226 , B01J2231/72 , B01J2531/64

8. 发明公开

EP0266976A1 Catalytic removal of peroxide contaminants from tertiary butyl alcohol 失效
标题翻译： Katalytische Entfernung von Peroxidverunreinigungen aus tert。 Butylalkohol。
公开(公告)号：EP0266976A1
公开(公告)日：1988-05-11
申请号：EP87309614.3
申请日：1987-10-30
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Sanderson, John Ronald , Gipson, Robert Malone , Keating, Kenneth Patrick , Marquis, Edward Thomas
IPC分类号： C07C31/12 , C07C29/88
CPC分类号： C07C29/88 , C07C31/12
摘要： Motor-fuel grade tertiary butyl alcohol contaminated with residual amounts of tertiary butyl hydroperoxide and ditertiary butyl peroxide (which is prepared, for example, by reacting propylene with tertiary butyl hydroperoxide to form propylene oxide and a motor fuel grade tertiary butyl alcohol reaction product) can be effectively catalytically treated under mild conversion conditions including a preferred temperature range of about 80° to 180°C with a base-treated hydrogenation catalyst from Groups VIB or VIIIB of the Periodic Table in order to substantially selectively convert the two peroxide contaminants to tertiary butyl alcohol and to thereby provide a treated tertiary butyl alcohol product substantially free from contaminating quantities of such peroxides.
摘要翻译：被残留量的叔丁基氢过氧化物和二叔丁基过氧化物（其通过例如通过丙烯与叔丁基过氧化氢反应形成环氧丙烷和马达燃料级叔丁醇反应产物制备）的汽油燃料级叔丁醇可以在温和的转化条件下，包括优选的温度范围为约80-180℃，由碱处理的加氢催化剂从元素周期表VIB或VIIIB组分进行有效催化处理，以便基本上选择性地将两种过氧化物污染物转化为叔丁基并由此提供基本上不含污染量的这种过氧化物的经处理的叔丁醇产物。

9. 发明公开

EP0251526A3 Catalytic purification of tertiary butyl alcohol 失效
标题翻译：仲丁醇的催化净化
公开(公告)号：EP0251526A3
公开(公告)日：1988-03-23
申请号：EP87305118
申请日：1987-06-10
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Sanderson, John Ronald , Marquis, Edward Thomas , Meyer, Robert Allen , Renken, Terry Lee
IPC分类号： C07C31/12 , C07C29/88
CPC分类号： C07C29/132 , C07C29/88 , C07C31/12
摘要： Motor-fuel grade tertiary butyl alcohol which is prepared, for example, by reacting propylene with tertiary butyl hydroperoxide to form propylene oxide and a tertiary butyl alcohol reaction product contaminated with residual amounts of tertiary butyl hydroperoxide and ditertiary butyl peroxide can be effectively catalytically treated under mild conversion con- dltions including a temperature of about 80° to 280°C with an unsupported catalyst composed of nickel, copper, chromia and iron, or the oxides thereof, or a catalyst containing nickel, copper, chromia and iron which is supported on silica in order to substantially selectively convert the two peroxide contaminants to tertiary butyl alcohol and to thereby provide a treated tertiary butyl alcohol product substantially free from contaminating quantities of such peroxides.

10. 发明授权

EP0188912B2 Epoxidation of propylene 失效
标题翻译：丙烯环氧化
公开(公告)号：EP0188912B2
公开(公告)日：1998-03-04
申请号：EP85309373.0
申请日：1985-12-20
申请人： TEXACO DEVELOPMENT CORPORATION
发明人： Marquis, Edward Thomas , Keating, Kenneth Patrick , Knifton, John Frederick , Smith, William Alan , Sanderson, John Ronald , Lustri, Jonathan Philip
IPC分类号： C07D301/19 , C07D303/04
CPC分类号： C07D301/19 , C07D303/04

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