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    • 8. 发明公开
    • METHOD OF CRYSTALLIZING LOW-MOLECULAR POLYCARBONATE AND PROCESS FOR PRODUCING POLYCARBONATE RESIN FROM THE SAME
    • 工艺结晶低分子聚碳酸酯及其制备方法聚碳酸酯树脂SAME
    • EP1245607A4
    • 2004-11-10
    • EP00961159
    • 2000-09-21
    • TEIJIN LTD
    • SAKURAI TOMONORIKIDO NOBUAKIMATSUMURA SHUNICHIISHIWATA TOYOAKIKOHNO KAZUTERUSUZUKI HIROTAKAHAGA HIRONORIHIKOSAKA TORU
    • C08G64/20C08G64/40
    • C08G64/20C08G64/40
    • A method of efficiently crystallizing a low-molecular aromatic polycarbonate; and a process for producing a polycarbonate resin with a desired intrinsic viscosity from the polycarbonate obtained by the method through crystallization. A low-molecular aromatic polycarbonate (preferably one produced through melt polycondensation) is contacted with an aromatic monohydroxy compound or a mixture of the compound and water to crystallize the polycarbonate. Alternatively, a low-molecular aromatic polycarbonate is melt-mixed with at least one compound selected from the group consisting of aromatic monohydroxy compounds, carbonic diester compounds, and aromatic dihydroxy compounds to crystallize the polycarbonate. The crystallized polycarbonate is heated at a temperature lower than its melting point either at a reduced pressure or in an inert gas stream to polymerize it to a high degree. Thus, a polycarbonate resin having a desired intrinsic viscosity is produced.
    • 一种用于有效地结晶化的低分子量芳族聚碳酸酯的方法和用于制备通过使用具有结晶的上述方法结晶的聚碳酸酯具有所需特性粘度的聚碳酸酯树脂的方法。 低分子量的芳族聚碳酸酯(优选地,通过熔融缩聚制备的一种)是通过将其与接触在单羟基芳族化合物或所述化合物和水的混合物中结晶。 或者,低分子量的芳族聚碳酸酯是用熔融选自芳族单羟基化合物,碳酸二酯化合物和芳族二羟基化合物的结晶的低分子量芳族聚碳酸酯所选化合物中的至少一种或多种混合。 结晶产物在减压条件下比其熔点低的温度下或在惰性气体中加热到流动以将其转化成高聚合状态。 因此,具有所期望的特性粘度的聚碳酸酯树脂是准备。