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    • 2. 发明公开
    • ADDITIVE FOR NONAQUEOUS ELECTROLYTE, NONAQUEOUS ELECTROLYTE, AND ELECTRICITY STORAGE DEVICE
    • 额外的材料对于自由用水电解液,电解质免费的水和蓄电装置
    • EP2731187A1
    • 2014-05-14
    • EP12807104.0
    • 2012-07-06
    • Sumitomo Seika Chemicals Co., Ltd.
    • ONOZUKA, TomohiroFUJIMOTO, ShoheiFUJITA, Koji
    • H01M10/0567C07C311/03C07C311/08H01M10/0568H01M10/0569
    • H01M10/0567C07C309/65C07C311/03C07C311/08C07C311/13C07D285/01C07D285/36C07D295/26C07D327/04C07F7/21C07F9/4006C07F9/6544C07F9/6552H01G11/58H01G11/64Y02E60/13
    • The present invention aims to provide an additive for a non-aqueous electrolyte solution with excellent storage stability capable of forming a stable SEI on the surface of an electrode to improve cell performance such as a cycle performance, a discharge/charge capacity, and internal resistance, when the additive is used for electrical storage devices such as non-aqueous electrolyte solution secondary cells and electric double layer capacitors. The present invention also aims to provide a non-aqueous electrolyte solution containing the additive for a non-aqueous electrolyte solution and to provide an electrical storage device using the non-aqueous electrolyte solution. The present invention is an additive for a non-aqueous electrolyte solution, comprising a compound that has a structure represented by the formula (1-1) or (1-2):


      in which A represents C m H(2 m-n )Z n , m being an integer of 1 to 6, n being an integer of 0 to 12, and Z representing a substituted or unsubstituted alkyl group, a silyl group, a phosphonic acid ester group, an acyl group, a cyano group, or a nitro group, the compound having a lowest unoccupied molecular orbital energy of -3.0 to 0.4 eV, a standard enthalpy of formation of -220 to -40 kcal/mol, and an enthalpy change with hydrolysis reaction of -5 to 5 kcal/mol.
    • 本发明的目的是具有能够以提高电池性能的电极的表面上形成稳定的SEI的保存稳定性优异的非水电解质溶液提供添加剂:如一个循环性能,放电/充电容量和内部电阻 ,当添加剂被用于电存储设备:如非水电解质溶液二次电池和双电层电容器。 因此,本发明目的在于提供一种非水电解质溶液,其中含有该添加剂的非水电解液以及使用该非水电解质溶液,以提供到蓄电装置。 本发明是用于非水电解质溶液中的添加剂,其包含化合物具有这样的结构也由式(1-1)或(1-2)表示:其中A darstellt C M H(2分钟)Z N ,m是1至6的整数,n为12的0-4的整数,并且Z代表substituiertem奥德unsubstituiertem烷基,甲硅烷基,膦酸酯基,对酰基,氰基,或硝基 基,具有-3.0最低未占据分子轨道能级的能量来为0.4eV,形成-220至-40千卡/摩尔的标准焓的化合物,并与焓-5至5千卡/摩尔的水解反应的变化。