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    • 2. 发明公开
    • MODIFIED NATURAL RUBBER PARTICLE, PROCESS FOR PRODUCING THE MODIFIED NATURAL RUBBER PARTICLE, AND MODIFIED NATURAL RUBBER LATEX
    • 改进NATURKAUTSCHUKTEILCHEN,改性NATURKAUTSCHUKTEILCHENS生产方法和改进胶乳
    • EP2301974A1
    • 2011-03-30
    • EP09794498.7
    • 2009-07-09
    • Tokai Rubber Industries, Ltd.National University Corporation Nagaoka University of Technology
    • WAKISAKA, OsamuSHIBAHARA, AkihiroKAWAHARA, SeiichiYAMAMOTO, YoshimasaPUKKATE, Nanthaporn
    • C08C19/28C08F253/00
    • C08F222/1006C08C1/04C08C19/28C08F8/14C08F253/00C08F222/20C08F212/34
    • The present invention provides a modified natural rubber particle having the carbon-carbon double bonds assigned to monomers graft-copolymerized onto the surface of the modified natural rubber particle, and a production method thereof.
      A modified natural rubber particle having carbon-carbon double bonds assigned to multifunctional vinyl monomers graft-copolymerized onto the surface of the modified natural rubber particle, which is prepared by graft-copolymerization of multifunctional vinyl monomers having two or more carbon-carbon double bonds onto natural rubber particles or deproteinized natural rubber particles. One of the methods for producing a modified natural rubber particle includes the steps of: forming inclusion complex of the multifunctional vinyl monomers having two or more carbon-carbon double bonds with a guest-protecting agent to protect at least one of the double bonds of the multifunctional vinyl monomers; graft-copolymerizing the resulting inclusion complex onto natural rubber particles or deproteinized natural rubber particles; and deprotecting the protected double bonds by removing the guest-protecting agent from the obtained graft-copolymer.
    • 本发明提供具有被分配给单体的碳 - 碳双键的改性天然橡胶粒子接枝共聚到改性天然橡胶粒子的表面上,以及它们的制造方法。 一种改性天然橡胶粒子具有分配给具有两个或更多碳 - 碳双键,其通过多官能乙烯基单体的接枝共聚制得的多官能乙烯基单体接枝共聚到改性天然橡胶粒子的表面上,全部在碳 - 碳双键 天然橡胶粒子或脱蛋白质化天然橡胶粒子。 之一的用于生产改性天然橡胶粒子的方法包括以下步骤:具有两个或更多碳 - 碳双键,以保护的双键的至少一种的保护剂形成的多官能乙烯基单体的包合配合物 多官能乙烯基单体; 接枝共聚所得到的包合配合物走上天然橡胶粒子或脱蛋白质化天然橡胶粒子; 并且通过去除从接枝共聚物中获得的包接保护剂脱保护的保护双键。