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    • 2. 发明公开
    • METHOD FOR PRODUCING HIGH-STRENGTH SEAMLESS CR-NI ALLOY PIPE
    • 用于生产高强度无缝钢管从Cr-Ni合金
    • EP2415883A1
    • 2012-02-08
    • EP10758614.1
    • 2010-03-29
    • Sumitomo Metal Industries, Ltd.
    • OTOME, YoheiIGARASHI, MasaakiOKADA, HirokazuKONDO, KunioSAGARA, MasayukiSHIMODA, Kazuhiro
    • C21D8/10C22C38/00C22C38/58
    • C21D8/10C21D6/004C22C1/002
    • A method for producing a high-strength Cr-Ni alloy seamless pipe, excellent in hot workability and stress corrosion cracking resistance, without causing the lamination during piercing-rolling, comprising:
      preparing an alloy billet that has a chemical composition comprising, by mass%, of C: 0.05% or less, Si: 1.0% or less, Mn: less than 3.0%, P: 0.005% or less, S: 0.005% or less, Cu: 0.01 to 4.0%, Ni: 25% or more and less than 35%, Cr: 20 to 30%, Mo: 0.01% or more and less than 4.0%, N: 0.10 to 0.30%, Al: 0.03 to 0.30%, O (oxygen): 0.01% or less, REM (rare earth metal): 0.01 to 0.20%, and the balance being Fe and impurities, and satisfying the following formula (1);
      hot working to make a seamless material pipe on the basis of a cross roll piercing process; subjecting a solution treatment; and
      cold working. N × P / REM ≤ 0.10
      wherein P, N and REM in formula (1) represent the contents (mass%) of P, N and REM, respectively.
      The Cr-Ni alloy may further contain one or more of W, Ti, Nb, Zr, V, Ca and Mg.
    • 一种用于生产高强度Cr-Ni合金无缝管,优异的热加工性和耐应力腐蚀裂纹性,没有穿孔轧制过程中引起的层压方法,包括:准备合金坯料确实具有化学组合物,包含,以质量%计 中,C:0.05%以下,Si:1.0%以下,Mn:小于3.0%,P:0.005%以下,S:0.005%以下,Cu:0.01〜4.0%以下,Ni:25%或更多 且小于35%以下,Cr:20〜30%以下,Mo:0.01%以上且小于4.0%,N:0.10〜12:30%以下,Al:0.03〜12:30%,O(氧):0.01%以下,REM (稀土类金属):12:01到12:20%,且余量由Fe及杂质构成,且满足下述式(1); 热加工以使横辊穿孔过程的基础上的无缝管的材料; 经受固溶处理; 和冷加工。 N×P / REM‰¤00:10 worin P,N和REM在式(1)表示的P,N和SEM的含量(质量%)表示。 的Cr-Ni合金可含有一个或多个另外的钨,钛,铌,锆,V,Ca和Mg的。
    • 4. 发明公开
    • PROCESS FOR PRODUCTION OF HIGH ALLOY STEEL PIPE
    • VERFAHREN ZUR HERSTELLUNG VON ROHREN AUS HOCHLEGIERTEM STAHL
    • EP2163655A1
    • 2010-03-17
    • EP08790632.7
    • 2008-06-26
    • Sumitomo Metal Industries, Ltd.
    • SAGARA, MasayukiSUWABE, HitoshiAMAYA, HisashiKIMURA, ShigemitsuIGARASHI, Masaaki
    • C21D8/10C22C38/00C22C38/44
    • C22C38/02C21D6/004C21D8/10C21D8/105C21D9/14C22C38/04C22C38/42C22C38/44
    • Problem to be Solved
      There is provided a method for manufacturing a high alloy pipe which can be hot worked for pipe-making, and has an excellent ductility and an excellent corrosion resistance when cold working is further performed to obtain a high strength after pipe-making.
      Solution
      A method for manufacturing a high alloy pipe, characterized by comprising forming, by hot working, a high alloy material pipe which has a chemical composition that consists of, by mass percent, C: 0.03% or less, Si: 1.0% or less, Mn: 0.05 to 1.5%, P: 0.03% or less, S: 0.03% or less, Ni: more than 22% and not more than 40%, Cr: 20 to 30%, Mo: not less than 0.01% and less than 4.0%, Cu: 0 to 4.0%, Al: 0.001 to 0.30%, N: more than 0.05% and not more than 0.30%, and O: 0.010% or less, the balance being Fe and impurities, and that satisfies formula (1) for the product of the N content and the O content, and thereafter performing cold working to form the high alloy pipe, wherein the final cold working process is performed under the condition that a working ratio Rd in the reduction of area satisfies formula (2): N × O ≤ 0.001 15 ≤ Rd % ≤ 370 × C + N
      where N, O and C are the contents (by mass percent) of the respective elements, and Rd is the working ratio (%) in the reduction of area. The high alloy pipe may also contain one or more of Ca, Mg, and rare-earth elements.
    • 要解决的问题提供一种制造可以热加工用于制管的高合金管的方法,并且在进一步进行冷加工以获得制管后的高强度时具有优异的延展性和优异的耐腐蚀性 。 方案一种制造高合金管的方法,其特征在于,通过热加工形成具有质量%C:0.03%以下,Si:1.0%以下的化学组成的高合金材料管 ,Mn:0.05〜1.5%,P:0.03%以下,S:0.03%以下,Ni:22%以上40%以下,Cr:20〜30%,Mo:0.01%以上, 小于4.0%,Cu:0〜4.0%,Al:0.001〜0.30%,N:0.05以上且0.30以下,O:0.010%以下,余量为Fe,杂质,满足 式(1)表示N含量和O含量的乘积,然后进行冷加工以形成高合金管,其中在减少面积的加工率Rd满足的条件下进行最终冷加工工序 公式(2):N×O‰‰0.001 15‰¤Rd%‰370×C + N其中N,O和C分别为各元素的含量(质量百分比),Rd为加工率(% ) 在那里 区域的区域。 高合金管也可以含有一种或多种Ca,Mg和稀土元素。
    • 7. 发明公开
    • HIGH-STRENGTH WELDED STEEL STRUCTURES HAVING EXCELLENT CORROSION RESISTANCE
    • HCHFESTE,GESCHWEISSTE STAHLSTRUKTUREN MIT HERVORRAGENDEM KORROSIONSWIDERSTAND
    • EP0864663A1
    • 1998-09-16
    • EP96932043.1
    • 1996-09-27
    • SUMITOMO METAL INDUSTRIES, LTD.
    • UEDA, MasakatsuOGAWA, KazuhiroKONDO, KunioIGARASHI, Masaaki
    • C22C38/00C22C38/18C22C38/44C22C38/50B23K9/167B23K9/173
    • B23K35/3086Y10T428/12965Y10T428/12979
    • High-strength welded steel structures having excellent SSC and corrosion resistances in a wet carbon dioxide environment having a low H 2 S concentration. (1) A structure having a Vickers hardness of at most 350 and a joint tensil strength of at least 620 Mpa and composed of a base metal comprising a martensitic stainless steel with a martensitic or tempered martensitic structure containing 0.001 to 0.05 % C and 9 to 14 % Cr and a weld metal comprising an austenitic-ferritic stainless steel having a duplex structure composed of austenite and 35 to 75 % by volume of ferrite and containing 22 to 27 % Cr, 7 to 11 % Ni and 1.5 to 5 % Mo, and at most 0.03 % C as an impurity. (2) Another structure according to the above item (1), wherein the base metal comprises the elements described in the above item (1) and further comprises Mn, Ni, sol. Al, Mo, Cu, Ti or the like, and Fe and the weld metal comprises the elements described in the above item (1) and further comprises sol. Al, N, Cu, W or the like, and Fe. (3) Still another structure according to the above item (2), wherein the content of C, Mn, Cr or the like of the base metal is further limited to a narrower range, and so is the content of Mn, Cu, W or the like.
    • 在具有低H2S浓度的湿二氧化碳环境中具有优异的SSC和耐腐蚀性的高强度焊接钢结构。 (1)维氏硬度在350以下且结合张力强度为至少620Mpa的结构体,由含有马氏体或回火马氏体组织的马氏体系不锈钢构成,该马氏体系不锈钢含有0.001〜0.05%的C和9〜 14%Cr和包含由奥氏体和35〜75体积%铁素体组成的双相组织的奥氏体 - 铁素体不锈钢的焊接金属,含有22〜27%的Cr,7〜11%的Ni和1.5〜5%的Mo, 和最多0.03%的C作为杂质。 (2)根据上述(1)所述的另一种结构,其中所述贱金属包括上述(1)中所述的元素,并且还包含Mn,Ni,sol。 Al,Mo,Cu,Ti等,Fe和焊接金属包含上述(1)所述的元素,还含有溶胶。 Al,N,Cu,W等,Fe。 (3)根据上述(2)所述的另一种结构,其中所述贱金属的C,Mn,Cr等的含量进一步限制在较窄的范围内,Mn,Cu,W的含量 或类似物。
    • 8. 发明公开
    • Ni BASED HEAT-RESISTANT ALLOY
    • HITZEBESTÄNDIGELEGIERUNG AUF NICKELBASIS
    • EP2330225A1
    • 2011-06-08
    • EP09817858.5
    • 2009-10-01
    • Sumitomo Metal Industries, Ltd.
    • SEMBA, HiroyukiISEDA, AtsuroHIRATA, HiroyukiKAWANO, KaoriIGARASHI, MasaakiMIYAHARA, Osamu
    • C22C19/05
    • C22C19/055C22C19/056
    • A Ni-base heat resistant alloy, which comprises by mass percent, C: 0.1% or less, Si: 1% or less, Mn: 1% or less, Cr: not less than 15% to less than 28%, Fe: 15% or less, W: more than 5% to not more than 20%, Al: more than 0.5% to not more than 2%, Ti: more than 0.5% to not more than 2%, Nd: 0.001 to 0.1% and B: 0.0005 to 0.01%, with the balance being Ni and impurities, in which the contents of P, S, Sn, Pb, Sb, Zn and As among the impurities are P: 0.03% or less, S: 0.01% or less, Sn: 0.020% or less, Pb: 0.010% or less, Sb: 0.005% or less, Zn: 0.005% or less and As: 0.005% or less, and further satisfies the formulas of [0.015 ≤ Nd + 13.4 × B ≤ 0.13], [Sn + Pb≤ 0.025] and [Sb + Zn + As ≤ 0.010] is an alloy in which much higher strength than the conventional Ni-base heat resistant alloy can be achieved, the ductility and toughness after a long period of use at a high temperature are remarkably improved, and moreover the zero ductility temperature and the hot workability are also further improved. This alloy can be suitably used as a pipe material, a thick plate material for a heat resistant pressure member, a bar material, a forging, and the like for a boiler for power generation, a plant for chemical industry, and the like. This alloy may contain a specific amount of one or more elements selected from Mo, Co, Nb, V, Zr, Hf, Mg, Ca, La, Ce, Ta and Re.
    • Ni基耐热合金,以质量%计含有C:0.1%以下,Si:1%以下,Mn:1%以下,Cr:15%以上且小于28%Fe: 15%以下,W:5%以上20%以下,Al:0.5%以上2%以下,Ti:超过0.5%以上2%以下,Nd:0.001〜0.1% B:0.0005〜0.01%,其余为Ni和杂质,杂质中的P,S,Sn,Pb,Sb,Zn,As含量为P:0.03%以下,S:0.01%以下 较少,Sn:0.020%以下,Pb:0.010%以下,Sb:0.005%以下,Zn:0.005%以下,As:0.005%以下,进一步满足[0.015‰÷Nd + 13.4 ×B‰¤0.13],[Sn + Pb‰‰0.025]和[Sb + Zn + As‰‰0.010]是一种合金,其强度比传统的Ni基耐热合金高得多,其延展性和 在高温下长时间使用后的韧性明显提高,而且零延展性温度和热加工性 也进一步改善。 该合金可以适合用作管材,用于发电锅炉,化学工业用植物等的耐热压力构件的厚板材料,棒材,锻造等。 该合金可以含有一定量的选自Mo,Co,Nb,V,Zr,Hf,Mg,Ca,La,Ce,Ta和Re中的一种或多种元素。
    • 10. 发明公开
    • HIGH-STRENGTH Cr-Ni ALLOY PRODUCT AND SEAMLESS OIL WELL PIPES MADE BY USINFG THE SAME
    • HCHFESTES CR-NI-LEGIERUNGSPRODUKT UND DARAUS HERGESTELLTE NAHTLOSEÖLBOHRROHRE
    • EP2194152A1
    • 2010-06-09
    • EP08835001.2
    • 2008-10-01
    • Sumitomo Metal Industries, Ltd.
    • OTOME, YoheiIGARASHI, MasaakiAMAYA, HisashiOKADA, Hirokazu
    • C22C38/00C22C38/58
    • C22C38/02C22C38/001C22C38/005C22C38/04C22C38/06C22C38/42C22C38/44Y10S148/909
    • [Object] To provide a high strength Cr-Ni alloy material excellent in hot workability and stress corrosion cracking resistance, and seamless pipe for oil well.
      [Solution] A high strength Cr-Ni alloy material which consists of, by mass percent, C: 0.05% or less, Si: 0.05 to 1.0%, Mn: 0.01% or more and less than 3.0%, P: 0.05% or less, S: 0.005% or less, Cu: 0.01 to 4%, Ni: 25% or more and less than 35%, Cr: 20 to 30%, Mo: 0.01% or more and less than 4.0%, N: 0.10 to 0.30%, Al: 0.03 to 0.30%, O (oxygen): 0.01% or less, and REM (rare earth metal): 0.01 to 0.20%, with the balance being Fe and impurities, and also satisfies the conditions in the following formula (1). N × P / REM ≤ 0.40
      where P, N, and REM in the formula (1) respectively denote the contents (mass%) of P, N, and REM. The high strength Cr-Ni alloy material may further contain one or more types of W, Ti, Nb, Zr, V, Ca, and Mg, instead of part of Fe.
    • 本发明提供热加工性和耐应力腐蚀开裂性优异的高强度Cr-Ni合金材料,以及油井无缝管。 [解决方案]以质量%计,C:0.05%以下,Si:0.05〜1.0%,Mn:0.01%以上且小于3.0%,P:0.05%以上的高强度Cr-Ni合金材料, 较少,S:0.005%以下,Cu:0.01〜4%,Ni:25%以上且不足35%,Cr:20〜30%,Mo:0.01%以上且4.0%以下N:0.10 至0.30%,Al:0.03〜0.30%,O(氧)0.01%以下,REM(稀土金属):0.01〜0.20%,余量为Fe和杂质,也满足以下条件 公式1)。 N×P / REM‰0.40其中,式(1)中的P,N和REM分别表示P,N和REM的含量(质量%)。 高强度Cr-Ni合金材料可以进一步含有一种或多种W,Ti,Nb,Zr,V,Ca和Mg而不是Fe的一部分。