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    • 4. 发明公开
    • AROMATIC GRAFT POLYMER
    • AROMATISCHES PFROPFPOLYMER
    • EP1892257A1
    • 2008-02-27
    • EP06766520.8
    • 2006-06-09
    • Sumitomo Chemical Company, Limited
    • OHUCHI, KazueiHIGASHIMURA, HideyukiANRYU, Makoto
    • C08G61/00C09K11/06H01L51/50H05B33/10
    • H01L51/5012C08G61/00C08G61/02C08G61/12C08G2261/1434C08G2261/3142C08G2261/3162C08G2261/411C08G2261/5222C08G2261/77C08G2261/92H01L51/0039H01L51/0043H01L51/0059H01L51/5048
    • An aromatic graft polymer containing one or more kinds of repeating units represented by the following formula (1). (In the formula, Ar 1 represents a divalent residue of a π-conjugated cyclic compound having a side chain represented by the following formula (2), the side chain being bonded to a carbon atom which is included in the ring structure of the divalent π-conjugated-cyclic-compound residue represented by Ar 1 and has an sp 2 hybrid orbital: (wherein Ar 2 represents a divalent group having a residue of a π-conjugated cyclic compound; X 1 represents a direct bond or a divalent group selected from the group consisting of NQ 1 -, -PQ 2 -, and -BQ 3 -, wherein Q 1 to Q 3 each independently represents a substituent; Z represents a direct bond or a divalent connecting group; k is an integer of 3 or larger; and E 1 represents hydrogen, halogeno, or a monovalent organic group, provided that when two or more Ar 2 ' s, X 1 ' s, and Z's are present, then they each may be the same or different and when two or more side chains represented by the formula (2) are present, then they may be the same or different.))
    • 含有下述式(1)所示的一种以上的重复单元的芳香族接枝聚合物。 (式中,Ar 1表示具有由下式(2)表示的侧链的共轭环状化合物的二价残基,该侧链与碳原子键合,该碳原子包含在二价 由Ar 1表示的α-共轭环状化合物残基,并具有sp 2杂化轨道:(其中Ar 2表示具有共轭环状化合物残基的二价基团; X 1表示直接键或选择的二价基团 由NQ 1 - , - PQ 2 - 和 - BQ 3 - 组成的组,其中Q 1至Q 3各自独立地表示取代基; Z表示直接键或二价连接基团; k表示3或3的整数, 较大; E 1表示氢,卤素或一价有机基团,条件是当存在两个或更多个Ar 2,X 1和Z时,它们各自可以相同或不同,当两个或多个 存在更多由式(2)表示的侧链,则它们可以相同或二元 fferent。))
    • 5. 发明公开
    • NOVEL ARYL COMPOUND
    • NEY ARYLVERBINDUNGEN
    • EP1892234A1
    • 2008-02-27
    • EP06766522.4
    • 2006-06-09
    • Sumitomo Chemical Company, Limited
    • OHUCHI, KazueiHIGASHIMURA, HideyukiFUKUSHIMA, Daisuke
    • C07C211/56C07F5/02
    • C07F5/025C07C211/56
    • A novel aryl compound represented by the formula (1) in which the characteristic groups represented by X 1 and X 2 are different from each other:

      wherein X 1 and X 2 are characteristic groups which are different from each other and each of which is selected from the group consisting of a chlorine, bromine or iodine atom, -OSO 2 Q 1 , -B(OQ 2 ) 2 , -Si(OQ 3 ) 3 , -Sn(Q 4 ) 3 , Z 1 (Z 2 )m, a metal acetylide group and a terminal acetylene group (where Q represents a hydrocarbon group; Q 2 represetns a hydrogen atom or a hydrocarbon gruop; two Q 2 's may be the same as or different from each other or may together form a ring; Q 3 represents a hydrocarbon group and three Q 3 's may be the same as or different from one another; Q 4 represetns a hydrocarbon group and three Q 4 's may be the same as different from one another; Z 1 represents a metal atom or a metal ion; Z 2 represents a counter anion; and m is an integer of 0 or higher); Ar 1 and Ar 2 independently represent an arylene group and Ar 3 represetns an aryl group, provided that any two of Ar 1 , Ar 2 and Ar 3 may be bound to each other via a substituent or directly; Y represents a trivalent atomic group having a nitrogen, carbon, boron or silicon atom to which a hydrogen atom or a hydrocarbon group may be added if required; J represents an arylene group; and n is an integer of 0 or higher; provided that, when each of J, Y and Ar 3 is present in the molecule in plural number, they may be the same as or different from each other or one another.
    • 由式(1)表示的新的芳基化合物,其中由X 1和X 2表示的特征基团彼此不同:其中X 1和X 2是彼此不同的特征基团,并且各自被选择 来自由氯,溴或碘原子组成的组,-OSO 2 Q 1,-B(OQ 2)2,-Si(OQ 3)3,-Sn(Q 4)3,Z 1(Z 2)m ,金属乙炔基和末端乙炔基(其中Q表示烃基; Q 2表示氢原子或烃基);两个Q 2可以彼此相同或不同,或者可以一起形成环 Q 3表示烃基,3个Q 3可以相同或不同; Q 4表示烃基,三个Q 4可以彼此不同; Z 1表示 金属原子或金属离子; Z 2表示抗衡阴离子,m为0以上的整数)。 Ar 1和Ar 2独立地表示亚芳基,Ar 3表示芳基,只要Ar 1,Ar 2和Ar 3中的任意两个可以通过取代基彼此结合或直接键合; Y表示如果需要,可以加入氢原子或烃基的具有氮原子,碳原子,硼原子或硅原子的三价原子团; J表示亚芳基; n为0以上的整数, 条件是当分子中存在多个J,Y和Ar 3中的每一个时,它们可以彼此相同或不同。
    • 6. 发明公开
    • METHOD FOR PRODUCING AROMATIC POLYMER
    • VERFAHREN ZUR HERSTELLUNG VON AROMATISCHEM POLYMER
    • EP1854833A1
    • 2007-11-14
    • EP06714236.4
    • 2006-02-15
    • Sumitomo Chemical Company, Limited
    • YOKOZAWA, TsutomuOHUCHI, KazueiKUBOTA, YasuhiroHIGASHIMURA, Hideyuki
    • C08G85/00C08G61/12
    • C08G61/02C08G61/10C08G61/12
    • A method for producing an aromatic polymer comprising polycondensing an aromatic compound of the following formula (I) in the presence of a palladium complex containing a phosphine compound of the following formula (II):

      (wherein, Ar represents an aromatic ring-containing bi-functional organic group. X represents a halogen atom, nitro group or group of the formula -SO 3 Q (wherein, Q represents an optionally substituted hydrocarbon group). Y represents an oxygen atom, sulfur atom or the like, and n represents 0 or 1. M represents a hydrogen atom, -B(OQ 1 ) 2 or the like (Q 1 represents a hydrogen atom or hydrocarbon group.)

              P(R 1 ) 3      (II)

      (wherein, R 1 represents a group of the following formula (III) or a group of the following formula (IV) and three R 1 s may be the same or different, providing at least one of three R 1 s is a group of the following formula (III))

              -C(R 2 ) 3      (III)

      (wherein, R 2 represents a hydrogen atom or an optionally substituted hydrocarbon group)

      (wherein, R 3 to R 7 represent each independently a hydrogen atom, optionally substituted hydrocarbon group or the like).
    • 一种芳香族聚合物的制造方法,其特征在于,在含有下述式(II)的膦化合物的钯络合物的存在下,使下式(I)的芳香族化合物缩聚:(式中,Ar表示含芳环的双 - 官能性有机基团,X表示卤素原子,硝基或式-SO 3 Q基团(其中,Q表示任选取代的烃基),Y表示氧原子,硫原子等,n表示0或 M表示氢原子,-B(OQ 1)2等(Q 1表示氢原子或烃基)。€ƒ€ƒ€ƒ€ƒ€ƒ€ƒP(R 1) 3ƒ€ƒ€ƒ€ƒ(II)(其中,R 1表示下式(III)的基团或下述式(Ⅳ)的基团,并且三个R 1可以相同或不同 ,提供三个R 1中的至少一个是下面的公式(III)的组:€ƒ€€ƒ€ƒ€ƒ€ƒ-C(R 2)3€ƒ (III)(其中,R 2表示氢原子或任选取代的烃基)(其中,R 3〜R 7各自独立地表示氢原子,可以具有取代基的烃基等) 。
    • 7. 发明公开
    • METHOD FOR PRODUCING AROMATIC COMPOUND POLYMER
    • VERFAHREN ZUR HERSTELLUNG VON POLYMEREN AUS AROMATISCHEN VERBINDUNGEN
    • EP1767560A1
    • 2007-03-28
    • EP05755871.0
    • 2005-06-24
    • Sumitomo Chemical Company, Limited
    • HIGASHIMURA, HideyukiFUKUSHIMA, DaisukeOHUCHI, Kazuei
    • C08G61/10C07C49/92C07F9/00
    • C08G61/12C07C49/92C07F9/005C08G61/02C08G61/10
    • A method for producing an aromatic compound polymer comprising oxidatively polymerizing one or more of aromatic compound(s) having two or more hydrogen atoms directly connected to aromatic ring(s), in the presence of an oxidizing agent, wherein the method employs a catalyst composed of a transition metal complex or a catalyst prepared from a transition metal complex and an activating agent, and said catalyst has a parameter P defined by the following formula (A) of 0.50 or more, and a parameter Eo defined by the following formula (B) of 0.50 [V] or more: P = Af / Ai
      (wherein Ai represents an absorbance at an absorption maximum belonging in an absorption band located at the longest wavelength side in an absorption spectrum obtained for a solution containing the catalyst, in a ultraviolet to near-infrared wavelength region from 200 nm to 800 nm, and Af represents an absorbance at the same wavelength applied to the Ai, in an absorption spectrum in the above wavelength region obtained for a solution prepared by adding 3 equivalent of water per mole of the metal contained in the catalyst to the solution), and Eo = Epa + Epc / 2 V
      (wherein, Epa represents a peak potential at the oxidation side of an oxidation-reduction potential derived from the transition metal contained in the catalyst, at a potential of 0.50 [V] or more based on oxidation-reduction potential of ferrocene/ferrocenium ion measured with a cyclic voltammetry for the solution containing the catalyst, and Epc represents a peak potential at the reduction side corresponding to Epa by the same measurement).
    • 一种芳族化合物聚合物的制造方法,其特征在于,在氧化剂的存在下,使直接与芳香环连接的2个以上的氢原子的一种或多种芳香族化合物氧化聚合, 的过渡金属络合物或由过渡金属络合物和活化剂制备的催化剂,所述催化剂具有由下式(A)定义的参数P为0.50以上,以及由下式(B )为0.50 [V]以上:P = Af / Ai(其中,A 1表示在含有催化剂的溶液中获得的吸收光谱中位于最长波长侧的吸收带中的吸收率的吸光度, 至200nm至800nm的近红外波长区域,Af表示在上述波长区域中获得的吸收光谱中施加于Ai的相同波长处的吸光度 通过向溶液中每摩尔催化剂中添加3当量的水制备的溶液)和Eo = Epa + Epc / 2V(其中,Epa表示氧化还原电位的氧化侧的峰值电位 衍生自催化剂中所含的过渡金属,以含有催化剂的溶液的循环伏安法测量的基于二茂铁/二茂铁离子的氧化还原电位为0.50 [V]以上的电位,Epc表示在 通过相同的测量对应于Epa的还原侧)。