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    • 8. 发明公开
    • New polymer and polymer light-emitting device using the same
    • Polymer und Licht-emittierende Vorrichtung unter Verwendung desselben
    • EP2067808A1
    • 2009-06-10
    • EP09004355.5
    • 2002-12-05
    • Sumitomo Chemical Company, Limited
    • Kobayashi, SatoshiNoguchi, TakanobuTsubata, YoshiakiKitano, MakotoDoi, ShujiUeoka, TakahiroNakazono, Akiko
    • C08G61/12
    • C07F9/65683C07D333/76C07D339/08C07F7/0818C08G61/122C08G2261/1424C08G2261/3162C08G2261/3243C08G2261/3244C08G2261/5222C09K11/06C09K2211/1416Y10T428/31663
    • Provided is a polymer having a polystyrene reduced number average molecular weight of 10 3 -10 8 , and comprising a repeating unit of formula (1):

      wherein A 1 is a divalent group represented by -Z- or -Z-Z-, in which Z is an atomic group which may have a substituent; A 1 represents a divalent group in which the bond distance ratio (bond distance C2-A 1 / bond distance C2-C1) is 1.10 or more, in which C2 is the carbon of the α-position, and C1 is the carbon of the β-position, respectively to A 1 ; R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 , each independently represent a hydrogen atom, halogen atom, alkyl group, alkenyl group, alkynyl group, alkyloxy group, alkylthio group, alkylamino group, aryl group, aryloxy group, arylthio group, arylamino group, arylalkyl group, arylalkyloxy group, arylalkylthio group, arylalkylamino group, substituted silyl group, acyl group, acyloxy group, imino group, amide group, arylalkenyl group, arylalkynyl group, monovalent heterocyclic group, or cyano group; R 2 and R 3 may be connected to form a ring; and R 4 and R 5 may be connected to form a ring, wherein A 1 is a divalent group of formula (4):

      wherein R 7 represents an alkyl group, alkyloxy group, alkylthio group, alkylamino group, aryl group, aryloxy group, arylthio group, arylamino group, arylalkyl group, arylalkyloxy group, arylalkylthio group, arylalkylamino group, acyl group, acyloxy group, amide group, or monovalent heterocyclic group.
    • 本发明提供聚苯乙烯换算数均分子量为10 3 -10 8的聚合物,其包含式(1)的重复单元:其中A 1为由-Z-或-ZZ-表示的二价基团,其中Z 是可以具有取代基的原子团; A 1表示键合距离比(键距C2-A 1 /键距C2-C1)为1.10以上的二价基团,其中C2为±位的碳,C1为碳原子数 ²位,分别为A 1; R 1,R 2,R 3,R 4,R 5和R 6各自独立地表示氢原子,卤素原子,烷基,烯基,炔基,烷氧基,烷硫基,烷基氨基,芳基, 芳氧基,芳硫基,芳基氨基,芳基烷基,芳基烷氧基,芳基烷硫基,芳烷基氨基,取代甲硅烷基,酰基,酰氧基,亚氨基,酰胺基,芳基烯基,芳基炔基,1价杂环基或氰基 ; R 2和R 3可以连接形成环; R 4和R 5可以连接形成环,其中A 1是式(4)的二价基团:其中R 7表示烷基,烷氧基,烷硫基,烷基氨基,芳基,芳氧基, 芳基硫基,芳基氨基,芳基烷基,芳基烷氧基,芳基烷硫基,芳烷基氨基,酰基,酰氧基,酰胺基或1价杂环基。