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    • 5. 发明公开
    • FLUORINE-CONTAINING THERMOPLASTIC ELASTOMER COMPOSITION
    • 荧光热塑性弹性体ELASTOMERZUSAMMENSETZUNG
    • EP3027664A1
    • 2016-06-08
    • EP14744306.3
    • 2014-07-24
    • Solvay Specialty Polymers Italy S.p.A.
    • BANDI, SuneelLI, KunSCHILD, PhilipFIGUEROA, EdwinKENT, Bradley Lane
    • C08F210/02C08F214/24C08L27/12H01B3/30
    • C09D127/20C08F210/02C08F214/242C08L27/12C09D127/16H01B3/28H01B3/441H01B3/445C08L23/08C08F214/24C08F216/1408
    • The invention pertains to a thermoplastic vulcanizate fluorine-containing composition [vulcanizate (C)], comprising a continuous thermoplastic fluoropolymer phase and a dispersed vulcanized fluoroelastomer phase, said composition comprising: - at least one thermoplastic fluoropolymer [polymer (F)], said polymer (F) comprising (j) from 40 to 60% by moles of recurring units derived from ethylene (E); (jj) from 60 to 40% by moles of recurring units derived from at least one of chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE); and (jjj) from 0.5 to 10% by moles of recurring units derived from of at least one (per)fluoroalkylvinylether of formula CX2=CX-OR
      f , wherein each of X, equal to or different from each other, is independently H or F (preferably F); and R
      f is a C
      1 -C
      12 (per)fluoroalkyl group or a C
      1 -C
      12 (per)fluoro-oxy-alkyl group comprising one or more than one catenary oxygen atoms [monomer (V)], with % by moles being referred to the total moles of recurring units of the polymer (F); and - at least one (per)fluoroelastomer [elastomer (A)].
    • 本发明涉及包含连续热塑性含氟聚合物相和分散的硫化含氟弹性体相的热塑性硫化橡胶含氟组合物[硫化橡胶(C)],所述组合物包含: - 至少一种热塑性含氟聚合物[聚合物(F)],所述聚合物 (F)包含(j)40-60%(摩尔)衍生自乙烯(E)的重复单元; (jj)60至40摩尔%的由三氟氯乙烯(CTFE)和四氟乙烯(TFE)中的至少一种衍生的重复单元; 和(jjj)0.5至10摩尔%的衍生自式CX2 = CX-ORf的至少一个(全)氟代烷基乙烯基醚的重复单元,其中彼此相同或不同的X各自独立地为H或F (优选F); 并且Rf是包含一个或多于一个链状氧原子的C1-C12(全)氟代烷基或C1-C12(全)氟 - 氧基 - 烷基[单体(V)],其摩尔数相对于 聚合物(F)的重复单元的总摩尔数; 和至少一种(全)氟弹性体[弹性体(A)]。