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    • 1. 发明公开
    • POLYMER COMPOSITION
    • 聚合物组合物
    • EP2401318A1
    • 2012-01-04
    • EP10705591.5
    • 2010-02-22
    • Solvay SA
    • MOORE, TheodoreREICHMANN, Mark G.AVATANEO, MarcoMARCHIONNI, Giuseppe
    • C08G65/323C08G65/40C08L71/02C08L81/06
    • C08G65/007C08G2650/40C08G2650/48C08L71/00C08L71/02C08L79/08C08L81/06C08L2205/05C08L2666/22C08L81/00C08L2666/14
    • The invention pertains to a polymer composition comprising: - at least one polycondensation polymer having a heat deflection temperature (HDT) of above 80°C under a load of 1.82 MPa when measured according to ASTM D648 [polymer (P)]; at least one perfluoropolyether block copolymer [polymer (F)] comprising: A) one or more (per)fluoropolyoxyalkylene segment (chain R
      f ), that is to say a segment comprising recurring units having at least one catenary ether bond and at least one fluorocarbon moiety, and B) one or more polyalkylene segment (chain R
      a ) comprising recurring units of formula: -(CR
      1 R
      2 -CR
      3 R
      4 )- wherein R
      1 , R
      2 , R
      3 , R
      4 , equal to or different from each other, are selected from the group consisting of H, halogens (preferably F, Cl); C
      1 -C
      6 (hydro)carbon groups, optionally containing fluorine or other heteroatoms, preferably perfluoroalkyl or (per)fluorooxyalkyl, to a process for its manufacture and to its use for manufacturing shaped articles, in particular by extrusion moulding or injection moulding techniques.
    • 本发明涉及一种聚合物组合物,其包含: - 当根据ASTM D648 [聚合物(P)]测量时,在1.82MPa的负荷下具有高于80℃的热挠曲温度(HDT)的至少一种缩聚聚合物; 至少一种全氟聚醚嵌段共聚物[聚合物(F)],其包含:A)一种或多种(全)氟聚氧化烯链段(链R f),即包含具有至少一个链状醚键的重复单元的链段和至少一个 氟碳部分,和B)一个或多个包含下式的重复单元的聚亚烷基链段(链R a): - (CR 1 R 2 -CR 3 R 4) - 其中R 1,R 2,R 3,R 4等于或不同 彼此相邻,选自H,卤素(优选F,Cl); 任选含有氟或其它杂原子,优选全氟烷基或(全)氟烷基的C 1 -C 6(氢)碳基团,涉及其制造方法及其用于制造成型制品的用途,特别是通过挤出成型或注射成型技术 。
    • 3. 发明公开
    • METHOD FOR MANUFACTURING SULFONE POLYMER MEMBRANE
    • 一种用于生产砜
    • EP2935420A1
    • 2015-10-28
    • EP13818727.3
    • 2013-12-18
    • Solvay SA
    • MOORE, TheodoreCHEN, HongBOURDETTE, Arnaud
    • C08J5/22B01D71/68B01D67/00
    • B01D67/0011B01D67/0013B01D69/04B01D69/06B01D71/68C08J5/18C08J5/2256C08J2381/06
    • The invention pertains to a method for manufacturing a sulfone polymer membrane comprising the steps of: (i) preparing a sulfone polymer solution [solution (SP)] comprising: —at least one sulfone polymer [polymer (P)]; a solvent mixture [mixture (M)] comprising: at least one solvent selected from the group consisting of diesters of formula (Ide) and ester-amide of formula (lea), and optionally comprising at least one diamide of formula (Ida): R1—OOC-Ade-COO—R2 (lde); R1—OOC-AeaCO—NR3R4 (lea); R5R6N—OC-Ada-CO—NR5R6 (lda), wherein: R1 and R2, equal to or different from each other, are independently selected from the group consisting of C1-C20 hydrocarbon groups; R3, R4, R5 and R6 equal to or different from each other and at each occurrence, are independently selected from the group consisting of hydrogen, C1-C36 hydrocarbon groups, possibly substituted, being understood that R3 and R4 might be part of a cyclic moiety including the nitrogen atom to which they are bound, said cyclic moiety being possibly substituted and/or possibly comprising one or more than one additional heteroatom, and mixtures thereof; Ade, Aea, and Ada equal to or different from each other, are independently a linear or branched divalent alkylene group, and optionally dimethylsulfoxide (DMSO); (ii) processing said solution (SP) into a film; (iii) immersing said film in a non-solvent bath.