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    • 3. 发明公开
    • Fluorescent compound, method for producing the same, and fluorescent resin composition
    • 佛罗伦萨VERBINDUNG,VERFAHREN ZU IHRER HERSTELLUNG,UND HARZZUSAMMENSETZUNG
    • EP2767571A1
    • 2014-08-20
    • EP14155284.4
    • 2014-02-14
    • Shin-Etsu Chemical Co., Ltd.
    • Itoh, YusukeKiyomori, Ayumu
    • C09K11/06C07F7/08
    • C08K5/544C07F7/0854C09K11/06C09K2211/1007C09K2211/1014
    • An object of the present invention is to provide a fluorescent compound that has an excellent compatibility with resins and can be incorporated into a resin composition in a simple way, a method of producing the same, and a fluorescent resin composition containing the same. The present invention provides a fluorescent compound represented by the following general formula (1):

      wherein R 1 to R 4 each independently represent a substituent selected from a linear, branched or cyclic monovalent hydrocarbon group having 1 to 20 carbon atoms, alkoxy group having 1 to 20 carbon atoms, aryloxy group having 6 to 20 carbon atoms, halogen atom, hydrogen atom, amino group, cyano group, amine-containing group, and siloxane-containing group; with the proviso that when an amine-containing group as the substituent is not included, at least one of R 1 to R 4 is a siloxane-containing group represented by S x -A-, and that when an amine-containing group as the substituent is included, at least one of R 1 to R 4 and a substituent of the amine-containing group is a siloxane-containing group represented by S x -A-; a method of producing the same; and a fluorescent resin composition containing the same.
    • 本发明的目的是提供一种与树脂相容性优异并且可以以简单的方式并入树脂组合物中的荧光化合物,其制备方法和含有该荧光化合物的荧光树脂组合物。 本发明提供由以下通式(1)表示的荧光化合物:其中R 1至R 4各自独立地表示选自具有1至20个碳原子的直链,支链或环状一价烃基的取代基,烷氧基具有1 20个碳原子,具有6〜20个碳原子的芳氧基,卤原子,氢原子,氨基,氰基,含胺基团和含硅氧烷基团; 条件是当不包括含胺基团作为取代基时,R 1至R 4中的至少一个为由S x -A-表示的含硅氧烷基团,当含胺基团为 包括取代基,R 1至R 4中的至少一个和含胺基团的取代基是由S x -A-表示的含硅氧烷的基团; 其制造方法; 和含有它们的荧光树脂组合物。
    • 6. 发明公开
    • Silanol-containing triarylamine derivatives
    • 硅烷醇三芳基胺衍生物
    • EP2457917A1
    • 2012-05-30
    • EP11009278.0
    • 2011-11-23
    • Shin-Etsu Chemical Co., Ltd.
    • Itoh, YusukeKiyomori, Ayumu
    • C07F7/08H01L51/00
    • C07F7/0836H01L51/0059H01L51/0094H01L51/5056
    • To provide a triarylamine derivative excellent in compatibility with various organic solvents or resins, capable of forming a silicon-oxygen bond on the surface of an inorganic material, and allowing easy purification; a preparation process of the triarylamine derivative; an intermediate product of the triarylamine derivative; an inorganic composite material obtained by bonding the triarylamine derivative to the surface of an inorganic material; and a preparation process of the inorganic composite material.
      More specifically, provided are a silanol-containing triarylamine derivative represented by the following formula (1):

      (wherein, at least one of R 1 , R 4 , R 6 , R 9 , R 11 , and R 14 is a substituent represented by SiR 16 R 17 OH (R 16 and R 17 each independently representing a linear, branched, or cyclic C 1-20 monovalent hydrocarbon); a preparation process of the triarylamine derivative; an intermediate product of the triarylamine derivative; an inorganic composite material obtained by bonding the triarylamine derivative to the surface of an inorganic material; and a preparation process of the material.
    • 提供能够在无机材料的表面上形成硅 - 氧键的各种有机溶剂或树脂的相容性优异的三芳基胺衍生物,并且易于纯化; 三芳基胺衍生物的制备方法; 三芳基胺衍生物的中间产物; 通过将三芳基胺衍生物键合到无机材料的表面而获得的无机复合材料; 和无机复合材料的制备方法。 更具体地,提供由下式(1)表示的含硅烷醇的三芳基胺衍生物:(其中,R 1,R 4,R 6,R 9,R 11和R 14中的至少一个为由 SiR 16 R 17 OH(R ​​16和R 17各自独立地表示直链,支链或环状的C 1-20一价烃);三芳基胺衍生物的制备方法;三芳基胺衍生物的中间产物;获得的无机复合材料 通过将三芳基胺衍生物键合到无机材料的表面;以及该材料的制备方法。