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    • 2. 发明公开
    • Shaped articles of synthetic resins having improved surface properties and method for making same
    • 由合成树脂制成的模塑制品具有改进的表面性能和其制备方法。
    • EP0057835A1
    • 1982-08-18
    • EP82100417.3
    • 1982-01-21
    • Shin-Etsu Chemical Co., Ltd.
    • Ueno, SusumuNomura, HirokazuImada, Kiyoshi
    • B29C71/04C08J7/12
    • C08J7/123
    • The invention provides a novel shaped article of a synthetic resin, such as vinyl chloride-based resins and fluorocarbon resins, remarkably insusceptible to the accumulation of static electricity on the surface. The inventive shaped article is characteristic in having a surface layer which has been subjected to exposure to low temperature plasma generated in a gaseous atmosphere containing an organosilane compound represented by the general formula R a H b SiX 4-a-b , in which R is a monovalent hydrocarbon group, X is a halogen atom or an alkoxy group, a is 1, or 3 and b is 0 or 1 with the proviso that a+b is 1, 2 or 3, or a hydrolysis condensation product thereof. The strong antistatic performance of the shaped article is presumably due to the fact that the surface layer thereof has a structure modified by the plasma treatment although true nature of the structure modification is not well understood.
    • 本发明提供一种合成树脂,颜色的一种新颖的成形制品:如基于氯乙烯树脂和氟树脂,显着地不易受到静电的表面上的积累。 本发明的成型制品在具有已经经历暴露于在气态气氛中,在由通式RaHbSiX4断,其中R是一价烃基为代表的有机硅烷化合物含有生成的低温等离子体的表面层是特性,X是 卤原子或烷氧基,a为1,2或3,b为0或1,条件做a + b为1,2或3,或水解缩合物。 成形制品的强的抗静电性能可能是由于所述factthat其表面层具有通过等离子体处理改性的结构虽然结构修饰的真正性质还没有很好理解的。
    • 4. 发明公开
    • A synthetic resin foamed body and a method for the preparation thereof
    • Schaumgegenstand aus Kunstharz und Verfahren zu dessen Herstellung。
    • EP0103733A2
    • 1984-03-28
    • EP83107861.3
    • 1983-08-09
    • Shin-Etsu Chemical Co., Ltd.
    • Imada, KiyoshiTsuchida, MichinoriEguchi, YoshituguMatsumoto, Osamu
    • C08L27/24C08J9/14
    • C08J9/0061C08J2327/24C08L27/24C08L27/06C08L33/00C08L25/08
    • The invention provides a foamed body of a chlorine-containing synthetic resin of high expansion with extremely low bulk density still retaining very fine and uniform cellular structure. Different from conventional foamed bodies of polyvinyl chloride resins, the inventive foamed body is formed of a chlorinated polyvinyl chloride resin so that the foamed body has excellent heat resistance. The method for the preparation of the foamed resin comprises: preparing a resin composition comprising a chlorinated polyvinyl chloride resin or a mixture thereof with a polyvinyl chloride resin, a foam conditioning resin, e.g. an acrylic resin or a styrene-based resin, and a cell uniformnizing agent, e.g. a heat-decomposable blowing agent or an inorganic fine powder; supplying the resin composition to the cylinder of an extruder machine; uniformly impregnating the at leat partly molten resin composition in the cylinder with a volatilizable blowing agent by pressurization; and shaping the resin composition by extruding out of the extruder with simultaneous expansion by foaming.
    • 本发明提供了具有极低堆积密度的高膨胀的含氯合成树脂的发泡体,仍然保持非常细且均匀的蜂窝结构。 与传统的聚氯乙烯发泡体不同,本发明的发泡体由氯化聚氯乙烯树脂形成,使发泡体具有优异的耐热性。 制备发泡树脂的方法包括:制备包含氯化聚氯乙烯树脂或其与聚氯乙烯树脂的混合物的树脂组合物,泡沫调理树脂,例如, 丙烯酸树脂或苯乙烯类树脂,和细胞均匀剂,例如, 热分解发泡剂或无机细粉末; 将树脂组合物供给到挤出机的圆筒中; 用可挥发的发泡剂通过加压均匀地浸渍在圆筒中的部分熔融的树脂组合物; 并通过挤出机同时膨胀通过发泡挤出成型树脂组合物。