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1. 发明公开

EP1904422A1 INTEGRATED PROCESS FOR PRODUCING HYDROCARBONS 审中-公开
标题翻译：集成方法烃类FOR动作的准备和方法
公开(公告)号：EP1904422A1
公开(公告)日：2008-04-02
申请号：EP06764177.9
申请日：2006-07-14
申请人： Shell Internationale Research Maatschappij B.V.
发明人： SCHOLTEN, Wilhelmus, Johannes, Franciscus , TIO, Thian, Hoey
IPC分类号： C07C1/04 , C10G2/00
CPC分类号： C10G2/00 , C10G2300/1022 , C10G2300/4012
摘要： A method to start up a process for the production of normally gaseous, normally liquid, and optionally normally solid hydrocarbon products from a. hydrocarbonaceous feedstock comprising ths steps of (1) producing high pressure (HP) steam, preferably HP superheated steam, by means of at least one gas turbine generator and optionally one or more boilers fed with a hydrocarbonaceous feedstock.; (2) reducing the pressure of at least part of the HP steam produced according to step 1 to medium pressure (MP) steam; (3) using at least part of the MP steam produced according to step 2 to drive a compressor ; (4) using the compressor to drive one or more means for compressing and optionally separating an oxygen containing gas; (5) using at least part of the oxygen containing gas to convert a hydrocarbonaceous feedstock into synthesis gas; (6) converting the synthesis gas produced according to step 5 exothermally to a range of normally gaseous, normally liquid, and optionally normally solid hydrocarbon products in a Fischer-Tropsch reaction; (7) controlling the reaction temperature of step 6 by indirect heat exchange of the reaction medium with water, the water being converted to saturated steam (FT steam); (8) separating the hydrocarbon products produced in step 6 into a light product stream (comprising any unconverted syngas and at least part of the normally-gaseous hydrocarbon products) and a heavy product stream (comprising the normally liquid and optionally normally solid hydrocarbon products) ; (9) feeding at least part of the light product stream to one or more gas turbine generators to form combusted gas and expanding said combusted gas through an expansion chamber of the gas turbine generator (s) to form hot flue gas and energy; (10) heating boiler feed water by heat exchange with the hot flue gas to produce additional high pressure (HP), preferably superheated, steam, (11) cooling and/or condensing at least a part of the HP steam produced in step 10 in a heat exchanger against at least part of the FT steam produced in step 7 to produce additional MP steam for use in generating electrical and/or mechanical energy for steps 1 to 10; and optionally (12) reducing the pressure of at least part of the superheated HP steam produced in step 10 to medium pressure (MP) steam for use in earlier steps .

2. 发明公开

EP1794083A1 INTEGRATED PROCESS FOR HYDROCARBON SYNTHESIS 审中-公开
标题翻译：集成方法合成烃类
公开(公告)号：EP1794083A1
公开(公告)日：2007-06-13
申请号：EP05789543.5
申请日：2005-10-04
申请人： Shell Internationale Research Maatschappij B.V.
发明人： SCHOLTEN, Wilhelmus, Johannes, Franciscus , TIO, Thian, Hoey
IPC分类号： C01B3/34 , C01B3/38
CPC分类号： C01B3/382 , C01B3/36 , C01B3/384 , C01B2203/0227 , C01B2203/0244 , C01B2203/0255 , C01B2203/0261 , C01B2203/0475 , C01B2203/062 , C01B2203/0844 , C01B2203/141 , C01B2203/142 , C01B2203/148 , C01B2203/82 , C10G2/32 , Y02P20/125
摘要： A process for the preparation of syngas from a hydrocarbonaceous feedstock is described. It comprises the steps of: (i) splitting the hydrocarbonaceous feedstock into a first feedstock stream and a second feedstock stream; (ii) catalytically reforming the first feedstock stream in at least one reforming zone to produce a reforming product; (iii) oxidising the second feedstock stream in at least one partial oxidation zone to produce a partial oxidation product; (iv) mixing some or all of the reforming product and some or all of the partial oxidation product to produce a heating gas (syngas) in a mixing zone which is separated from the reforming zone and the partial oxidation zone; (v) heating the reforming zone(s) by means of the heating gas; and (vi) optionally separating carbon dioxide from the cooled heating gas to produce a carbon dioxide depleted syngas stream. The syngas can be used to produce hydrocarboneous products, e.g. by the Fischer Tropsch process. The invention provides an integrated process for the production of hydrocarbon products from a hydrocarboneous feedstock. Operation of the reforming step and the partial oxidation step in parallel as opposed to in series provides an effective means for balancing the energy characteristics of the two steps. The process of the invention also facilitates flexible operation in that the H2/CO ratio can be readily tuned in a number of ways.

3. 发明公开

EP1622827A1 REACTOR FOR PERFORMING A STEAM REFORMING REACTION AND A PROCESS TO PREPARE SYNTHESIS GAS 审中-公开
标题翻译：反应器实施蒸汽重整反应和方法生产合成气
公开(公告)号：EP1622827A1
公开(公告)日：2006-02-08
申请号：EP04727011.1
申请日：2004-04-13
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： BERGGREN, Wouter, Detlof , VAN DONGEN, Franciscus, Gerardus , TIO, Thian, Hoey , ZUIDEVELD, Pieter, Lammert
IPC分类号： C01B3/38 , B01J8/06 , B01J8/00
CPC分类号： B01J8/067 , B01J8/008 , B01J8/0449 , B01J8/0496 , B01J8/062 , B01J2208/00309 , B01J2208/00495 , B01J2208/00504 , C01B3/382 , C01B3/384 , C01B2203/00 , C01B2203/0233 , C01B2203/0244 , C01B2203/025 , C01B2203/0255 , C01B2203/0405 , C01B2203/042 , C01B2203/062 , C01B2203/0844 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/141 , C01B2203/142 , C01B2203/143 , C01B2203/148 , C01B2203/82
摘要： Reactor vessel for performing a steam reforming reaction comprising: a vessel inlet for natural gas and steam (2), a vessel inlet for a hot gaseous medium (3), a vessel outlet for a gaseous product comprising the steam reforming product (4), and a reactor space (7) comprising of a bed of steam reforming catalyst (8), which reactor space inlet is fluidly connected to the inlet for natural gas and steam and at its outlet end fluidly connected with the outlet for the gaseous product, wherein inside the catalyst bed a passageway (9) is provided fluidly connected to the vessel inlet for the hot gaseous medium for passage of hot gaseous mixture counter currently to the flow of reactants in the catalyst bed.

4. 发明授权

EP1414771B1 INTEGRATED PROCESS FOR HYDROCARBON SYNTHESIS 有权
标题翻译：综合烃合成方法
公开(公告)号：EP1414771B1
公开(公告)日：2005-03-02
申请号：EP02747450.1
申请日：2002-06-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： DE GRAAF, Winnifred , MOHAMAD ALI, Abdul, Razak , TIO, Thian, Hoey
IPC分类号： C07C2/00
CPC分类号： C10G2/32 , C01B3/382 , C01B3/384 , C01B2203/0227 , C01B2203/0261 , C01B2203/062 , C01B2203/0827 , C01B2203/0844 , C01B2203/142 , C01B2203/148 , Y02P20/125
摘要： Process for producing liquid hydrocarbons from a hydrocarbonaceous feedstock which comprises the following steps: (i) catalytically reforming at least part of the hydrocarbonaceous feedstock at elevated temperature and pressure with steam in at least one reforming zone; (ii) heating the reforming zone (s) by means of a carbon dioxide containing heating gas comprising a product obtained by partial oxidation of reformer product obtained in step (i) and carbon dioxide depleted light product obtained in step (vi) with an oxygen-containing gas in an oxidation zone; (iii) separating carbon dioxide from cooled down heating gas obtained in step (ii); (iv) catalytically converting at leasts part of the carbon dioxide depleted gas stream obtained in step (iii) at elevated temperature and pressure into normally liquid hydrocarbons; (v) separating product stream obtained in step (iv) into a light product comprising mainly unconverted synthesis gas, inerts and light hydrocarbons and a heavy product comprising mainly normally liquid and solid hydrocarbons; (vi) separating carbon dioxide from light product obtained in step (v); and (vii) combining at least part of the carbon dioxide feed obtained in step (iii) and/or step (vi) with hydrocarbonaceous for step (i).

5. 发明公开

EP1742901A1 SYSTEM AND PROCESS FOR SYNTHESIS OF METHANOL 审中-公开
标题翻译：系统和方法合成甲醇的
公开(公告)号：EP1742901A1
公开(公告)日：2007-01-17
申请号：EP05743070.4
申请日：2005-05-04
申请人： Shell Internationale Research Maatschappij B.V.
发明人： JENZER, Gregor, August , TIO, Thian, Hoey , ZUIDEVELD, Pieter, Lammert
IPC分类号： C07C29/151 , C07C31/04
CPC分类号： C07C29/1518 , C07C31/04
摘要： System and process for synthesising methanol out of a source gas containing light hydrocarbons. The system comprises - a hydrocarbon gas supply (3) for providing the source gas;- an oxygen supply (1) for providing an oxygen containing fluid;- a syngas reactor (2) in the form of a gasification reactor, arranged to receive the source gas from the hydrocarbon gas supply (3) and the oxygen containing fluid from the oxygen supply (1), the syngas reactor (2) being arranged to produce an intermediate reaction product from the source gas and the oxygen containing fluid, and to discharge the intermediate reaction product, the intermediate reaction product comprising syngas;- a methanol reactor (5), arranged to receive at least a fraction of the intermediate reaction product from the syngas reactor, and arranged to let the intermediate reaction product react into at least methanol via a methanol forming reaction, the methanol reactor being provided with a methanol outlet (11) for discharging the formed methanol and an offgas outlet (12) for discharging an offgas.

6. 发明授权

EP1438534B1 PROCESS TO REDUCE THE TEMPERATURE OF A HYDROGEN AND CARBON MONOXIDE CONTAINING GAS AND HEAT EXCHANGER FOR USE IN SAID PROCESS 有权
标题翻译：用于减少的氢和一氧化碳温度含气，热交换具体实施这个过程
公开(公告)号：EP1438534B1
公开(公告)日：2012-11-14
申请号：EP02785273.0
申请日：2002-10-22
申请人： Shell Internationale Research Maatschappij B.V.
发明人： VAN DONGEN, Franciscus, Gerardus , DE GRAAF, Winnifred , TIO, Thian, Hoey , WOLFERT, Anthonij
IPC分类号： F22B37/04 , F22B1/18
CPC分类号： F28F21/087 , B01J19/02 , B01J2219/00094 , B01J2219/029 , B23K9/04 , B32B15/013 , C01B3/36 , C01B3/382 , C01B3/386 , C01B2203/0233 , C01B2203/0238 , C01B2203/0255 , C01B2203/0844 , C01B2203/0883 , C01B2203/142 , C01B2203/148 , C22C27/06 , C22C30/00 , F22B37/04 , F28F19/00 , Y02P20/142 , Y02P20/52

7. 发明公开

EP1926885A1 METHOD OF PRODUCING A HYDROCARBON STREAM FROM A SUBTERRANEAN ZONE 审中-公开
标题翻译：用于生产烃物流从地下区域
公开(公告)号：EP1926885A1
公开(公告)日：2008-06-04
申请号：EP06793611.2
申请日：2006-09-19
申请人： Shell Internationale Research Maatschappij B.V.
发明人： VAN DER PLOEG, Hendrik, Jan , TIO, Thian, Hoey , ZUIDEVELD, Pieter, Lammert
IPC分类号： E21B43/16
CPC分类号： E21B43/168
摘要： The present invention relates to a method of producing a hydrocarbon containing stream (110) from a subterranean zone (100) wherein an injection fluid (50) is injected into the subterranean zone (100), the method at least comprising the steps of: (a) providing an injection fluid (50) comprising synthesis gas; (b) injecting the injection fluid (50) into a subterranean zone (100) for obtaining a desired pressure therein; (c) obtaining a hydrocarbon containing stream (110) from the subterranean zone (100).

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