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1. 发明授权

EP2174963B1 Metallocene catalysts for olefin polymerization and methog of polymerizing olefins using the metallocene catalysts 有权
标题翻译：用于烯烃聚合的茂金属催化剂和使用茂金属催化剂聚合烯烃的方法
公开(公告)号：EP2174963B1
公开(公告)日：2013-02-27
申请号：EP09016141.5
申请日：1999-09-08
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Chang, Seok , Yoon, Keun-Byoung , Jung, Won-Cheol
IPC分类号： C08F210/00 , C08F4/642 , C07F17/00 , C08F10/00 , C08F4/6592
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F4/65904

2. 发明公开

EP2174963A3 Metallocene catalysts for olefin polymerization and methog of polymerizing olefins using the metallocene catalysts 有权
公开(公告)号：EP2174963A3
公开(公告)日：2012-05-02
申请号：EP09016141.5
申请日：1999-09-08
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Chang, Seok , Yoon, Keun-Byoung , Jung, Won-Cheol
IPC分类号： C08F210/00 , C08F4/642 , C07F17/00 , C08F10/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F4/65904
摘要： The new metallocene catalysts according to the present invention are prepared by reacting a metallocene compound with a compound having at least two functional groups. The metallocene compound is a transition metal compound, which is coordinated with a main ligand such as cyclopentadienyl group, and an ancillary ligand. The functional groups in the compound are selected from the group consisting of a hydroxyl group, an alkyl or aryl magnesium halide, a thiol group, a primary amine group, a secondary amine group, a primary phosphorous group, a secondary phosphorous group, etc. The metallocene catalysts according to the present invention have a structure in which an ancillary ligand of a metallocene compound is bonded to the functional groups of a compound having at least two functional groups. A structure of the metallocene catalysts can be varied with the type of a metallocene compound and a compound having at least two functional groups, and the molar ratio of each reactant. The metallocene catalysts are employed with a co-catalyst for olefin polymerization. The co-catalyst is an organometallic compound, or a mixture of non-coordinated Lewis acid and alkyl aluminium as it is well known in the art.

3. 发明公开

EP2174963A2 Metallocene catalysts for olefin polymerization and methog of polymerizing olefins using the metallocene catalysts 有权
标题翻译：用于烯烃聚合的茂金属催化剂和使用茂金属催化剂聚合烯烃的方法
公开(公告)号：EP2174963A2
公开(公告)日：2010-04-14
申请号：EP09016141.5
申请日：1999-09-08
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Chang, Seok , Yoon, Keun-Byoung , Jung, Won-Cheol
IPC分类号： C08F210/00 , C08F4/642 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F4/65904
摘要： The new metallocene catalysts according to the present invention are prepared by reacting a metallocene compound with a compound having at least two functional groups. The metallocene compound is a transition metal compound, which is coordinated with a main ligand such as cyclopentadienyl group, and an ancillary ligand. The functional groups in the compound are selected from the group consisting of a hydroxyl group, an alkyl or aryl magnesium halide, a thiol group, a primary amine group, a secondary amine group, a primary phosphorous group, a secondary phosphorous group, etc. The metallocene catalysts according to the present invention have a structure in which an ancillary ligand of a metallocene compound is bonded to the functional groups of a compound having at least two functional groups. A structure of the metallocene catalysts can be varied with the type of a metallocene compound and a compound having at least two functional groups, and the molar ratio of each reactant. The metallocene catalysts are employed with a co-catalyst for olefin polymerization. The co-catalyst is an organometallic compound, or a mixture of non-coordinated Lewis acid and alkyl aluminium as it is well known in the art.
摘要翻译：根据本发明的新型茂金属催化剂通过使茂金属化合物与具有至少两个官能团的化合物反应来制备。茂金属化合物是过渡金属化合物，其与主要配体如环戊二烯基和辅助配体配位。化合物中的官能团选自羟基，烷基或芳基卤化镁，硫醇基，伯胺基，仲胺基，伯磷基，仲磷基等。根据本发明的茂金属催化剂具有其中茂金属化合物的辅助配体与具有至少两个官能团的化合物的官能团键合的结构。茂金属催化剂的结构可以随茂金属化合物和具有至少两个官能团的化合物的类型以及每种反应物的摩尔比而变化。茂金属催化剂与用于烯烃聚合的助催化剂一起使用。该助催化剂是一种有机金属化合物，或者是非配位路易斯酸和烷基铝的混合物，这在本领域中是众所周知的。

4. 发明授权

EP0964004B1 New metallocene catalyst for olefin or styrene polymerization and polymerization method using the metallocene catalyst 有权
标题翻译：使用这些茂金属催化剂新型茂金属催化剂进行烯烃与苯乙烯聚合和
公开(公告)号：EP0964004B1
公开(公告)日：2003-08-20
申请号：EP99102164.3
申请日：1999-02-03
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Yim, Jin-Heong
IPC分类号： C08F4/60 , C08F12/04 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F12/08 , C08F2410/03 , C08F2420/04 , C08F4/6592

5. 发明公开

EP2174964A3 Metallocene catalysts for olefin polymerization and method of polymerizing olefins using the metallocene catalysts 有权
标题翻译：用于烯烃聚合的茂金属催化剂和使用茂金属催化剂聚合烯烃的方法
公开(公告)号：EP2174964A3
公开(公告)日：2012-05-02
申请号：EP09016142.3
申请日：1999-09-08
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Chang, Seok , Yoon, Keun-Byoung , Jung, Won-Cheol
IPC分类号： C08F210/00 , C08F4/642 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F4/65904
摘要： The new metallocene catalysts according to the present invention are prepared by reacting a metallocene compound with a compound having at least two functional groups. The metallocene compound is a transition metal compound, which is coordinated with a main ligand such as cyclopentadienyl group, and an ancillary ligand. The functional groups in the compound are selected from the group consisting of a hydroxyl group, an alkyl or aryl magnesium halide, a thiol group, a primary amine group, a secondary amine group, a primary phosphorous group, a secondary phosphorous group, etc. The metallocene catalysts according to the present invention have a structure in which an ancillary ligand of a metallocene compound is bonded to the functional groups of a compound having at least two functional groups. A structure of the metallocene catalysts can be varied with the type of a metallocene compound and a compound having at least two functional groups, and the molar ratio of each reactant. The metallocene catalysts are employed with a co-catalyst for olefin polymerization. The co-catalyst is an organometallic compound, or a mixture of non-coordinated Lewis acid and alkyl aluminium as it is well known in the art.
摘要翻译：根据本发明的新型茂金属催化剂通过使茂金属化合物与具有至少两个官能团的化合物反应来制备。茂金属化合物是过渡金属化合物，其与主要配体如环戊二烯基和辅助配体配位。化合物中的官能团选自羟基，烷基或芳基卤化镁，硫醇基，伯胺基，仲胺基，伯磷基，仲磷基等。根据本发明的茂金属催化剂具有其中茂金属化合物的辅助配体与具有至少两个官能团的化合物的官能团键合的结构。茂金属催化剂的结构可以随茂金属化合物和具有至少两个官能团的化合物的类型以及每种反应物的摩尔比而变化。茂金属催化剂与用于烯烃聚合的助催化剂一起使用。该助催化剂是一种有机金属化合物，或者是非配位路易斯酸和烷基铝的混合物，这在本领域中是众所周知的。

6. 发明公开

EP2174964A8 Metallocene catalysts for olefin polymerization and method of polymerizing olefins using the metallocene catalysts 有权
标题翻译：使用这些金属茂催化剂的金属茂催化剂的烯烃聚合和工艺用于烯烃聚合
公开(公告)号：EP2174964A8
公开(公告)日：2010-06-30
申请号：EP09016142.3
申请日：1999-09-08
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Chang, Seok , Yoon, Keun-Byoung , Jung, Won-Cheol
IPC分类号： C08F210/00 , C08F4/642 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F4/65904
摘要： The new metallocene catalysts according to the present invention are prepared by reacting a metallocene compound with a compound having at least two functional groups. The metallocene compound is a transition metal compound, which is coordinated with a main ligand such as cyclopentadienyl group, and an ancillary ligand. The functional groups in the compound are selected from the group consisting of a hydroxyl group, an alkyl or aryl magnesium halide, a thiol group, a primary amine group, a secondary amine group, a primary phosphorous group, a secondary phosphorous group, etc. The metallocene catalysts according to the present invention have a structure in which an ancillary ligand of a metallocene compound is bonded to the functional groups of a compound having at least two functional groups. A structure of the metallocene catalysts can be varied with the type of a metallocene compound and a compound having at least two functional groups, and the molar ratio of each reactant. The metallocene catalysts are employed with a co-catalyst for olefin polymerization. The co-catalyst is an organometallic compound, or a mixture of non-coordinated Lewis acid and alkyl aluminium as it is well known in the art.

7. 发明授权

EP2174964B1 Metallocene catalysts for olefin polymerization and method of polymerizing olefins using the metallocene catalysts 有权
标题翻译：用于烯烃聚合的茂金属催化剂和使用茂金属催化剂聚合烯烃的方法
公开(公告)号：EP2174964B1
公开(公告)日：2013-02-20
申请号：EP09016142.3
申请日：1999-09-08
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Chang, Seok , Yoon, Keun-Byoung , Jung, Won-Cheol
IPC分类号： C08F4/6592 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F4/65904

8. 发明公开

EP2174964A2 Metallocene catalysts for olefin polymerization and method of polymerizing olefins using the metallocene catalysts 有权
标题翻译：使用这些金属茂催化剂的金属茂催化剂的烯烃聚合和工艺用于烯烃聚合
公开(公告)号：EP2174964A2
公开(公告)日：2010-04-14
申请号：EP09016142.3
申请日：1999-09-08
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Chang, Seok , Yoon, Keun-Byoung , Jung, Won-Cheol
IPC分类号： C08F210/00 , C08F4/642 , C07F17/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/03 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F4/65904
摘要： The new metallocene catalysts according to the present invention are prepared by reacting a metallocene compound with a compound having at least two functional groups. The metallocene compound is a transition metal compound, which is coordinated with a main ligand such as cyclopentadienyl group, and an ancillary ligand. The functional groups in the compound are selected from the group consisting of a hydroxyl group, an alkyl or aryl magnesium halide, a thiol group, a primary amine group, a secondary amine group, a primary phosphorous group, a secondary phosphorous group, etc. The metallocene catalysts according to the present invention have a structure in which an ancillary ligand of a metallocene compound is bonded to the functional groups of a compound having at least two functional groups. A structure of the metallocene catalysts can be varied with the type of a metallocene compound and a compound having at least two functional groups, and the molar ratio of each reactant. The metallocene catalysts are employed with a co-catalyst for olefin polymerization. The co-catalyst is an organometallic compound, or a mixture of non-coordinated Lewis acid and alkyl aluminium as it is well known in the art.
摘要翻译： gemäß到本发明的新的金属茂催化剂是由金属茂起反应与具有至少两个官能团的化合物的化合物来制备。金属茂化合物是配位的主配体的过渡金属化合物，在所有：如环戊二烯基，和配体，以辅助。该化合物中的官能团选自羟基，烷基或卤化镁，硫醇基，伯胺基，仲胺基团，伯磷基，仲磷基等的芳基中选择的 gemäß到本发明的金属茂催化剂具有其中一种茂金属化合物的辅助配位体被结合到具有至少两个官能团的化合物的官能团的结构。金属茂催化剂的结构可与金属茂化合物的种类和具有至少两个官能团的化合物，并且每个反应物的摩尔比而变化。茂金属催化剂采用与助催化剂用于烯烃聚合。所述助催化剂为有机金属化合物，或如本领域中公知的非协调的路易斯酸和烷基铝的混合物。

9. 发明公开

EP0964004A1 New metallocene catalyst for olefin or styrene polymerization and polymerization method using the metallocene catalyst 有权
标题翻译：使用这些茂金属催化剂新型茂金属催化剂进行烯烃与苯乙烯聚合和
公开(公告)号：EP0964004A1
公开(公告)日：1999-12-15
申请号：EP99102164.3
申请日：1999-02-03
申请人： Samsung General Chemicals Co., Ltd.
发明人： Lyu, Yi-Yeol , Yim, Jin-Heong
IPC分类号： C08F4/60 , C08F12/04 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F12/08 , C08F2410/03 , C08F2420/04 , C08F4/6592
摘要： The new metallocene catalysts according to the present invention are prepared by reacting a metallocene compound with a compound having at least two functional groups. The metallocene compound is a transition metal compound in which a transition metal is coordinated with a main ligand such as cycloalkanedienyl group and an ancillary ligand. The functional groups of the compound having at least two functional groups are selected from the group consisting of a hydroxy group, a thiol group, a primary amine group, a secondary amine group, etc. The metallocene catalysts according to the present invention have a structure in which an ancillary ligand of a metallocene compound is bonded with functional groups. A structure of the metallocene catalysts can be varied according to the metallocene compounds, the compound having at least two functional groups, and the molar ratio of each reactant. The metallocene catalyst is employed with a co-catalyst for styrene and olefin polymerization. The co-catalyst is an organometallic compound or a mixture of non-coordinated Lewis acid and alkylaluminium. The organometallic compound is usually alkylaluminoxane and organoaluminium compound. The syndiotactic polystyrenes and the polyolefins having good physical properties are prepared by using the metallocene catalyst according to the present invention. A monomer for polymerization includes styrene, derivatives of styrene, and a compound having ethylenically unsaturated double bonds. Those compounds are homopolymerized and copolymerized to give polystyrene and polyolefin.
摘要翻译： gemäß到本发明的新的金属茂催化剂是由金属茂起反应与具有至少两个官能团的化合物的化合物来制备。金属茂化合物是其中的过渡金属配位有配体的主要的过渡金属化合物：如环烷二烯基和配体的辅助。具有至少两个官能团的化合物的官能团选自羟基，巯基，伯胺基团，仲胺基团，的选择等的金属茂催化剂雅丁到本发明具有这样的结构在其中的金属茂化合物的辅助配位体的键合的官能团。金属茂催化剂的结构可以变化gemäß到的金属茂化合物，其具有至少两个官能团的化合物，和各反应物的摩尔比。金属茂催化剂，采用与助催化剂苯乙烯和烯烃聚合。所述助催化剂为有机金属化合物或非配位的路易斯酸和烷基铝的混合物。该有机金属化合物是烷基铝氧烷一般和有机铝化合物。间同立构聚苯乙烯和具有良好的物理性能聚烯烃通过使用金属茂催化剂gemäß到本发明制备。一种用于聚合单体包括苯乙烯，苯乙烯衍生物，以及具有烯不饱和双键的化合物。这些化合物均聚和共聚，得到聚苯乙烯和聚烯烃。

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