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    • 2. 发明公开
    • INK COMPOSITION FOR PHOTOCURABLE INKJET PRINTING
    • EP4173825A1
    • 2023-05-03
    • EP21828095.6
    • 2021-06-04
    • Sakata INX Corporation
    • NAKASHIMA, OkinoriNITTA, RyoichiOGASAHARA, Koki
    • B41J2/01C09D11/101C09D11/30C09D11/38B41M5/00
    • An object is to provide a photocurable inkjet printing ink composition that, subject to having a viscosity suitable for discharge, offers excellent curability, tackiness (no tackiness) after curing, adhesion to various types of resin base materials, bending resistance, abrasion resistance, water resistance, ethanol resistance, and banding resistance. As a solution, a photocurable inkjet printing ink composition is provided that satisfies all of requirements A to F below:
      A: the total content of one or more types of compounds selected from vinyl methyl oxazolidinone, N,N-dimethylacrylamide, benzyl acrylate, and N-vinylcaprolactam, is 30.0% by mass or higher in the photocurable inkjet printing ink composition;
      B: the total content of one or more types of compounds selected from saturated hydrocarbon group-containing monofunctional monomers with 6 or more carbon atoms and saturated hydrocarbon group-containing polyfunctional monomers with 6 or more carbon atoms is 15.0% by mass or higher in the photocurable inkjet printing ink composition;
      C: the content of bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide is 3.5% by mass or higher in the photocurable inkjet printing ink composition;
      D: the total content of ethoxy(2,4,6-trimethylbenzoyl)phenylphosphine oxide and bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide is 6.0 to 12.0% by mass in the photocurable inkjet printing ink composition, and their ratio by mass, or ethoxy(2,4,6-trimethylbenzoyl)phenylphosphine oxide / bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide, is 0.3 to 1.5;
      E: the content of amine-modified oligomer is 0.5 to 15.0% by mass in the photocurable inkjet printing ink composition; and
      F: a colorant.
    • 4. 发明公开
    • ACTIVE ENERGY RAY-CURABLE INK COMPOSITION FOR INKJET
    • EP4316848A1
    • 2024-02-07
    • EP21933257.4
    • 2021-12-14
    • Sakata INX Corporation
    • NAKASHIMA, OkinoriMYOSE, TakuyaKAWABATA, JunOGASAHARA, Koki
    • B41J2/01C09D11/101C09D11/322B41M5/00
    • An object of the present invention is to obtain an active energy ray-curable inkjet ink composition designed to improve color development property and to be LED curable, and designed so that a cured coating film has high hardness and excellent rub resistance and water resistance. As a solution, the ink composition contains a pigment, a pigment dispersant, and a photopolymerizable compound, wherein the pigment contains Pigment Violet 19 and Pigment Orange 71, and Pigment Violet 19 is 30.0 to 85.0% by mass relative to a total mass of Pigment Violet 19 and Pigment Orange 71, and the photopolymerizable compound satisfies all of the following requirements (A) to (F): (A) a multifunctional amine-modified oligomer is contained by 0.20 to 15.0% by mass in a total amount of all polymerizable components; (B) a monofunctional monomer is contained by 50.0% by mass or more in the total amount of all polymerizable components; (C) a monofunctional monomer whose glass transition temperature is 20°C or more is contained by 35.0% by mass or more in the total amount of all polymerizable components; (D) a monofunctional monomer whose glass transition temperature is 10°C or less is contained by 35.0% by mass or more in the total amount of all polymerizable components; (E) a multifunctional monomer whose glass transition temperature is 10°C or less is contained by 2.0 to 11.0% by mass in the total amount of all polymerizable components; and (F) a nitrogen-containing monofunctional monomer is contained by 10.0 to 25.0% by mass in the total amount of all polymerizable components.