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1. 发明公开

EP0373534A2 Symmetrical dioxazine compounds and their use as fiber-reactive dyes 失效
标题翻译： Symmetrische Oxazin-Verbindungen und ihre Verwendung als faserreaktive Farbstoffe。
公开(公告)号：EP0373534A2
公开(公告)日：1990-06-20
申请号：EP89122698.7
申请日：1989-12-08
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Miyamoto, Tetsuya , Takahashi, Miyao , Fujisaki, Takahiko , Ikeou, Shinei , Omura, Takashi
IPC分类号： C09B62/503 , C09B62/04 , D06P1/38
CPC分类号： C09B62/4405 , C09B62/5033
摘要： A dioxazine compound represented by the following formula (I),
wherein V is a direct linkage or
in which R 3 is hydrogen or unsubstituted or substituted alkyl, and X is a direct linkage or an aliphatic, araliphatic or aromatic bridging group, provided that X stands for the bridging group as defined hereinabove when V is
Y is unsubstituted or substituted phenylene, or unsubstituted or substituted naphthylene, Z is -SO 2 CH=CH 2 or -SO 2 CH 2 CH 2 Z 1 in which Z 1 is a group capable of being split by the action of an alkali, Q is sulfo, hydroxy, halo, alkoxy, unsubstituted or substituted phenoxy or unsubstituted or substituted amino, and R 1 and R 2 independently of one another are each hydrogen or unsubstituted or substituted alkyl, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a blue color superior in fastness properties, particularly those such as chlorine fastness, with superior build-up property.
摘要翻译：由下式（I）表示的二恶嗪化合物，其中V是直接键或CHEM，其中R3是氢或未取代或取代的烷基，X是直接键或脂族，芳脂族或芳族桥键基团，条件是当X表示未取代或取代的亚苯基或未取代或取代的亚萘基时，X表示上述定义的桥连基团，Z为-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z1，其中Z 1为能够通过碱的作用分开，Q是磺基，羟基，卤素，烷氧基，未取代或取代的苯氧基或未取代或取代的氨基，并且R 1和R 2彼此独立地为氢或未取代或取代的烷基，其可用于染色或印刷纤维材料以得到具有优异耐牢度性质的蓝色的染色或印刷产品，特别是耐氯牢度的那些，具有优异的聚集性能。

2. 发明公开

EP0385120A1 Fiber reactive asymmetric dioxazine compounds and their use as fiber reactive dyes 失效
标题翻译： Faserreaktive不对称Dioxazinverbindungen und deren Verwendung als faserreaktive Farbstoffe。
公开(公告)号：EP0385120A1
公开(公告)日：1990-09-05
申请号：EP90101890.3
申请日：1990-01-31
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Miyamoto, Tetsuya , Takahashi, Miyao , Fujisaki, Takahiko , Ikeou, Shinei , Omura, Takashi , Harada, Naoki
IPC分类号： C09B62/503 , C09B62/04 , D06P1/38
CPC分类号： C09B62/5033 , C09B62/4405
摘要： An asymmetric dioxazine compound of the following formula in the free acid form,
wherein R is hydrogen, halogen, sulfo or alkoxy, R 1 , R 2 and R 3 are each hydrogen or alkyl, X, and X 2 are each hydrogen, halogen, alkyl, alkoxy or phenoxy, Y is alkylene, phenylene or naphthylene, Z is -SO 2 CH=CH 2 , -SO 2 CH 2 CH 2 OSO 3 H or the like, V is hydrogen, alkyl, acyl or substituted triazinyl, and Q is halogen, alkoxy, amino or a group similar to that of
provided that R is hydrogen, and Q is amino or a group similar to that of
when V is substituted triazinyl, which is useful for dyeing or printing fiber materials to give dyed or printed products of a brilliant blue color superior in fastness properties, particularly those such as chlorine fastness with superior build-up property.
摘要翻译：游离酸形式的下式的不对称二恶嗪化合物其中R是氢，卤素，磺基或烷氧基，R 1，R 2和R 3各自为氢或烷基，X 1和X 2各自为氢，卤素，烷基，烷氧基或苯氧基，Y是亚烷基，亚苯基或亚萘基，Z是-SO2CH = CH2，-SO2CH2CH2OSO3H等，V是氢，烷基，酰基或取代的三嗪基，Q是卤素，烷氧基，氨基或类似的基团条件是当V是取代的三嗪基时，R是氢，Q是氨基或类似于

3. 发明公开

EP0325246A3 Dioxazine blue dye compounds having vinylsulfone type fiber reactive groups 失效
标题翻译：具有乙烯基型纤维反应组的二氧化钛蓝色染料化合物
公开(公告)号：EP0325246A3
公开(公告)日：1989-08-23
申请号：EP89100874.0
申请日：1989-01-19
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Miyamoto, Tetsuya , Takahashi, Miyao , Fujisaki, Takahiko , Harada, Naoki , Kayane, Yutaka , Omura, Takashi
IPC分类号： C09B62/503 , D06P1/384
CPC分类号： C09B62/5033
摘要： Described are dioxazine compounds represented by the following formula in the free acid form,
wherein V is a direct linkage or
in which R₃ is hydrogen or alkyl, X is a direct linkage or an aliphatic, araliphatic or aromatic bridging group, Y is phenylene or naphthylene, Z is a so-called vinylsulfone type fiber reactive group, and R₁ and R₂ are each hydrogen or alkyl, which are useful for dyeing or printing fiber materials to give a dyed or printed product of a blue color superior in fastness properties with superior build-up property.

4. 发明授权

EP0541084B1 Asymmetric dioxazine compounds and method for dyeing or printing fiber materials using the same 失效
标题翻译：使用相同的非对称的二恶嗪化合物和方法用于染色或印花的纤维材料
公开(公告)号：EP0541084B1
公开(公告)日：1997-02-26
申请号：EP92118962.7
申请日：1992-11-05
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Yokogawa, Kazufumi , Fujisaki, Takahiko , Takahashi, Miyao , Kawabata, Shigeru , Harada, Naoki , Akahori, Kingo , Kayane, Yutaka , Omura, Takashi
IPC分类号： C09B62/02 , C09B62/503
CPC分类号： C09B62/5033 , C09B62/0025 , C09B62/021 , C09B62/4405

5. 发明授权

EP0373534B1 Symmetrical dioxazine compounds and their use as fiber-reactive dyes 失效
标题翻译：对称二恶唑化合物及其作为纤维反应性染料的使用
公开(公告)号：EP0373534B1
公开(公告)日：1993-09-15
申请号：EP89122698.7
申请日：1989-12-08
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Miyamoto, Tetsuya , Takahashi, Miyao , Fujisaki, Takahiko , Ikeou, Shinei , Omura, Takashi
IPC分类号： C09B62/503 , C09B62/04 , D06P1/38
CPC分类号： C09B62/4405 , C09B62/5033

6. 发明授权

EP0385120B2 Fiber reactive asymmetric dioxazine compounds and their use as fiber reactive dyes 失效
标题翻译：纤维反应性二恶嗪不对称化合物及其作为纤维反应性染料的使用
公开(公告)号：EP0385120B2
公开(公告)日：2005-06-15
申请号：EP90101890.3
申请日：1990-01-31
申请人： Sumitomo Chemical Company, Limited
发明人： Miyamoto, Tetsuya , Takahashi, Miyao , Fujisaki, Takahiko , Ikeou, Shinei , Omura, Takashi , Harada, Naoki
IPC分类号： C09B62/503 , C09B62/04 , D06P1/38
CPC分类号： C09B62/5033 , C09B62/4405

7. 发明公开

EP0541084A3 Asymmetric dioxazine compounds and method for dyeing or printing fiber materials using the same 失效
标题翻译：不对称二氧杂环己烯化合物及其使用的染料或印刷纤维材料的方法
公开(公告)号：EP0541084A3
公开(公告)日：1993-10-13
申请号：EP92118962.7
申请日：1992-11-05
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yokogawa, Kazufumi , Fujisaki, Takahiko , Takahashi, Miyao , Kawabata, Shigeru , Harada, Naoki , Akahori, Kingo , Kayane, Yutaka , Omura, Takashi
IPC分类号： C09B62/02 , C09B62/503
CPC分类号： C09B62/5033 , C09B62/0025 , C09B62/021 , C09B62/4405
摘要： An asymmetric dioxazine compound represented by the following formula (I) in the free acid form:

wherein A₁ and A₂ independently of one another are each sulfo, halo, alkyl or alkoxy, X₁ and X₂ independently of one another are each hydrogen, halo, alkyl, alkoxy or phenoxy, R₁ is hydrogen or unsubstituted or substituted alkyl, R₂ and R₃ independently of one another are each hydrogen, alkyl, alkoxy, halo or unsubstituted or substituted amino, Z is a fiber-reactive group, m and n independently of one another are each 0 or 1, provided that m≠n, and L is 1 or 2. This compound is suitable for dyeing and printing cellulose fiber, natural and synthetic polyamide fibers, polyurethane fiber, leather and the like and mixed yarns thereof, to obtain dyed or printed products of a color fast to light, wetness and chlorine with superior build-up and level dyeing properties.

8. 发明授权

EP0325246B1 Dioxazine blue dye compounds having vinylsulfone type fiber reactive groups 失效
标题翻译：具有乙烯基纤维型纤维反应性组合物的二恶唑蓝色染料化合物
公开(公告)号：EP0325246B1
公开(公告)日：1992-07-22
申请号：EP89100874.0
申请日：1989-01-19
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Miyamoto, Tetsuya , Takahashi, Miyao , Fujisaki, Takahiko , Harada, Naoki , Kayane, Yutaka , Omura, Takashi
IPC分类号： C09B62/503 , D06P1/384
CPC分类号： C09B62/5033

9. 发明授权

EP0385120B1 Fiber reactive asymmetric dioxazine compounds and their use as fiber reactive dyes 失效
标题翻译：纤维反应性二恶嗪不对称化合物及其作为纤维反应性染料的使用。
公开(公告)号：EP0385120B1
公开(公告)日：1995-04-19
申请号：EP90101890.3
申请日：1990-01-31
申请人： SUMITOMO CHEMICAL COMPANY LIMITED
发明人： Miyamoto, Tetsuya , Takahashi, Miyao , Fujisaki, Takahiko , Ikeou, Shinei , Omura, Takashi , Harada, Naoki
IPC分类号： C09B62/503 , C09B62/04 , D06P1/38
CPC分类号： C09B62/5033 , C09B62/4405

10. 发明公开

EP0541084A2 Asymmetric dioxazine compounds and method for dyeing or printing fiber materials using the same 失效
标题翻译：不对称的二恶嗪化合物和用于使用相同的染色或印花纤维材料的方法。
公开(公告)号：EP0541084A2
公开(公告)日：1993-05-12
申请号：EP92118962.7
申请日：1992-11-05
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED
发明人： Yokogawa, Kazufumi , Fujisaki, Takahiko , Takahashi, Miyao , Kawabata, Shigeru , Harada, Naoki , Akahori, Kingo , Kayane, Yutaka , Omura, Takashi
IPC分类号： C09B62/02 , C09B62/503
CPC分类号： C09B62/5033 , C09B62/0025 , C09B62/021 , C09B62/4405
摘要： An asymmetric dioxazine compound represented by the following formula (I) in the free acid form:

wherein A₁ and A₂ independently of one another are each sulfo, halo, alkyl or alkoxy, X₁ and X₂ independently of one another are each hydrogen, halo, alkyl, alkoxy or phenoxy, R₁ is hydrogen or unsubstituted or substituted alkyl, R₂ and R₃ independently of one another are each hydrogen, alkyl, alkoxy, halo or unsubstituted or substituted amino, Z is a fiber-reactive group, m and n independently of one another are each 0 or 1, provided that m≠n, and L is 1 or 2. This compound is suitable for dyeing and printing cellulose fiber, natural and synthetic polyamide fibers, polyurethane fiber, leather and the like and mixed yarns thereof, to obtain dyed or printed products of a color fast to light, wetness and chlorine with superior build-up and level dyeing properties.
摘要翻译： worin A <5>和A <6>彼此的unabhängig各自是磺基，卤素，烷基或烷氧基，X <5>和：通过在游离酸形式的下式（I）表示的不对称二恶嗪化合物 X <6>彼此分别是氢，卤素，烷基，烷氧基或苯氧基，R <5>是氢或unsubstituiertem或substituiertem烷基，R <6>和R <7>unabhängig一个的另一个各自为氢的unabhängig，烷基，烷氧基，卤素或unsubstituiertem或substituiertem氨基，Z是一个纤维活性基团，m和n彼此unabhängig各自为0或1，条件做m * n个，并且L是1或2该化合物是适用于染色和打印的纤维素纤维，天然和合成的聚酰胺纤维，聚氨酯纤维，皮革及它们的类似物和混合纱线，以获得颜色的染色或印花的产品快速对光，湿度和氯具有优异积聚和水平的染色性能。

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