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1. 发明公开

EP0031695A1 Production of mixture of branched and linear carboxylic acid salts 失效
标题翻译： Herstellung einer Mischung von Salzen线人和VervinweigterCarbonsäuren。
公开(公告)号：EP0031695A1
公开(公告)日：1981-07-08
申请号：EP80304634.1
申请日：1980-12-19
申请人： STAUFFER CHEMICAL COMPANY
发明人： Magee, Walter Lee , Bayer, Arthur Craig
IPC分类号： C07C51/295 , C07C53/126
CPC分类号： C07C51/295
摘要： A process for reacting a mixture of branched and linear alcohols with a caustic, optionally in the presence of a catalyst, to produce a reaction mixture containing carboxylic acid salts, and to liberate hydrogen comprises introducing into the reaction mixture at about a time when a significant evolution of hydrogen from the mixture begins to occur, an effective amount of an inert diluent for the reaction mixture. The effective amount is sufficient to maintain the fluidity of the reaction mixture. A preferred diluent is mineral oil. By operating in this way the tendency of the reaction mixture to foam and solidify is reduced, thus permitting the reaction to proceed to completion and permitting the easy removal of the reaction mixture from the reaction zone. The production of a branched and linear mixture of carboxylic acid salts which substantially corresponds to the branched and linear mixture of alcohols reacted is also ensured.
摘要翻译：使任选在催化剂存在下使支链和直链醇与苛性碱的混合物反应以产生含有羧酸盐的反应混合物和释放氢的方法包括在大约一段时间内引入反应混合物来自混合物的氢气的演变开始发生，有效量的反应混合物的惰性稀释剂。有效量足以保持反应混合物的流动性。优选的稀释剂是矿物油。通过以这种方式操作，反应混合物发泡和固化的趋势降低，从而允许反应进行到完成，并允许从反应区容易地除去反应混合物。也确保了基本上对应于反应的醇的支链和线性混合物的羧酸盐的支链和线性混合物的生产。

2. 发明授权

EP0031695B1 Production of mixture of branched and linear carboxylic acid salts 失效
标题翻译：生产分散和线性羧酸盐的混合物
公开(公告)号：EP0031695B1
公开(公告)日：1983-07-06
申请号：EP80304634.1
申请日：1980-12-19
申请人： STAUFFER CHEMICAL COMPANY
发明人： Magee, Walter Lee , Bayer, Arthur Craig
IPC分类号： C07C51/295 , C07C53/126
CPC分类号： C07C51/295

3. 发明授权

EP0031694B1 Production of carboxylic acid salts 失效
标题翻译：生产羧酸盐
公开(公告)号：EP0031694B1
公开(公告)日：1983-06-01
申请号：EP80304633.3
申请日：1980-12-19
申请人： STAUFFER CHEMICAL COMPANY
发明人： Magee, Walter Lee
IPC分类号： C07C51/295 , C07C53/126
CPC分类号： C07C51/295

4. 发明公开

EP0031694A1 Production of carboxylic acid salts 失效
标题翻译： Herstellung vonCarbonsäuresalzen。
公开(公告)号：EP0031694A1
公开(公告)日：1981-07-08
申请号：EP80304633.3
申请日：1980-12-19
申请人： STAUFFER CHEMICAL COMPANY
发明人： Magee, Walter Lee
IPC分类号： C07C51/295 , C07C53/126
CPC分类号： C07C51/295
摘要： A process for reacting an alcohol with a caustic at a reaction temperature in the presence of a catalytic amount of metallic zinc or a zinc compound to produce a final reaction mixture containing carboxylic acid salts and to liberate hydrogen which comprises mixing (i) the caustic: (ii) the catalytic amount of metallic zinc or zinc compound, and (iii) an effective amount of an inert diluent for the final reaction mixture, to form an intermediate reaction mixture. The effective amount of diluent is an amount sufficient to maintain fluidity of the final reaction mixture. A preferred diluent is mineral oil. The intermediate reaction mixture is then heated to the reaction temperature. Alcohol is then added to the intermediate reaction mixture over a period of time to form the final reaction mixture. The improved process permits greater control of the process thus reducing the tendency of the reaction mixtures to foam and solidify.
摘要翻译：在催化量的金属锌或锌化合物的存在下，在反应温度下使醇与苛性碱反应的方法，以产生含有羧酸盐的最终反应混合物并释放氢，该方法包括混合（i）苛性碱; （ii）催化量的金属锌或锌化合物，和（iii）有效量的用于最终反应混合物的惰性稀释剂，以形成中间反应混合物。稀释剂的有效量是足以保持最终反应混合物的流动性的量。优选的稀释剂是矿物油。然后将中间反应混合物加热至反应温度。然后在一段时间内将醇加入到中间反应混合物中以形成最终的反应混合物。改进的方法允许更好地控制该方法，从而降低反应混合物发泡和固化的趋势。

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