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1. 发明公开

EP0305790A1 Production of graphite intercalation compound and doped carbon films 失效
标题翻译： Herstellung von Graphiteinlagerungsverbindung und gedopte Carbonfilme。
公开(公告)号：EP0305790A1
公开(公告)日：1989-03-08
申请号：EP88113145.2
申请日：1986-03-20
申请人： SHARP KABUSHIKI KAISHA
发明人： Yoshimoto, Yoshikasu , Suzuki, Tomonari , Higashigaki, Yoshiyuki , Nakajima, Shigeo , Inoguchi, Toshio
IPC分类号： C01B31/00 , H01L29/16
CPC分类号： C30B29/04 , C01B32/22 , C23C16/26 , C30B25/02
摘要： The present invention provide a method for preparing graphite intercalation compounds with metal or metal compounds consisting of a simultaneous thermal decomposition of two kinds of starting materials, modified CVD (Chemical vapor deposition) method in which hydrocarbon as a source material for the host graphite and other organometal reagents or metal halides for guest metal species or metal compound are decomposed at a same time in a reactor in order to intercalate the metal species or metal compound into carbon being depositing on the substrate. Further, the present invention provides a doped carbon film which is capable of P-type or N-type according to kinds of dopant species obtained by partial substitution of dopants for carbon atoms which constitute graphite hexagonal net layer during the growth of carbon films, through simultaneous thermal decomposition of two kinds of source materials for carbon films and for dopant to be substituted.
摘要翻译：本发明提供了一种用金属或金属化合物制备石墨插层化合物的方法，该金属或金属化合物由两种起始材料同时热分解，改性CVD（化学气相沉积）法，其中烃作为主体石墨的源材料在反应器中同时分解用于客体金属物质或金属化合物的有机金属试剂或金属卤化物，以将金属物质或金属化合物嵌入到沉积在基底上的碳中。此外，本发明提供了一种掺杂碳膜，其能够根据通过在碳膜生长过程中构成石墨六方网状碳层的碳原子的掺杂剂的部分取代而获得的掺杂物种的种类通过P型或N型，通过用于碳膜和待取代的掺杂剂的两种源材料的同时热分解。

2. 发明授权

EP0201696B1 Production of carbon films 失效
标题翻译：生产碳膜
公开(公告)号：EP0201696B1
公开(公告)日：1991-03-13
申请号：EP86103833.9
申请日：1986-03-20
申请人： SHARP KABUSHIKI KAISHA
发明人： Yoshimoto, Yoshikasu , Suzuki, Tomonari , Higashigaki, Yoshiyuki , Nakajima, Shigeo , Inoguchi, Toshio
IPC分类号： C23C16/26
CPC分类号： C30B29/04 , C01B32/22 , C23C16/26 , C30B25/02
摘要： Disclosed is a method for preparing pyrolytic carbon films with highly ordered graphite structure at relatively low temperature comprising thermal decomposing an organic compounds introduced by a carrier gas into a reaction chamber to deposit the carbon films onto a single-crystalline substrate. The present invention also is to provide a method for preparing graphite intercalation compounds with metal or metal compounds consisting of a simultaneous thermal decomposition of two kinds of starting materials, modified CVD (Chemical vapor deposition) method in which hydrocarbon as a source material for the host graphite and other organometal reagents or metal halides for guest metal species or metal compound are decomposed at a same time in a reactor in order to intercalate the metal species or metal compound into carbon being depositing on the substrate. Further, the present invention is to provide a doped carbon film which is capable of P-type or N-type according to kinds of dopant species obtained by partial substitution of dopants for carbon atoms which constitute graphite hexagonal net layer during the growth of carbon films, through simultaneous thermal decomposition of two kinds of source materials for carbon films and for dopant to be substituted.

3. 发明授权

EP0305790B1 Production of graphite intercalation compound and doped carbon films 失效
标题翻译：石墨介质化合物和碳化硅膜的生产
公开(公告)号：EP0305790B1
公开(公告)日：1993-01-13
申请号：EP88113145.2
申请日：1986-03-20
申请人： SHARP KABUSHIKI KAISHA
发明人： Yoshimoto, Yoshikasu , Suzuki, Tomonari , Higashigaki, Yoshiyuki , Nakajima, Shigeo , Inoguchi, Toshio
IPC分类号： C01B31/00 , H01L29/16
CPC分类号： C30B29/04 , C01B32/22 , C23C16/26 , C30B25/02
摘要： Disclosed is a method for preparing pyrolytic carbon films with highly ordered graphite structure at relatively low temperature comprising thermal decomposing an organic compounds introduced by a carrier gas into a reaction chamber to deposit the carbon films onto a single-crystalline substrate. The present invention also is to provide a method for preparing graphite intercalation compounds with metal or metal compounds consisting of a simultaneous thermal decomposition of two kinds of starting materials, modified CVD (Chemical vapor deposition) method in which hydrocarbon as a source material for the host graphite and other organometal reagents or metal halides for guest metal species or metal compound are decomposed at a same time in a reactor in order to intercalate the metal species or metal compound into carbon being depositing on the substrate. Further, the present invention is to provide a doped carbon film which is capable of P-type or N-type according to kinds of dopant species obtained by partial substitution of dopants for carbon atoms which constitute graphite hexagonal net layer during the growth of carbon films, through simultaneous thermal decomposition of two kinds of source materials for carbon films and for dopant to be substituted.

4. 发明公开

EP0196011A3 Methods and materials for thermoelectric and light-heat conversion 失效
标题翻译：用于热电和光热转换的方法和材料
公开(公告)号：EP0196011A3
公开(公告)日：1988-08-31
申请号：EP86103734
申请日：1986-03-19
申请人： SHARP KABUSHIKI KAISHA
发明人： Higashigaki, Yoshiyuki , Yoshimoto, Yoshikazu , Suzuki, Tomonari , Nakajima, Shigeo , Inoguchi, Toshio
IPC分类号： H01L35/22 , H01L35/32
CPC分类号： H01L35/34 , H01L35/22 , Y10S428/913 , Y10T428/1317
摘要： 57 The disclosure is directed to a method for converting between heat energy and electric energy which is characterized in that a carbon intercalation compound is employed as a thermoelectric material by utilizing temperature difference in a direction perpendicular to the structure of carbon layers, or a method for producing a light-heat converting material which is characterized in that a thin metallic layer like a translucent mirror is caused to adhere to the inner surface of a light transmissive hollow tube by pyrolytically decomposing at a temperature approximately below 1000°C, with hydrocarbons being introduced into the hollow tube (3) at the rate of a predetermined amount an hour.

5. 发明公开

EP0196011A2 Method for thermoelectric conversion 失效
标题翻译：一种用于热电转换过程。
公开(公告)号：EP0196011A2
公开(公告)日：1986-10-01
申请号：EP86103734.9
申请日：1986-03-19
申请人： SHARP KABUSHIKI KAISHA
发明人： Higashigaki, Yoshiyuki , Yoshimoto, Yoshikazu , Suzuki, Tomonari , Nakajima, Shigeo , Inoguchi, Toshio
IPC分类号： H01L35/22 , H01L35/32
CPC分类号： H01L35/34 , H01L35/22 , Y10S428/913 , Y10T428/1317
摘要： 57 The disclosure is directed to a method for converting between heat energy and electric energy which is characterized in that a carbon intercalation compound is employed as a thermoelectric material by utilizing temperature difference in a direction perpendicular to the structure of carbon layers, or a method for producing a light-heat converting material which is characterized in that a thin metallic layer like a translucent mirror is caused to adhere to the inner surface of a light transmissive hollow tube by pyrolytically decomposing at a temperature approximately below 1000°C, with hydrocarbons being introduced into the hollow tube (3) at the rate of a predetermined amount an hour.

6. 发明授权

EP0196011B1 Method for thermoelectric conversion 失效
标题翻译：一种用于热电转换过程。
公开(公告)号：EP0196011B1
公开(公告)日：1993-10-27
申请号：EP86103734.9
申请日：1986-03-19
申请人： SHARP KABUSHIKI KAISHA
发明人： Higashigaki, Yoshiyuki , Yoshimoto, Yoshikazu , Suzuki, Tomonari , Nakajima, Shigeo , Inoguchi, Toshio
IPC分类号： H01L35/22 , H01L35/32
CPC分类号： H01L35/34 , H01L35/22 , Y10S428/913 , Y10T428/1317

7. 发明公开

EP0201696A3 Production of carbon films, graphite intercalation compound and doped carbon films 失效
标题翻译：碳膜，石墨介质化合物和碳化硅膜的生产
公开(公告)号：EP0201696A3
公开(公告)日：1987-02-04
申请号：EP86103833
申请日：1986-03-20
申请人： SHARP KABUSHIKI KAISHA
发明人： Yoshimoto, Yoshikasu , Suzuki, Tomonari , Higashigaki, Yoshiyuki , Nakajima, Shigeo , Inoguchi, Toshio
IPC分类号： C23C16/26 , C30B29/02
CPC分类号： C30B29/04 , C01B32/22 , C23C16/26 , C30B25/02
摘要： @ Disclosed is a method for preparing pyrolytic carbon films with highly ordered graphite structure at relatively low temperature comprising thermal decomposing an organic compounds introduced by a carrier gas into a reaction chamber to deposit the carbon films onto a single-crystalline substrate. The present invention also is to provide a method for preparing graphite intercalation compounds with metal or metal compounds consisting of a simultaneous thermal decomposition of two kinds of starting materials, modified CVD (Chemical vapor deposition) method in which hydrocarbon as a source material for the host graphite and other organometal reagents or metal halides for guest metal species or metal compound are decomposed at a same time in a reactor in order to intercalate the metal species or metal compound into carbon being depositing on the substrate. Further, the present invention is to provide a doped carbon film which is capable of P-type or N-type according to kinds of dopant species obtained by partial substitution of dopants for carbon atoms which constitute graphite hexagonal net layer during the growth of carbon films, through simultaneous thermal decomposition of two kinds of source materials for carbon films and for dopant to be substituted.

8. 发明公开

EP0201696A2 Production of carbon films 失效
标题翻译： Herstellung von Kohlenstoffschichten。
公开(公告)号：EP0201696A2
公开(公告)日：1986-11-20
申请号：EP86103833.9
申请日：1986-03-20
申请人： SHARP KABUSHIKI KAISHA
发明人： Yoshimoto, Yoshikasu , Suzuki, Tomonari , Higashigaki, Yoshiyuki , Nakajima, Shigeo , Inoguchi, Toshio
IPC分类号： C23C16/26
CPC分类号： C30B29/04 , C01B32/22 , C23C16/26 , C30B25/02
摘要： @ Disclosed is a method for preparing pyrolytic carbon films with highly ordered graphite structure at relatively low temperature comprising thermal decomposing an organic compounds introduced by a carrier gas into a reaction chamber to deposit the carbon films onto a single-crystalline substrate. The present invention also is to provide a method for preparing graphite intercalation compounds with metal or metal compounds consisting of a simultaneous thermal decomposition of two kinds of starting materials, modified CVD (Chemical vapor deposition) method in which hydrocarbon as a source material for the host graphite and other organometal reagents or metal halides for guest metal species or metal compound are decomposed at a same time in a reactor in order to intercalate the metal species or metal compound into carbon being depositing on the substrate. Further, the present invention is to provide a doped carbon film which is capable of P-type or N-type according to kinds of dopant species obtained by partial substitution of dopants for carbon atoms which constitute graphite hexagonal net layer during the growth of carbon films, through simultaneous thermal decomposition of two kinds of source materials for carbon films and for dopant to be substituted.
摘要翻译：公开了一种在相对低的温度下制备具有高度有序石墨结构的热解碳膜的方法，包括将由载气引入的有机化合物热分解成反应室，以将碳膜沉积在单晶衬底上。本发明还提供一种制备石墨插层化合物的方法，所述金属或金属化合物由两种原料的同时热分解组成，其中烃作为主体的源材料的改性CVD（化学气相沉积）方法在反应器中同时分解用于客体金属物质或金属化合物的石墨和其它有机金属试剂或金属卤化物，以将金属物质或金属化合物嵌入到沉积在基底上的碳中。此外，本发明提供一种掺杂碳膜，其能够根据在碳膜生长期间构成石墨六方网状碳层的碳原子的掺杂剂的部分取代而获得的掺杂剂种类的P型或N型，通过对碳膜和待取代的掺杂剂的两种源材料的同时热分解。

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