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    • 1. 发明公开
    • INK COMPOSITION, RECORDING METHOD USING THE SAME, AND RECORDED MATTER
    • 墨水组合物,用它MACH RACING AUFZEICHUNGSVERFAHREN并记录对象
    • EP1878774A1
    • 2008-01-16
    • EP06730269.5
    • 2006-03-28
    • Seiko Epson Corporation
    • KANAYA, MiharuAOYAMA, TetsuyaHANMURA, Masahiro
    • C09D11/00B41J2/01B41M5/00C09C3/10
    • C09D11/30C01P2004/64C09C3/10C09D11/106C09D11/326Y10T428/24802
    • An object of the present invention is to provide an ink composition which can provide an image having excellent glossy texture to various recording media, particularly to a glossy recording medium, is decreased in bronzing phenomenon, and is also good in fixing property and scratch resistance such as gloss change. The invention relates to an ink composition containing at least a coloring agent coated with a water-insoluble polymer as a coloring material and a resin emulsion as an additive, wherein the weight average molecular weight of the water-insoluble polymer is from 50,000 to 150,000, and wherein the resin emulsion comprises a resin comprising a monomer component of the same kind as the monomer component constituting the water-insoluble polymer and having a weight average molecular weight of 1.5 to 4 times that of the water-insoluble polymer; and an ink composition containing at least a coloring agent coated with a water-insoluble polymer and resin particles, wherein the water-insoluble polymer is a polymer obtained by a solution polymerization process using at least a polymerizable unsaturated monomer and a polymerization initiator, wherein the coloring agent coated with the water-insoluble polymer is a coloring material obtained by a phase inversion emulsification process in which after the water-insoluble polymer is dissolved in an organic solvent, at least the coloring agent and water are added thereto, followed by mixing, and the organic solvent is removed to perform dispersion in an aqueous system, and wherein the resin particles are a polymer obtained by an emulsion polymerization process using at least a crosslinking agent.
    • 本发明的一个目的是提供一种油墨组合物,其能够提供具有优异的光泽的纹理,以各种记录介质,尤其涉及一种光泽记录介质中的图像,在青铜现象减少,并因此在定影性和耐擦伤性搜索良好 作为光泽变化。 本发明涉及对包含至少涂有水不溶性聚合物作为着色材料和树脂乳液作为添加剂的着色剂,worin的重均分子量的水不溶性聚合物的是从50,000至150,000的油墨组合物, 和worin树脂乳液包括树脂,其包括同种的单体成分作为单体成分构成的水不溶性聚合物和具有1.5至4倍做了水不溶性聚合物的重均分子量; 以及含有油墨组合物至少涂布有水不溶性聚合物和树脂颗粒,worin的水不溶性聚合物的着色剂是至少使用聚合性不饱和单体和聚合引发剂,通过溶液聚合方法得到的聚合物,worin的 涂有水不溶性聚合物的着色剂是水不溶性聚合物溶解于有机溶剂后通过在转相乳化方法得到的着色材料,至少,将着色剂和水加入其中,接着进行混合, 并除去有机溶剂,以在wässrige系统进行色散,和worin所述树脂颗粒是由至少在使用交联剂而得到的聚合物的乳液聚合方法。
    • 5. 发明公开
    • RECORDING MEDIUM EXCELLENT IN LIGHT−RESISTANCE AND METHOD FOR PRODUCTION THEREOF
    • 澳大利亚麻省理工学院麻省理工学院
    • EP1418056A1
    • 2004-05-12
    • EP02751634.3
    • 2002-07-18
    • Mitsui Chemicals, Inc.SEIKO EPSON CORPORATION
    • ISHIDA, Tadashi c/o MITSUI CHEMICALS, INC.KUSUMOTO, MasayaTOMITA, YoshihikoITO, SotaONISHI, HiroyukiHANMURA, Masahiro
    • B41M5/00
    • B41M5/5245B41M5/508B41M5/52B41M5/5236B41M5/5254
    • An ink jet recording medium comprising a support and, on the support, at least one layer comprising cationic organic particles which have a glass transition temperature of from 70 to 130°C and comprise (A) 0.1 to 10 % by weight of a monomer having a hindered amine type functional group, (B) 0.1 to 10 % by weight of a monomer having a benzotriazole type functional group and (C) 80 to 99.8 % by weight of a monomer selected from styrene and acrylic monomers.
      A process for producing an ink jet recording medium which process comprises applying a suspension of copolymeric particles which have a glass transition temperature of from 70 to 130°C and comprise (A) 0.1 to 10 % by weight of a monomer having a hindered amine type functional group, (B) 0.1 to 10 % by weight of a monomer having a benzotriazole type functional group and (C) 80 to 99.8 % by weight of a monomer selected from styrene and acrylic monomers, on a support, and allowing the coating surface in a wet state or in a dried state to pressure contact with a mirror roll to smooth the surface.
      The present invention can provide the ink jet recording sheet having excellent ink absorption characteristics, color development concentration, water resistance, light resistance, yellowing resistance and surface strength, and the process for producing the recording sheet.
    • 一种喷墨记录介质,其包括载体,并且在载体上至少包含玻璃化转变温度为70至130℃的阳离子有机颗粒的层,并且包含(A)0.1-10重量%的具有 受阻胺型官能团,(B)0.1〜10重量%的具有苯并三唑型官能团的单体和(C)80〜99.8重量%的选自苯乙烯和丙烯酸单体的单体。 一种制造喷墨记录介质的方法,该方法包括施加玻璃化转变温度为70至130℃的共聚物颗粒的悬浮液,并且包含(A)0.1-10重量%的具有 受阻胺型官能团,(B)0.1〜10重量%的具有苯并三唑型官能团的单体和(C)80〜99.8重量%的选自苯乙烯和丙烯酸单体的单体,在载体上,和 允许涂覆表面处于湿状态或干燥状态,以与镜辊压力接触以使表面光滑。 本发明可以提供具有优异的油墨吸收特性,显色浓度,耐水性,耐光性,耐黄变性和表面强度的喷墨记录纸及其制备方法。