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    • 10. 发明公开
    • Hydrogen-absorbing alloy electrode and process for producing the same
    • Elektrode aus einer wasserstoffabsorbierenden Legierung und Herstellungsverfahrendafür。
    • EP0647973A1
    • 1995-04-12
    • EP94115782.8
    • 1994-10-06
    • SANYO ELECTRIC CO., LTD.
    • Nogami, MitsuzoKimoto, MamoruMatsuura, YoshinoriNishio, KojiSaito, Toshihiko
    • H01M4/38H01M4/24
    • B22F3/22H01M4/242H01M4/383Y10S420/90
    • A first hydrogen-absorbing alloy electrode is obtained by applying a hydrogen-absorbing alloy powder on a collector or having a collector filled with a hydrogen-absorbing alloy powder and then sintering the hydrogen-absorbing alloy powder. The hydrogen-absorbing alloy powder is pre-pared by centrifugal spraying or gas atomizing and particles constituting the powder have a spherical shape, a nearly spherical shape, an egg-like shape or a mixed shape including the foregoing. The hydrogen-absorbing alloy electrode can readily be produced at low cost and have high packing density and good corrosion resistance, and can hence yield, when used for negative electrodes, metal hydride secondary batteries having excellent cycle characteristics. A second hydrogen-absorbing alloy electrode comprises a mixed powder containing a spherical-particle powder of a hydrogen-absorbing alloy and a powder as pulverized of the same alloy in a specific ratio. This electrode has high packing density and electronic conductivity, and can therefore gives batteries having excellent discharge characteristics on both high-rate discharge and low-rate discharge.
    • 通过将吸氢合金粉末施加到集电体上或者填充有吸氢合金粉末的集电体,然后烧结吸氢合金粉末,获得第一吸氢合金电极。 吸氢合金粉末通过离心喷雾或气体雾化进行预处理,构成粉末的颗粒具有球形,近球形,卵形或包括上述的混合形状。 吸氢合金电极可以容易地以低成本制造并且具有高填充密度和良好的耐腐蚀性,因此当用于负极时,可以产生具有优异的循环特性的金属氢化物二次电池。 第二吸氢合金电极包括含有吸氢合金的球形颗粒粉末和以特定比例粉碎的相同合金粉末的混合粉末。 该电极具有高的堆积密度和电子导电性,因此可以在高倍率放电和低倍率放电两种情况下给出具有优异放电特性的电池。