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    • 3. 发明公开
    • MODIFYING ORGANOALUMINUM CO-CATALYSTS FOR IMPROVED PERFORMANCE
    • MODIFIZIERUNG VON ORGANOALUMINIUM-COKATALYSATORENFÜRVERBESSERTE LEISTUNG
    • EP3102326A1
    • 2016-12-14
    • EP15708048.2
    • 2015-02-04
    • Sabic Global Technologies B.V.
    • LICCIULLI, SebastianoSCHMIDT, Roland
    • B01J31/02B01J31/14
    • Processes of making catalyst compositions are provided. In an exemplary embodiment, the processes include modifying an organoaluminum compound with a modifier that decreases the initial reducing strength of the organoaluminum compound, where the modifier can be an ether, an anhydride, an amine, an amide, a silicate, a silyl ether, a siloxane, an ester, a carbonate, a urea, a carbamate, a sulfoxide, a sulfone, a phosphoramide, or a combination thereof. The processes further include adding a transition metal complex to the mixture of the organoaluminum compound and the modifier; and obtaining a catalyst composition including the organoaluminum compound and the transition metal complex.
    • 提供制备催化剂组合物的方法。 在一个示例性实施方案中,所述方法包括用改进剂改性有机铝化合物,所述改性剂降低有机铝化合物的初始还原强度,其中改性剂可以是醚,酸酐,胺,酰胺,硅酸盐,甲硅烷基醚, 硅氧烷,酯,碳酸酯,脲,氨基甲酸酯,亚砜,砜,磷酰胺或其组合。 所述方法还包括向有机铝化合物和改性剂的混合物中加入过渡金属络合物; 得到包含有机铝化合物和过渡金属络合物的催化剂组合物。