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1. 发明授权

EP1100766B1 CROSSLINKABLE LIQUID CRYSTALLINE COMPOUNDS 有权
标题翻译：性液晶化合物
公开(公告)号：EP1100766B1
公开(公告)日：2004-04-07
申请号：EP99929631.2
申请日：1999-07-19
申请人： Rolic AG
发明人： OHLEMACHER, Angela , BENECKE, Carsten , SCHMITT, Klaus
IPC分类号： C07C69/94 , C09K19/20 , C07C69/92 , C09K19/38 , C09K19/32 , C09K19/34
CPC分类号： C09K19/2007 , C07C69/92 , C07C69/94 , C09K19/32 , C09K19/3444 , C09K19/3458 , C09K19/38 , C09K2019/0448

2. 发明公开

EP1230319A1 TOPOLOGICALLY STRUCTURED POLYMER COATING 有权
标题翻译：拓扑结构聚合物涂层
公开(公告)号：EP1230319A1
公开(公告)日：2002-08-14
申请号：EP00965716.4
申请日：2000-10-18
申请人： Rolic AG
发明人： SEIBERLE, Hubert , SCHADT, Martin , IBN-ELHAJ, Mohammed , BENECKE, Carsten , SCHMITT, Klaus
IPC分类号： C09K19/54 , G02F1/1334 , G02F1/1335 , G02F1/1337
CPC分类号： B05D5/061 , B29C41/003 , B29K2995/0072 , B82Y30/00 , C09K19/542 , C09K19/56 , G02B1/08 , G02B1/11 , G02B5/0257 , G02B5/1847 , G02B5/3083 , G02F1/133711 , G02F1/13378 , G02F1/1391 , Y10T428/1005 , Y10T428/24479 , Y10T428/24521 , Y10T428/2457 , Y10T428/24942
摘要： Sub-micron-structured (nanostructured) polymer film or coatings are made by coating a substrate with a mixture of materials. One of the materials is removed using a selective solvent, leaving pores or other nanostructure. The substrate may be grooved, providing a competing nanostructure. The coating may act as an antireflective coating, optical retarder, optical diffuser, or orientation layer.
摘要翻译：亚微米结构（纳米结构）聚合物膜或涂层通过用材料混合物涂覆基底来制备。其中一种材料使用选择性溶剂除去，留下孔隙或其他纳米结构。衬底可以开槽，提供竞争的纳米结构。该涂层可以用作抗反射涂层，光学延迟器，光学漫射器或取向层。

3. 发明授权

EP1187802B1 LIQUID CRYSTAL COMPOUNDS 有权
标题翻译：液晶化合物
公开(公告)号：EP1187802B1
公开(公告)日：2008-01-02
申请号：EP00914329.8
申请日：2000-04-11
申请人： Rolic AG
发明人： CHERKAOUI, Zoubair, Mohammed , BENECKE, Carsten , SCHMITT, Klaus
IPC分类号： C07C69/92 , C09K19/20 , C09K19/32 , C07C69/54 , C07C69/734 , C07C255/54
CPC分类号： C07C69/54 , C07C69/734 , C07C69/92 , C07C255/54 , C09K19/2014 , C09K19/322 , C09K2019/326 , Y10T428/10
摘要： Compounds of formula I:wherein the variables are defined as explained in the disclosure. The invention also provides liquid crystalline mixtures and optical or electro-optical devices including compounds of formula (I).
摘要翻译：本发明提供了式（I）的化合物，其中A 1至A 4独立地选自氢，甲基和含有2至80个碳原子的烃基，其中一个或多个碳原子任选地被选自-O - ， - S-和-N-的杂原子替代，条件是首先不将两个杂原子连接在一起，其次，A 1至A 4中的至少一个包括可聚合基团; B1代表含有4至80个碳原子的烃基，其中一个或多个碳原子任选地被选自-O - ， - S-和-N-的杂原子替代，条件是没有两个杂原子是联合在一起; MG 1和MG 2相同或不同，并且各自独立地表示含有1至80个碳原子的芳族或非芳族碳环或杂环体系，条件是首先将MG 1， MG 2包含至少两个环体系，其次，当MG 1和MG 2相同时，A 1和A 2或A 3和A 4各自不同。本发明还提供了包含式（I）化合物的液晶混合物和光学或电光学装置。

4. 发明授权

EP1051454B1 LIQUID-CRYSTALLINE PHOTOCROSSLINKABLE MIXTURE 有权
标题翻译：液晶光交联MIX
公开(公告)号：EP1051454B1
公开(公告)日：2004-03-10
申请号：EP99900272.8
申请日：1999-01-26
申请人： Rolic AG
发明人： BENECKE, Carsten , BUCHECKER, Richard , MARCK, Guy
IPC分类号： C09K19/38
CPC分类号： C09K19/38 , Y10T428/1005 , Y10T428/1036

5. 发明授权

EP0983225B1 NEW POLYMERISABLE LIQUID CRYSTALLINE COMPOUNDS 失效
标题翻译： NEW聚合性液晶化合物
公开(公告)号：EP0983225B1
公开(公告)日：2003-12-17
申请号：EP98919404.8
申请日：1998-05-22
申请人： Rolic AG
发明人： BENECKE, Carsten , LUKAC, Teodor , OHLEMACHER, Angela
IPC分类号： C07C69/92 , C09K19/30 , C09K19/38 , C07C69/94 , C07C69/54 , C08F220/20 , C07C39/15
CPC分类号： C07C69/92 , C07C69/54 , C07C69/94 , C09K19/3059 , C09K19/3068 , C09K19/38 , C09K19/3852 , C09K2019/0444 , C09K2019/0448 , C09K2019/0481 , C09K2019/0485 , Y10T428/10

6. 发明公开

EP1169293A1 LIQUID CRYSTAL COMPOUNDS 有权
标题翻译：液晶化合物
公开(公告)号：EP1169293A1
公开(公告)日：2002-01-09
申请号：EP00902824.2
申请日：2000-02-15
申请人： Rolic AG
发明人： LUKAC, Teodor , BENECKE, Carsten , BUCHECKER, Richard
IPC分类号： C07C69/92 , C09K19/20 , C09K19/34 , C09K19/32 , C09K19/38
CPC分类号： C09K19/32 , C07C69/92 , C07C255/54 , C09K19/2007 , C09K19/34 , C09K19/38 , C09K2019/0448 , C09K2019/0481
摘要： A compound of formula (I), wherein G?1 and G2¿ independently represent a polymerisable mesogenic residue; X represents a group selected from -CH¿2?-, -O-, -CO-, -COO-, -OOC-, -CONR'-, -OCOO-, -OCONR'; Sp represents a group of the formula -(CH2)p- in which p is an integer of 1 to 18 and in which one or two non adjacent -CH2- groups are optionally replaced by -CH=CH-; or in which one or two -CH2- groups are optionally replaced by one or two groups selected from the group consisting of -O-, -CO-, -COO-, -OOC-, -CONR'-, -OCOO-, -OCONR' with the proviso that firstly the spacer group does not contain two adjacent heteroatoms and secondly when X is -CH2-, p can also have a value of 0; and M represents an achiral group of formula (II) in which A and B independently represent an optionally substituted six membered isocyclic or heterocyclic group or naphthalenediyl; C is selected from the group consisting of an optionally substituted five and six membered isocyclic or heterocyclic group or naphthalenediyl; n?1 and n2¿ are 0 or 1 with the proviso that firstly 1≤n1+n2≤2 and secondly, when C is naphthalenediyl 0≤n1+n2≤2; Z1 is selected from the group consisting of -O-, -COO-, -OOC-, -CO-, -CONR'-, -NR'CO-, OCOO-, -OCONR'-, -NR'COO- and a single bond; in which R' is selected from the group consisting of hydrogen, a lower achiral alkyl group and a lower achiral alkenyl group; Z?2 and Z3¿ are independently selected from the group consisting of single bond, -COO-, -OOC-, -CH¿2?-CH2-, -CH2O-, -OCH2-, -CH=CH-, -C C-, -(CH2)4- and -(CH2)3O-; and R?1¿ is selected from the group consisting of -CN, -COR, -COOR, -OCOR, -CONR'R, -NR'COR, OCOOR, -OCONR'R, -NR'COOR, -F, -Cl, -CF¿3?, -OCF3, -OR and -R in which R is selected from the group consisting of hydrogen, an achiral C1-18 alkyl group and an achiral C4-18 alkenyl group with the double bond at 3-position or higher; and R' is as defined above; with the proviso that at most one of the rings A, B and C is a naphthalenediyl group is provided as well as liquid crystalline mixtures, films and electro-optical devices comprising the compound.
摘要翻译：式（I）化合物，其中G 1和G 2独立地代表可聚合的介晶残基; X代表选自-CH 2， - O - ， - CO - ， - COO - ， - OOC - ， - CONR' - ， - OCOO - ， - OCONR' Sp表示式 - （CH 2）p - 的基团，其中p为1至18的整数，并且其中一个或两个不相邻的-CH 2 - 基团任选被-CH = CH-替代; 或其中一个或两个-CH 2 - 基团任选地被一个或两个选自-O - ， - CO - ， - COO - ， - OOC - ， - CONR'-，-OCOO - ， - OCONR'，条件是首先间隔基团不含有两个相邻的杂原子，其次当X是-CH 2 - 时，p也可以具有0的值; 且M代表式（II）的非手性基团，其中A和B独立地表示任选取代的六元异环或杂环基团或萘二基; C选自任选取代的五元和六元异环或杂环基或萘二基; n1和n2是0或1，条件是首先1≤n1+n2≤2，其次，当C是萘二基0≤n1+n2≤2时; Z 1选自-O - ， - COO - ， - OOC - ， - CO - ， - CONR'-， - NR'CO-，OCOO - ， - OCONR'-， - NR'COO-和单键; 其中R'选自氢，低级非手性烷基和低级非手性烯基; Z2和Z3独立地选自单键，-COO-，-OOC-，-CH2-，-CH2-，-CH2O-，-OCH2-，-CH = CH-，-C （CH 2）4 - 和 - （CH 2）3 O-; R 1选自-CN，-COR，-COOR，-OCOR，-CONR'R，-NR'COR，OCOOR，-OCONR'R，-NR'COOR，-F， - Cl，-CF 3，-OCF 3，-OR和-R，其中R选自氢，非手性C 1-18烷基和非手性C 4-18烯基，职位或更高; 和R'如上所定义; 条件是至多环A，B和C中的一个是萘二基，以及包含该化合物的液晶混合物，膜和电光器件。

7. 发明授权

EP1169293B1 LIQUID CRYSTAL COMPOUNDS 有权
标题翻译：的液晶化合物
公开(公告)号：EP1169293B1
公开(公告)日：2009-07-22
申请号：EP00902824.2
申请日：2000-02-15
申请人： Rolic AG
发明人： LUKAC, Teodor , BENECKE, Carsten , BUCHECKER, Richard
IPC分类号： C07C69/92 , C09K19/20 , C09K19/34 , C09K19/32 , C09K19/38
CPC分类号： C09K19/32 , C07C69/92 , C07C255/54 , C09K19/2007 , C09K19/34 , C09K19/38 , C09K2019/0448 , C09K2019/0481
摘要： A compound of formula (I), wherein G?1 and G2¿ independently represent a polymerisable mesogenic residue; X represents a group selected from -CH¿2?-, -O-, -CO-, -COO-, -OOC-, -CONR'-, -OCOO-, -OCONR'; Sp represents a group of the formula -(CH2)p- in which p is an integer of 1 to 18 and in which one or two non adjacent -CH2- groups are optionally replaced by -CH=CH-; or in which one or two -CH2- groups are optionally replaced by one or two groups selected from the group consisting of -O-, -CO-, -COO-, -OOC-, -CONR'-, -OCOO-, -OCONR' with the proviso that firstly the spacer group does not contain two adjacent heteroatoms and secondly when X is -CH2-, p can also have a value of 0; and M represents an achiral group of formula (II) in which A and B independently represent an optionally substituted six membered isocyclic or heterocyclic group or naphthalenediyl; C is selected from the group consisting of an optionally substituted five and six membered isocyclic or heterocyclic group or naphthalenediyl; n?1 and n2¿ are 0 or 1 with the proviso that firstly 1≤n1+n2≤2 and secondly, when C is naphthalenediyl 0≤n1+n2≤2; Z1 is selected from the group consisting of -O-, -COO-, -OOC-, -CO-, -CONR'-, -NR'CO-, OCOO-, -OCONR'-, -NR'COO- and a single bond; in which R' is selected from the group consisting of hydrogen, a lower achiral alkyl group and a lower achiral alkenyl group; Z?2 and Z3¿ are independently selected from the group consisting of single bond, -COO-, -OOC-, -CH¿2?-CH2-, -CH2O-, -OCH2-, -CH=CH-, -C C-, -(CH2)4- and -(CH2)3O-; and R?1¿ is selected from the group consisting of -CN, -COR, -COOR, -OCOR, -CONR'R, -NR'COR, OCOOR, -OCONR'R, -NR'COOR, -F, -Cl, -CF¿3?, -OCF3, -OR and -R in which R is selected from the group consisting of hydrogen, an achiral C1-18 alkyl group and an achiral C4-18 alkenyl group with the double bond at 3-position or higher; and R' is as defined above; with the proviso that at most one of the rings A, B and C is a naphthalenediyl group is provided as well as liquid crystalline mixtures, films and electro-optical devices comprising the compound.

8. 发明授权

EP1102741B1 LIQUID CRYSTALLINE COMPOUNDS 有权
标题翻译：液晶化合物
公开(公告)号：EP1102741B1
公开(公告)日：2003-07-02
申请号：EP99935005.1
申请日：1999-08-09
申请人： Rolic AG
发明人： CHERKAOUI, Zoubair, Mohammed , BENECKE, Carsten
IPC分类号： C07C69/92 , C09K19/20 , C09K19/34 , C09K19/38
CPC分类号： C07C69/92 , C09K19/2007 , C09K19/2014 , C09K19/3068 , C09K19/38 , C09K2019/0448

9. 发明公开

EP1154981A1 LIQUID CRYSTAL COMPOUNDS 有权
标题翻译： FLÜSSIGKRISTALLVERBINDUNGEN
公开(公告)号：EP1154981A1
公开(公告)日：2001-11-21
申请号：EP00901280.8
申请日：2000-02-01
申请人： Rolic AG
发明人： BUCHECKER, Richard , LUKAC, Teodor , BENECKE, Carsten
IPC分类号： C07C69/92 , C09K19/20 , C09K19/34 , C09K19/38
CPC分类号： C07D307/42 , C07C69/92 , C07C255/14 , C07C255/54 , C07C2601/14 , C09K19/2007 , C09K19/34 , C09K19/38 , C09K2019/0448
摘要： A compound of formula (I), wherein G?1 and G2¿ independently represent a polymerisable mesogenic residue X represents a group selected from the group consisting -CH¿2?-, -O-, -CO-, -COO-, -OOC-, -CONR'-, -OCOO- and -OCONR'; Sp represents a group of the formula -(CH2)p- in which p is an integer of 1 to 18 and in which one or two non adjacent -CH2- groups are optionally replaced by -CH=CH-; or in which one or two -CH2- groups may be replaced by one or two groups selected from the group consisting -CH2-, -O-, -CO-, -COO-, -OOC-, -CONR'-, -OCOO- and -OCONR'- with the proviso that firstly the spacer group does not contain two adjacent heteroatoms and secondly when X is -CH2-, p can also have a value of 0; Q represents a a polar group selected from -CN, -COR, -COOR, -OCOR, -CONR'R, -NR'COR, -OCOOR, -OCONR'R, -NR'COOR, F, Cl, -CF3, -OCF3 or -OR or a cyclic group which is unsubstituted or optionally substituted by a group selected from a lower alkyl, lower alkenyl, lower alkoxy, lower alkenyloxy, halogen, -CN, -COR'', -COOR'', -OCOR'', -CONR'R'', -NR'COR'', -OCOOR'', -OCONR'R'', -NR'COOR'', -CF3, and -OCF3; where R represents hydrogen, a lower alkyl, a lower alkenyl or a cyclic group as defined above; and R' is hydrogen, a lower alkyl or a lower alkenyl group; R'' represents a lower alkyl or a lower alkenyl group and liquid crystal mixtures containing the compounds.
摘要翻译：在一个实施方案中，本发明涉及式（I）的化合物，其中G1和G2独立地表示可聚合的介晶残基，X，Sp和Q如本文所定义。本发明的化合物例如可用作可固化液晶，并用于制备液晶膜。

10. 发明公开

EP0983225A1 NEW POLYMERISABLE LIQUID CRYSTALLINE COMPOUNDS 失效
标题翻译： NEW聚合性液晶化合物
公开(公告)号：EP0983225A1
公开(公告)日：2000-03-08
申请号：EP98919404.8
申请日：1998-05-22
申请人： Rolic AG
发明人： BENECKE, Carsten , LUKAC, Teodor , OHLEMACHER, Angela
IPC分类号： C07C69/92 , C09K19/30 , C09K19/38 , C07C69/94 , C07C69/54 , C08F220/20 , C07C39/15
CPC分类号： C07C69/92 , C07C69/54 , C07C69/94 , C09K19/3059 , C09K19/3068 , C09K19/38 , C09K19/3852 , C09K2019/0444 , C09K2019/0448 , C09K2019/0481 , C09K2019/0485 , Y10T428/10
摘要： Compounds with the general formula (I): R-S?1-A-Z1-B-S2¿-R, where A and B are independent ring systems with the formulae (a1), (a2) or (b), whereby in the trans-1,4-cyclohexylene ring, one or two non-adjacent CH¿2? groups may be replaced by oxygen, and whereby, in the 1,4-phenylene ring, one or two non-adjacent CH groups may be replaced by nitrogen; L?1, L2, L3¿ represent, independently, hydrogen, C¿1?-C20-alkyl, C1-C20-alkenyl, C1-C20-alkyloxy, C1-C20-alkyloxy carbonyl, formyl, C1-C20-alkyl carbonyl, C1-C20-alkyl carbonyloxy, halogen, cyano or nitro; Z1, Z2, Z3 represent, independently, a single bond, -CH2CH2-, -CH2O-, -OCH2-, -COO-, -OOC-, -(CH2)4-, -O(CH2)3-, -(CH2)3O- or -C=C-; S?1, S2¿ represent a spacer unit, R represents crosslinkable groups, with the proviso that at least one of the ring systems A or B represents a ring system with the formulae (a?1) or (a2), Z1 or Z2¿ denoting a single bond.

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