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    • 4. 发明公开
    • CO-ASSEMBLY METHOD AND CO-ASSEMBLED STRUCTURES MADE THEREBY
    • 共同组装方法及由其制成的共组装结构
    • EP2419784A1
    • 2012-02-22
    • EP09843429.3
    • 2009-07-24
    • Rhodia OpérationsCentre National de la Recherche Scientifique
    • FRESNAIS, JeromeBERRET, Jean-francoisQI, LingCHAPEL, Jean-paulCASTAING, Jean-christophe
    • G02F1/00
    • C08J5/20
    • A co-assembly method includes, in an aqueous polyelectrolyte composition comprising: (a) a first polyelectrolyte dispersed in the composition and having a net electric charge of a first polarity, (b)a second polyelectrolyte dispersed in the composition and having a net electric charge of a second polarity, wherein the second polarity is opposite the first polarity, and (c)an electrolyte dissolved in the composition in a concentration effective to prevent co-assembly of the polyelectrolytes, the step of allowing co- assembly of the polyelectrolytes by: (1) decreasing the concentration of the electrolyte, or (2) forming an interface between the aqueous polyelectrolyte composition and a surface of a solid substrate or of a second liquid phase, wherein the surface has an affinity for at least one of the polyelectrolytes, or (3) decreasing the concentration of the electrolyte and forming such an interface.
    • 一种共组装方法包括在含水聚电解质组合物中包含:(a)分散在该组合物中并具有第一极性净电荷的第一聚电解质,(b)分散在该组合物中并具有净电的第二聚电解质 其中第二极性与第一极性相反,以及(c)以有效防止聚电解质的共同组装的浓度溶解在组合物中的电解质,允许聚电解质的共组装 :(1)降低电解质的浓度,或(2)在含水聚电解质组合物与固体基质或第二液相的表面之间形成界面,其中所述表面对至少一种聚电解质具有亲和性 或(3)降低电解质的浓度并形成这样的界面。