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1. 发明公开

EP0601953A1 Process of hydrogenation in solution of the double bonds of polymers of conjugated dienes, and hydrogenated block copolymer produced 失效
标题翻译：一种用于在制备conjugiesten二烯的聚合物和氢化的嵌段共聚物的双键的溶液氢化方法。
公开(公告)号：EP0601953A1
公开(公告)日：1994-06-15
申请号：EP93500150.3
申请日：1993-11-03
申请人： REPSOL QUIMICA S.A.
发明人： Parellada Ferrer, Maria Dolores , Barrio Calle, Juan Antonio
IPC分类号： C08C19/02
CPC分类号： C08C19/02
摘要： Process of hydrogenation in solution of polymers of conjugated dienes in the presence of homogeneous catalysts which contain, as essential component, a titanium compound of the type CP₂Ti(PhOR)₂, where Cp is a cyclopentadienyl group, Ph a phenyl group, and OR an alkoxide group containing 1 to 4 carbon atoms; or a titanium compound of the type Cp₂TiR₂, where R is a CH₂PPh₂ group.
These catalysts are very active in the selective hydrogenation of the double bonds of the diene units of polymers or copolymers of conjugated dienes having number-averaged molecular weights of between approximately 500 and 1,000,000, and, in particular, of random and block copolymers of styrene and butadiene or isoprene, the latter containing at least one styrene block and one polybutadiene and/or polyisoprene block.
摘要翻译：在其中包含的均相催化剂的存在下共轭二烯的聚合物的溶液氢化的过程中，作为必要成分，类型Cp2Ti（普）2，其中Cp是环戊二烯基的钛化合物中，Ph为苯基，和OR，以醇盐组含1至4个碳原子; 或类型Cp2TiR2，其中R是CH2PPh2组的钛化合物。这些催化剂在聚合物或具有约500至1,000,000数均分子量的共轭二烯的共聚物的服务单元的双键的选择性加氢非常活跃，并且，特别地，苯乙烯的无规和嵌段共聚物和丁二烯或异戊二烯，后者包含至少一个苯乙烯嵌段和聚丁二烯一个和/或聚异戊二烯嵌段。

2. 发明授权

EP0885905B1 Process for producing hydrogenated rubbers 失效
标题翻译：一种用于生产氢化橡胶的过程
公开(公告)号：EP0885905B1
公开(公告)日：2005-03-09
申请号：EP97500108.2
申请日：1997-06-20
申请人： REPSOL QUIMICA S.A.
发明人： Barrio Calle, Juan Antonio , Parellada Ferrer, Maria Dolores , Espinosa Soriano, Maria Jose
IPC分类号： C08C19/02 , C08F8/04
CPC分类号： C08F8/04 , C08C19/02

3. 发明公开

EP0545844A1 Process for the hydrogenation of compounds with an olefinic unsaturation 失效
标题翻译： Verfahren zur Hydrierung von Verbindungen mitfinsischerUngesättigkeit。
公开(公告)号：EP0545844A1
公开(公告)日：1993-06-09
申请号：EP92500162.0
申请日：1992-12-04
申请人： REPSOL QUIMICA S.A.
发明人： Barrio Calle, Juan , Parellada Ferrer, Maria Dolores , Cuenca Agreda, Tomas , Flores Serrano, Juan Carlos , Royo Gracia, Pascual
IPC分类号： C07C5/03 , C08F8/04 , C08C19/02
CPC分类号： C08C19/02 , C07C5/03 , C07C2531/22 , C08F8/04 , Y10S526/943
摘要： Procedure of olefin hydrogenation in liquid phase in the presence of homogeneous catalysts that contain, as essential component,a titanocene of general formula Cp ¥ CpTiR₂, Cp^CpTiR₂, Cp^Cp [CpTiR₂]₂, or Cp^Cp[Cp ¥ TiR₂]₂ where Cp ¥ is a pentamethylcyclopentadienyl, Cp cyclopentadienyl, Cp^Cp are two cyclopentadienyl rings linked together by a dimethylsililene (Me₂Si), and R is an alyl, aryl, alkylaryl, or alcoxide group containing between 1 and 20 carbon atoms or a halogen atom, a PPh₂, CH₂SiMe₃, CH₂PPh₂, or H.
These catalysts are very active in the hydrogenation of linear and branched, internal and external olefins, cycloolefins and diolefins. In addition, they are able to selectively hydrogenate double bonds of diene groups in conjugated diene polymers and copolymers, of medium molecular weight between approximately 500 and 1,000,000 and, in particular, the random copolymers and styrene and butadiene or isoprene block copolymers, containing the latter at least one styrene block and a polybutadiene and/or isoprene block.
摘要翻译：在均相催化剂的存在下，在含有通式Cp CpTiR2，Cp＆amp; CpTiR2，Cp＆amp; Cp [CpTiR2] 2或Cp＆amp; Cp＆Cp [Cp]的二茂钛的均相催化剂的存在下， YEN> TiR 2] 2其中Cp 是五甲基环戊二烯基，Cp环戊二烯基，Cp＆amp; C p是通过二甲基硅烷（Me 2 Si）连接在一起的两个环戊二烯基环，R是含有1和1之间的烯丙基，芳基，烷基芳基或烷氧基 20个碳原子或一个卤素原子，一个PPh 2，CH 2 SiMe 3，CH 2 PPh 2或H.这些催化剂在直链和支链，内部和外部烯烃，环烯烃和二烯烃的氢化中非常有活性。此外，它们能够选择性地氢化共轭二烯聚合物和共聚物中的二烯基团的双键，其中等分子量在约500和1,000,000之间，特别是含有后者的无规共聚物和苯乙烯和丁二烯或异戊二烯嵌段共聚物至少一个苯乙烯嵌段和聚丁二烯和/或异戊二烯嵌段。

4. 发明公开

EP0885905A1 Process for producing hydrogenated rubbers 失效
标题翻译： Verfahren zur Herstellung von hydrierten Kautschuken
公开(公告)号：EP0885905A1
公开(公告)日：1998-12-23
申请号：EP97500108.2
申请日：1997-06-20
申请人： REPSOL QUIMICA S.A.
发明人： Barrio Calle, Juan Antonio , Parellada Ferrer, Maria Dolores , Espinosa Soriano, Maria Jose
IPC分类号： C08C19/02 , C08F8/04
CPC分类号： C08F8/04 , C08C19/02
摘要： Process for producing hydrogenated rubbers which allows an easy and effective deactivation of the living polymer before the hydrogenation step. The deactivation of living polymer is carried out using compounds with very good solubility in water of formula R-OH , R-COOH or compound of type R' n -Si-Cl 4-n , R' n -Sn-Cl 4-n , with n comprised between 0 and 3, extremes included; wherein R is a C 2 -C 20 alkyl group optionally containing one or more polar functional groups selected from C-OH, COOH, and R' is a C 1 -C 20 alkyl or C 6- C 20 aryl. The catalysts used in the hydrogenation of the deactivated polymer are titanocene compounds, being the most preferred those of formula Cp 2 Ti (PhOCH 3 ) 2 and Cp 2 Ti (CH 2 PPh 2 ) 2 .
摘要翻译：制备氢化橡胶的方法，其允许在氢化步骤之前容易且有效地使活性聚合物失活。活性聚合物的失活使用在式R-OH，R-COOH或R'n-Si-Cl4-n，R'n-Sn-Cl4-n的化合物在水中具有非常好的溶解度的化合物进行， n包含在0和3之间，包括极端值; 其中R是任选地含有一个或多个选自C-OH，COOH的极性官能团的C 2 -C 20烷基，R'是C 1 -C 20烷基或C 6 -C 20芳基。用于氢化失活的聚合物的催化剂是二茂钛化合物，最优选的是式Cp2Ti（PhOCH3）2和Cp2Ti（CH2PPh2）2。

5. 发明授权

EP0601953B1 Process of hydrogenation in solution of the double bonds of polymers of conjugated dienes, and hydrogenated block copolymer produced 失效
标题翻译：一种用于在conjugiesten二烯的聚合物，共聚物和嵌段共聚物的双键的溶液加氢方法产生氢化
公开(公告)号：EP0601953B1
公开(公告)日：1997-05-14
申请号：EP93500150.3
申请日：1993-11-03
申请人： REPSOL QUIMICA S.A.
发明人： Parellada Ferrer, Maria Dolores , Barrio Calle, Juan Antonio
IPC分类号： C08C19/02
CPC分类号： C08C19/02

6. 发明授权

EP0545844B1 Process for the hydrogenation of compounds with an olefinic unsaturation 失效
标题翻译：一种化合物的含有烯属不饱和的氢化方法
公开(公告)号：EP0545844B1
公开(公告)日：1997-04-23
申请号：EP92500162.0
申请日：1992-12-04
申请人： REPSOL QUIMICA S.A.
发明人： Barrio Calle, Juan , Parellada Ferrer, Maria Dolores , Cuenca Agreda, Tomas , Flores Serrano, Juan Carlos , Royo Gracia, Pascual
IPC分类号： C07C5/03 , C08F8/04 , C08C19/02
CPC分类号： C08C19/02 , C07C5/03 , C07C2531/22 , C08F8/04 , Y10S526/943

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