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    • 1. 发明公开
    • Polarographic measuring electrode device
    • 极坐标测量电极装置
    • EP0212126A3
    • 1989-02-22
    • EP86108303.8
    • 1986-06-18
    • RADIOMETER A/S
    • Christiansen, Torben FalchKokholm, Finn
    • G01N27/416
    • G01N27/404
    • An electrochemical measuring electrode device (10) for polarographically measuring the partial pressure of oxygen in an electrolytic medium comprises a cathode (14) which is capable of reducing oxygen and defines an exposed oxygen-reducing cathode surface (20), an anode (18), which defines an exposed anode surface which is arranged relative to the exposed oxygen-reducing cathode surface so as to communicate electrolytically therewith through the electrolytic medium, and a membrane (24), which covers the exposed oxygen-reducing cathode surface and further defines an electrolyte chamber (22) in which the electrolytic medium is confined. In order to effectively promote the decomposition H 2 0 2 generated in the electrolytic medium as an oxygen reduction intermediate and thereby reduce the response time of the electrode, a stable, non-biological catalytic means is provided catalytically communicating with the H 2 0 2 . The stable, non-biological catalytic means is preferably constituted by platinum black particles which may be received by the membrane at a central region (42) thereof or alternatively be received by a support structure which may further constitute a covering of at least part of the membrane (24). The platinum black particles may be pressed into a foil material constituting a base material of the membrane or alternatively be applied in a suspension to the membrane whereupon the suspension is solidifyed.
    • 3. 发明公开
    • Polarographic measuring electrode device
    • 极谱电极测量装置。
    • EP0212126A2
    • 1987-03-04
    • EP86108303.8
    • 1986-06-18
    • RADIOMETER A/S
    • Christiansen, Torben FalchKokholm, Finn
    • G01N27/416
    • G01N27/404
    • An electrochemical measuring electrode device (10) for polarographically measuring the partial pressure of oxygen in an electrolytic medium comprises a cathode (14) which is capable of reducing oxygen and defines an exposed oxygen-reducing cathode surface (20), an anode (18), which defines an exposed anode surface which is arranged relative to the exposed oxygen-reducing cathode surface so as to communicate electrolytically therewith through the electrolytic medium, and a membrane (24), which covers the exposed oxygen-reducing cathode surface and further defines an electrolyte chamber (22) in which the electrolytic medium is confined. In order to effectively promote the decomposition H 2 0 2 generated in the electrolytic medium as an oxygen reduction intermediate and thereby reduce the response time of the electrode, a stable, non-biological catalytic means is provided catalytically communicating with the H 2 0 2 . The stable, non-biological catalytic means is preferably constituted by platinum black particles which may be received by the membrane at a central region (42) thereof or alternatively be received by a support structure which may further constitute a covering of at least part of the membrane (24).
      The platinum black particles may be pressed into a foil material constituting a base material of the membrane or alternatively be applied in a suspension to the membrane whereupon the suspension is solidifyed.