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    • 3. 发明公开
    • ZINC-PLATED STEEL SHEET FOR HOT PRESSING HAVING OUTSTANDING SURFACE CHARACTERISTICS, HOT-PRESSED MOULDED PARTS OBTAINED USING THE SAME, AND A PRODUCTION METHOD FOR THE SAME
    • 镀锌钢热具有优异的表面性能,使GOT热压TRIMS及其制造方法PRESSING
    • EP2520686A2
    • 2012-11-07
    • EP10841224.8
    • 2010-12-28
    • Posco
    • SOHN, Il-RyoungKIM, Jong-SangPARK, Joong-ChulCHO, Yeol-RaeOH, Jin-KeunCHO, Han-GuCHUNG, Bong-HoonLEE, Jong-Seog
    • C23C2/06C22C38/00C23C2/02C23C2/28
    • C23C2/28C22C38/001C22C38/04C23C2/02C23C2/06C23C2/40C23C8/10Y10T428/12799Y10T428/12917Y10T428/12924Y10T428/12931Y10T428/12937Y10T428/12951Y10T428/12958
    • In one aspect of the present invention, provided is a zinc-plated steel sheet for hot pressing having outstanding surface characteristics, comprising: a steel foundation plate comprising a metal surface diffusion layer of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, to a depth of 1 µm from the surface; an aluminium-rich layer containing at least 30 wt.% of aluminium formed on the surface diffusion layer of the metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr; and a zinc plating layer formed on the aluminium-rich layer; wherein annealing oxides having a mean thickness of no more than 150 nm are distributed in a non-continuous fashion between the surface diffusion layer and the aluminium-rich layer, and there is a content of at least 0.1 wt.% of the metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, to a depth of 1 µm from the surface of the steel foundation plate. In this way, a metal having a low affinity for oxygen is coated to an effective thickness prior to annealing and thus the creation of annealing oxides at the surface of the steel sheet is suppressed and a uniform zinc plating layer is formed, and alloying of the zinc plating layer is promoted during press-processing heat treatment such that the melting temperature of the zinc plating layer is increased within a short time, thereby making it possible to prevent deterioration of the plating layer and to minimise the occurrence of internal oxides formed after hot press moulding. Also, according to another aspect of the present invention, an oxide layer able to prevent deterioration of the zinc plating layer is formed on the surface of the plating layer during hot press heating, and a three element phase of Zn, Fe and the metal is formed in the plating layer such that the zinc plating layer can be kept stable, good surface conditions are ensured and the phosphatability is outstanding, the plating properties during electrodeposition plating and film adhesion can be ensured even without carrying out a separate phosphating process, and workability can be improved as cracking in the steel foundation plate during hot press moulding is prevented.
    • 在本发明中,提供的一个方面是一种镀锌钢板热压具有优秀的表面特性,包括:一钢基础板,其包含的金属表面扩散层每氧的摩尔氧化期间的吉布斯自由能减少是 小于Cr的,从表面1微米的深度; 富铝层含有铝形成了的金属的表面扩散层上至少30%(重量)的每氧化过程中氧的摩尔的吉布斯自由能减小小于Cr的。 和锌电镀层形成的富铝层上; 具有不大于150nm的平均厚度worin退火氧化物分布在表面扩散层和富铝层之间的非连续的方式,并且存在其中的金属的至少0.1重量%的含量 每氧化过程中氧的摩尔的吉布斯自由能减小小于Cr的,以1微米的从钢基础板的表面的深度。 以这种方式,具有对氧的亲和性低的金属被涂覆在的有效厚度在退火之前,因此退火氧化物在钢板的表面的创建被抑制和均匀的锌镀层形成,并且合金化 压加工热处理期间镀锌层被促进检查没有镀锌层的熔化温度在短的时间内增加,从而使得能够防止电镀层的恶化,并最小化内部氧化物的后热成形发生 冲压成型。 所以,雅鼎在本发明的另一个方面,锌能够防止锌电镀层的劣化的氧化物层上形成热压加热时的镀覆层的表面上,和Fe的三个元件相和金属是 在检查的电镀层而形成没有镀锌层可以保持稳定,良好的表面条件被保证并且磷酸盐的能力是突出的,电沉积镀覆和薄膜粘附在电镀性能甚至可以不进行单独的磷化工艺来保证,和可加工性 可以如在热压成型时的钢基础板开裂防止得到改善。