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1. 发明公开

EP2159232A1 OLEFIN POLYMERIZATION CATALYST AND PREPARATION METHOD AND USE THEREOF 有权
标题翻译： OLEFINPOLYMERISATIONSKATALYSATOR，HERSTELLUNGSVERFAHRENDAFÜRUND VERWENDUNG DAVON
公开(公告)号：EP2159232A1
公开(公告)日：2010-03-03
申请号：EP08748499.4
申请日：2008-05-15
申请人： Petrochina Company Limited
发明人： YI, Jianjun , CUI, Chunming , LI, Huashu , YIN, Baozuo , ZHANG, Jianying , LANG, Xiaomei , WU, Linmei
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F110/06 , C08F4/6465 , C08F4/6567 , C08F4/6543 , C08F4/651 , C08F2500/15
摘要： An olefin polymerization catalyst and preparation method and use thereof are provided. The catalyst component comprises (1) an active magnesium halide, (2) a titanium compound containing at least one Ti-halide bond supported thereon, and (3) an electron donor selected from the group consisting of one or more sulfonyl-containing compounds having the following formula. There are two methods for preparing such solid catalyst component: I) treating the active magnesium halide (1) particles with alkylaluminum, subsequently adding the electron donor (3), treating it with the solution of titanium compound (2) one or more times; II) adding spherical magnesium chloride alcoholate particles to the solution of titanium compound (2), subsequently adding the electron donor (3), treating it with the solution of titanium compound (2) one or more times. The catalyst system comprises such solid catalyst component, a co-catalyst (alkylaluminum compound) and an external electron donor.
摘要翻译：提供烯烃聚合催化剂及其制备方法和用途。催化剂组分包括（1）活性卤化镁，（2）包含其上负载有至少一个Ti卤化物键的钛化合物，和（3）选自一种或多种含磺酰基化合物的电子给体，所述化合物具有以下公式。制备这种固体催化剂组分有两种方法：I）用烷基铝处理活性卤化镁（1）颗粒，随后加入电子给体（3），用钛化合物（2）的溶液处理一次或多次; II）向钛化合物（2）的溶液中加入球形氯化镁醇盐颗粒，随后加入电子给体（3），用钛化合物（2）的溶液处理一次或多次。催化剂体系包括这种固体催化剂组分，助催化剂（烷基铝化合物）和外电子给体。

2. 发明公开

EP2345675A1 A CATALYST FOR HOMOPOLYMERIZING AND COPOLYMERIZING PROPYLENE AND ITS PREPARATION AND USE 有权
标题翻译：催化剂用于丙烯均聚和共聚，其生产和使用
公开(公告)号：EP2345675A1
公开(公告)日：2011-07-20
申请号：EP08877924.4
申请日：2008-12-02
申请人： Petrochina Company Limited
发明人： YI, Jianjun , YIN, Baozuo , CUI, Chunming , LI, Zhifei , CUI, Liang , LI, Huashu , HUANG, Weihuan , ZHANG, Jianying , WANG, Li
IPC分类号： C08F4/649 , C08F10/06
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/6545 , C08F4/651 , C08F4/6543 , C08F2500/15 , C08F210/16 , C08F2500/12
摘要： A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl 2 .nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl 2 .nROH is 0.01-1, based on the amount of MgCl 2 .nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl 2 .nROH is 1-200. The catalyst has high activity high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.

3. 发明授权

EP2159232B1 OLEFIN POLYMERIZATION CATALYST AND PREPARATION METHOD AND USE THEREOF 有权
标题翻译：烯烃，工艺及其制造和使用
公开(公告)号：EP2159232B1
公开(公告)日：2012-11-21
申请号：EP08748499.4
申请日：2008-05-15
申请人： Petrochina Company Limited
发明人： YI, Jianjun , CUI, Chunming , LI, Huashu , YIN, Baozuo , ZHANG, Jianying , LANG, Xiaomei , WU, Linmei
IPC分类号： C08F4/64 , C08F10/00
CPC分类号： C08F110/06 , C08F4/6465 , C08F4/6567 , C08F4/6543 , C08F4/651 , C08F2500/15

4. 发明授权

EP2345675B1 A CATALYST FOR HOMOPOLYMERIZING AND COPOLYMERIZING PROPYLENE AND ITS PREPARATION AND USE 有权
标题翻译：丙烯均聚和共聚催化剂及其制备和使用
公开(公告)号：EP2345675B1
公开(公告)日：2017-11-08
申请号：EP08877924.4
申请日：2008-12-02
申请人： Petrochina Company Limited
发明人： YI, Jianjun , YIN, Baozuo , CUI, Chunming , LI, Zhifei , CUI, Liang , LI, Huashu , HUANG, Weihuan , ZHANG, Jianying , WANG, Li
IPC分类号： C08F4/649 , C08F10/06 , C08F4/651
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F4/6545 , C08F4/651 , C08F4/6543 , C08F2500/15 , C08F210/16 , C08F2500/12

5. 发明公开

EP2567986A1 OLEFIN POLYMERIZATION CATALYST AND PREPARATION METHOD AND USE THEREOF 有权转让
标题翻译：烯烃和工艺及其生产和使用
公开(公告)号：EP2567986A1
公开(公告)日：2013-03-13
申请号：EP11863798.2
申请日：2011-06-03
申请人： Petrochina Company Limited
发明人： YI, Jianjun , CUI, Chunming , LI, Huashu , LI, Zhifei , YIN, Baozuo , CUI, Liang , ZHANG, Jianying , WANG, Liang
IPC分类号： C08F4/656 , C08F4/654 , C08F10/00
CPC分类号： C08F4/16 , C08F10/06 , C08F110/06 , C08F4/6565 , C08F4/6465 , C08F2500/15
摘要： An olefin polymerization catalyst and preparation method and use thereof are provided. The components of the catalyst comprise an active magnesium halide, a titanium compound containing at least one Ti-halide bond loaded on the active magnesium halide, and an internal electron donor selected from one or more silicon esters compounds having formula (I). The method for preparing the catalyst components is that: adding spherical magnesium chloride alcoholate particles and the electron donor into the solution of titanium compound in sequence, and processing with the titanium compound for one or more times to obtain the catalyst. The catalyst system used for the olefin polymerization comprises the catalyst components, a cocatalyst and an external electron donor. The catalyst has high activity for the propylene polymerization, and the activity is 4399 gPP/gTi·h(50°C, lh, slurry polymerization at atmospheric pressure), and the isotacticity of the polymer is 98%.

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