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    • 4. 发明公开
    • ELECTRON TRANSPORT LAYER COMPRISING A MATRIX COMPOUND MIXTURE FOR AN ORGANIC LIGHT-EMITTING DIODE (OLED)
    • 包含用于有机发光二极管(OLED)的基质化合物混合物的电子传输层
    • EP3208861A1
    • 2017-08-23
    • EP16156578.3
    • 2016-02-19
    • Novaled GmbH
    • GANIER, JeromeROTHE, CarstenSENKOVSKYY, Volodymyr
    • H01L51/54
    • H01L51/0058H01L51/0072H01L51/008H01L51/508
    • The present invention is directed to an organic light emitting diode (100) comprising:
      - at least one anode electrode (120);
      - at least one emission layer (150), wherein the emission layer comprises at least one emitter dopant that emits visible light at operation of the OLED (100);
      - an electron transport layer stack (160) of at least two electron transport layers (161/ 162), and wherein
      a) the first electron transport layer (161) comprises i) a first organic aromatic matrix compound having a MW of about ≥ 400 to about ≤ 1000 and a dipole moment of about ≥ 0 Debye and about ≤ 2.5 Debye, wherein the first electron transport layer (161) is free of a polar organic aromatic phosphine compound; and
      b) the second electron transport layer (162) comprises two organic aromatic matrix compounds, which are a mixture of:
      i) the first organic aromatic matrix compound; and
      ii) a polar organic aromatic phosphine compound having a MW of about ≥ 400 to about ≤ 1000, and a dipole moment of about > 2.5 Debye and about ≤ 10 Debye; and
      - at least one cathode electrode layer (190); wherein
      the electron transport layer stack (160) is arranged between the emission layer (150) and the cathode electrode layer (190), the first electron transport layer (161) is in direct contact with the second electron transport layer (162), and wherein the first electron transport layer (161) is arranged nearer to the emission layer (150) and the second electron transport layer (162) is arranged nearer to the cathode electrode layer (190).
    • 本发明涉及一种有机发光二极管(100),包括: - 至少一个阳极(120); - 至少一个发射层(150),其中所述发射层包括在所述OLED(100)的操作下发射可见光的至少一种发射体掺杂剂; - 至少两个电子传输层(162分之161)的电子传输层堆叠(160),并且其中a)所述第一电子传输层(161)包括:i)具有大约≥400的MW的第一有机芳香基质化合物 其中第一电子传输层(161)不含极性有机芳族膦化合物;并且其中第一电子传输层(161)不含极性有机芳香族膦化合物。 和b)第二电子传输层(162)包含两种有机芳香族基质化合物,它们是以下物质的混合物:i)第一有机芳香族基质化合物; 和ii)分子量约为400至约1000的极性有机芳香族膦化合物以及约> 2.5德拜和约≤10德拜的偶极矩; 和 - 至少一个阴极电极层(190); 其中,所述电子传输层堆叠(160)布置在所述发射层(150)和所述阴极电极层(190),所述第一电子传输层(161)之间与所述第二电子传输层(162)直接接触,并且 其中第一电子传输层(161)布置得更靠近发射层(150)并且第二电子传输层(162)布置得更靠近阴极电极层(190)。