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    • 2. 发明公开
    • OLIGOANILINE COMPOUND AND USE THEREOF
    • 低聚安酰胺化合物及其用途
    • EP2062871A1
    • 2009-05-27
    • EP07806720.4
    • 2007-09-05
    • Nissan Chemical Industries, Ltd.
    • YOSHIMOTO, TakujiKATO, Taku
    • C07C211/56C08G73/00C09D5/24C09D179/00C09K11/06H01L51/50
    • C08G73/0266C07C211/56C08L79/02C09D5/24H01B1/128H01L51/0035H01L51/0059H01L51/0081H01L51/5048H01L2251/308H05B33/22Y02E10/549
    • Disclosed is an oligoaniline compound represented by the formula (1), (2), (3) or (4) below, which exhibits high solubility in a low-polarity solvent. This oligoaniline compound is suitable as a charge-transporting material which enables to realize excellent device characteristics such as low driving voltage when applied to an OLED device.




      (In the formulae, R 1 -R 20 independently represent a hydrogen atom, a halogen atom, a hydroxy group, an amino group, a silanol group, a thiol group, a carboxyl group, a sulfonic acid group, a phosphate group, a phosphoric acid ester group, an ester group, a thioester group, an amide group, a nitro group, a monovalent hydrocarbon group, an organoxy group, an organoamino group, an organosilyl group, an organothio group, an acyl group or a sulfonic group; m, n, l and k independently represent an integer respectively satisfying 1 ≤ m ≤ 20, 1 ≤ n ≤ 20, 1 ≤ l ≤ 20 and 1 ≤ k ≤ 20; and X represents a fluorinated aryl group.)
    • 公开了在低极性溶剂中显示出高溶解度的由式(1),(2),(3)或(4)表示的低聚苯胺化合物。 该低聚苯胺化合物适合作为电荷传输材料,其能够在应用于OLED器件时实现优异的器件特性,例如低驱动电压。 (式中,R 1〜R 20分别独立地表示氢原子,卤素原子,羟基,氨基,硅烷醇基,硫醇基,羧基,磺酸基,磷酸基,磷酸 酯基,硫酯基,酰胺基,硝基,一价烃基,有机氧基,有机氨基,有机甲硅烷基,有机硫基,酰基或磺酸基; m, n,l和k独立地表示分别满足1≤m≤20,1≤n≤20,1≤l≤20和1≤k≤20的整数; X表示氟化芳基。)
    • 4. 发明公开
    • OLIGOANILINE COMPOUNDS
    • 低聚赖氨酸化合物
    • EP2062870A1
    • 2009-05-27
    • EP07806719.6
    • 2007-09-05
    • Nissan Chemical Industries, Ltd.
    • KATO, TakuYOSHIMOTO, Takuji
    • C07C211/54C07C217/92C07C323/37C09K11/06H01L51/50
    • C07C323/37C07C211/55C07C217/92C07D493/18H01L51/0035H01L51/0059H01L51/5048H05B33/22
    • An oligoaniline compound represented by the formula (1) can provide a charge transporting thin film which shows a suppressed coloration in the visible range. Use of this thin film makes it possible to ensure a color reproducibility of a device without lowering the color purity of an electroluminescent light or a light having passed through a color filter.

      wherein R 1 to R 10 independently represent each a hydrogen atom, a halogen, etc.; m and n independently represent each an integer of 1 or more while satisfying the condition m+n ≤ 20; and X is a structure represented by any of the following formulae (4) to (10), etc.;

      wherein R 21 to R 36 independently represent each a hydrogen atom, a hydroxyl group, etc.; p and q represent each an integer of 1 or more while satisfying the conditions p ≤ 20 and q ≤ 20; and W 1 s independently represent each -(CR 1 R 2 )p-, -O-, -S-, etc.
    • 由式(1)表示的低聚苯胺化合物可以提供在可见光范围内显示抑制着色的电荷输送薄膜。 使用这种薄膜可以确保设备的颜色再现性,而不降低电致发光光或穿过滤色器的光的颜色纯度。 其中R1至R10各自独立地表示氢原子,卤素等; m和n在满足条件m +n≤20的同时独立地表示1以上的整数; X为下述式(4)〜(10)中的任一个所表示的结构等。 其中R 21至R 36各自独立地表示氢原子,羟基等; p和q分别表示1以上的整数,满足条件p≤20且q≤20; 和W1独立地表示 - (CR1R2)p - , - O-,-S-等